The orientation relationships of nanobelt-like Si2Hf precipitates in an Al–Si–Mg–Hf alloy

The orientation relationships (ORs) between the Al matrix and Si2Hf precipitates with an orthorhombic structure in an Al–Si–Mg–Hf alloy after heat treatment at 833 K for 20 h were investigated by transmission electron microscopy and electron diffraction. Four ORs are identified as (100)Al||(010)p, (0\overline {1}1)Al||(101)p and [011]Al||[\overline {1}01]p; (11\overline {1})Al||(010)p and [011]Al||[\overline {1}01]p; (12\overline {1})Al||(010)p, (101)Al||(100)p and [1\overline {11}]Al||[001]p; (\overline {11}1)Al||(010)p and [112]Al||[\overline {1}01]p. The habit planes of these four ORs are rationalized by the fraction of good atomic matching sites at the interface. In addition, the formation of Si2Hf precipitates with a nanobelt-like morphology is interpreted on the basis of the near-coincident site lattice distribution.

[1]  T. Furuhara,et al.  PTCLab: free and open‐source software for calculating phase transformation crystallography , 2016 .

[2]  Qing Liu,et al.  Hafnium in Aluminum Alloys: A Review , 2016, Acta Metallurgica Sinica (English Letters).

[3]  Yanjun Li,et al.  Growth Directions of Precipitates in the Al–Si–Mg–Hf Alloy Using Combined EBSD and FIB 3D-Reconstruction Techniques , 2015, Microscopy and Microanalysis.

[4]  Xinquan Zhang,et al.  Formation of multiple orientation relationships of Q precipitates in Al–Mg–Si–Cu alloys , 2014 .

[5]  Wen-Zheng Zhang Calculation of Interfacial Dislocation Structures: Revisit to the O-lattice Theory , 2013, Metallurgical and Materials Transactions A.

[6]  F. Dai,et al.  Crystallography of Mg2Sn precipitates with two newly observed orientation relationships in an Mg–Sn–Mn alloy , 2012 .

[7]  Xiaopeng Yang,et al.  A systematic analysis of good matching sites between two lattices , 2012 .

[8]  A. M. Muggerud,et al.  Precipitation of partially coherent α-Al(Mn,Fe)Si dispersoids and their strengthening effect in AA 3003 alloy , 2012 .

[9]  L. Arnberg,et al.  Nanobelts in multicomponent aluminum alloys , 2008 .

[10]  Y. Takao,et al.  FEM analysis based on the 3D-NCS model for precipitate morphology in the BCC/HCP system , 2008 .

[11]  K. Ameyama,et al.  Preferred orientation relationship of intra- and inter-granular precipitates in titanium alloys , 2002 .

[12]  T. Furuhara,et al.  Interphase boundary structure with irrational orientation relationship formed in grain boundary precipitation , 2002 .

[13]  W. Reynolds,et al.  Determining interphase boundary orientations from near-coincidence sites , 1998 .

[14]  H. Aaronson,et al.  A computer modeling study of partially coherent f.c.c.:b.c.c. boundaries , 1979 .

[15]  N. Ryum Precipitation in an Al-1.78 wt % Hf alloy after rapid solidification , 1975 .

[16]  J. Smith,et al.  The structures of ZrGe2, HfSi2 and HfGe2 , 1957 .