Halide-bridged arsine- and phosphine-capped diruthenium complexes, [(R3As)3Ru(µ-X)3Ru(AsR3)3]+ and [(R3P)3Ru(µ-X)3Ru(PR3)3]+ (X = Cl or Br), as precursors to confacial mixed-valence ruthenium ‘blues’: spectroelectrochemical studies spanning the binuclear oxidation states II,II, II,III and III,III