New monocyclopentadienyl complexes of Group 4 and 5 metals with chelating nitrogen ligands. Crystal and molecular structures of [Zr(η3-C3H5)(η4-Ph2N2C2Me2-2,3)Cp″] and [TaCl2{η4-C6H4(NSiMe3-1,2)2}Cp″] [Cp″ = C5H3(SiMe3)2-1,3]†