The influence of solid micro-deformation on contact angle equilibrium

At a triple wetting line, the liquid-fluid tension may produce a wetting ridge in sufficiently soft solids. By employing variational methods, it has been shown that the solid strain combined with the Laplace pressure may modify contact angle equilibrium on a mesoscopic scale, situated between that of the molecular structure of the triple line and the macroscopic behavior observed in quotidian contact angle assessment. Young's equation remains perfectly valid in the latter regime. Some possible consequences are discussed.

[1]  Martin E. R. Shanahan,et al.  Equilibrium of liquid drops on thin plates; plate rigidity and stability considerations , 1987 .

[2]  M. Jhon,et al.  Contact angles on deformable solids , 1986 .

[3]  M. Shanahan Contact Angle Equilibrium on Thin Elastic Solids , 1985 .

[4]  D. Platikanov,et al.  Line tension of Newton black films. II. Determination by the diminishing bubble method , 1980 .

[5]  M. Fortes General Equations for the Equilibrium Shape of a Fluid Interface and for Its Angle of Contact with a Solid , 1980 .

[6]  A. I. Rusanov On the thermodynamics of deformable solid surfaces , 1978 .

[7]  A. W. Neumann,et al.  Generalization of the classical theory of capillarity , 1977 .

[8]  A. Kjekshus,et al.  Thermodynamics of Surface Phase Systems. VII. The Influence of Solid Surface Strain Changes on the Contact Angle Equilibrium and Some Further Comments on Adhesional Wetting Thermodynamics. , 1977 .

[9]  Lee R. White,et al.  On deviations from Young's equation , 1977 .

[10]  G. Jameson,et al.  Theory for the equilibrium contact angle between a gas, a liquid and a solid , 1976 .

[11]  W. B. Tolstogusow,et al.  Zur Frage des Kontaktwinkels des Flüssigkeitstropfens auf der Oberfläche deformierbarer Festkörper , 1973 .

[12]  G. R. Lester Contact Angles of Liquids on Organic Solids , 1966, Nature.

[13]  G. R. Lester Contact angles of liquids at deformable solid surfaces , 1961 .

[14]  Rulon E. Johnson Conflicts between Gibbsian Thermodynamics and Recent Treatments of Interfacial Energies in Solid-Liquid-Vapor , 1959 .

[15]  R. E. Collins,et al.  Fundamental basis for the contact angle and capillary pressure , 1959 .

[16]  A. Wangerin,et al.  Vorlesungen über die Theorie der Capillarität , 1894 .

[17]  T. Young III. An essay on the cohesion of fluids , 1805, Philosophical Transactions of the Royal Society of London.

[18]  Thomas Young,et al.  An Essay on the Cohesion of Fluids , 1800 .