Photoconductivity of bridged polymeric phthalocyanines

Results of experiments on photoconductivity of one-dimensional bridged polymeric phthalocyanines [PcML]n consisting of different combinations of macrocycles, Pc, bridging ligands, L, and central metal atoms, M, are described. It is shown that the spectral response and photoconductive gain strongly depend on the type of bridging the planar phthalocyanine rings. Therefore, rules for the development of phthalocyanine-based polymeric photoconductors by synthesis, e.g., with significant long wavelength sensitivity, can be outlined.

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