Chemical micropropulsion. State of the art and catalyst surface requirements.

Different propellant types (solid, cold and hot gas, liquid) proposed for micropropulsion systems are reviewed. Liquid-substrate surface interactions are discussed, focusing on surface tension, viscosity and contact angle. A comparison between molecular and ionic liquids is presented and their relationship to microfluidics. The use of hydrophobic or superhydrophobic surface is of interest for microchanneled devices by decreasing the pressure drop. Such surfaces could be developed inside honeycomb monolith and the channel size could be tuned in the submillimeter range by finely controlling the washcoat procedure. Any further development of this field needs microfluidics data. An ideal set-up for a chemical, catalytic microthruster based on a single monolithic channel is proposed.

[1]  A. V. Rao,et al.  Superhydrophobic silica aerogels based on methyltrimethoxysilane precursor , 2003 .

[2]  Steven F. Son,et al.  Novel High Nitrogen Propellant Use in Solid Fuel Micropropulsion , 2004 .

[3]  Henrik Kratz,et al.  A Hybrid Cold Gas Microthruster System for Spacecraft , 2002 .

[4]  Pamela J. Martin,et al.  Aggregation behavior of aqueous solutions of ionic liquids. , 2004, Langmuir : the ACS journal of surfaces and colloids.

[5]  Vigor Yang,et al.  Development of meso and micro scale liquid propellant thrusters , 2003 .

[6]  Martin Tajmar,et al.  Bi-Propellant Micro-Rocket Engine , 2004 .

[7]  Philip R. Watson,et al.  Surface Tension Measurements of N-Alkylimidazolium Ionic Liquids , 2001 .

[8]  Craig Underwood,et al.  Micropropulsion from Snap to PALMSAT: When Does MEMS Become the Way Forward? , 2002 .

[9]  Abraham Marmur,et al.  The Lotus effect: superhydrophobicity and metastability. , 2004, Langmuir : the ACS journal of surfaces and colloids.

[10]  J R Wilson Major new thrust for MEMS engines. , 2003, Aerospace America.

[11]  Adam Baker,et al.  Development of 50 - 100 milliNewton Level Thrusters for Low Cost Small Spacecraft , 2002 .

[12]  Siaw Kiang Chou,et al.  Development of a solid propellant microthruster with chamber and nozzle etched on a wafer surface , 2004 .

[13]  H. Matsumoto,et al.  Low-Viscous, Low-Melting, Hydrophobic Ionic Liquids: 1-Alkyl-3-methylimidazolium Trifluoromethyltrifluoroborate , 2004 .

[14]  Zhou Zhaoying,et al.  A homogeneously catalyzed micro-chemical thruster , 2003 .

[15]  Zhaoying Zhou,et al.  A vaporizing water micro-thruster , 2000, Proceedings IEEE Thirteenth Annual International Conference on Micro Electro Mechanical Systems (Cat. No.00CH36308).

[16]  E. Furlong,et al.  MEMS-based pulse detonation engine for small-scale propulsion applicationsMEMS-based pulse detonation engine for small-scale propulsion applications , 2001 .

[17]  Norman Chigier,et al.  A Review of Micro Propulsion Technology , 2003 .

[18]  Henggao Ding,et al.  Study of a vaporizing water micro-thruster , 2001 .

[19]  N. Miki,et al.  Development of a catalytic silicon micro-combustor for hydrocarbon-fueled power MEMS , 2002, Technical Digest. MEMS 2002 IEEE International Conference. Fifteenth IEEE International Conference on Micro Electro Mechanical Systems (Cat. No.02CH37266).

[20]  Norihisa Miki,et al.  Preliminary development of a hydrocarbon-fueled catalytic micro-combustor ☆ , 2003 .

[21]  B. Reed Decomposing Solid Micropropulsion Performance Issues , 2003 .

[22]  Neelesh A Patankar,et al.  Mimicking the lotus effect: influence of double roughness structures and slender pillars. , 2004, Langmuir : the ACS journal of surfaces and colloids.

[23]  Ian A. Waitz,et al.  High Power Density Silicon Combustion Systems for Micro Gas Turbine Engines , 2003 .

[24]  C. Rossi,et al.  Micropropulsion for Space — A Survey of MEMS‐based Micro Thrusters and their Solid Propellant Technology , 2002 .

[25]  S. Baldelli,et al.  Influence of water on the surface of hydrophilic and hydrophobic room-temperature ionic liquids. , 2004, Journal of the American Chemical Society.

[26]  Neelesh A Patankar,et al.  Transition between superhydrophobic states on rough surfaces. , 2004, Langmuir : the ACS journal of surfaces and colloids.

[27]  Shu Yang,et al.  From rolling ball to complete wetting: the dynamic tuning of liquids on nanostructured surfaces. , 2004, Langmuir : the ACS journal of surfaces and colloids.

[28]  W. Liou,et al.  AIAA 2001-3074 Predictions of MEMS Flow and Heat Transfer Using DSMC with Implicit Boundary Conditions , 2001 .

[29]  C. Sung,et al.  Catalyzed Combustion of Bipropellants for Micro-Spacecraft Propulsion , 2003 .

[30]  Carole Rossi,et al.  Design, fabrication and modeling of solid propellant microrocket-application to micropropulsion , 2002 .

[31]  M. Kilter,et al.  Micropropulsion Technologies for the European High-Precision Formation Flying Interferometer DARWIN , 2004 .

[32]  Jin Zhai,et al.  Reversible wettability of a chemical vapor deposition prepared ZnO film between superhydrophobicity and superhydrophilicity. , 2004, Langmuir : the ACS journal of surfaces and colloids.

[33]  Antonella Ingenito,et al.  Using Aluminum for Space Propulsion , 2004 .

[34]  Manuel Martinez-Sanchez,et al.  Externally Wetted Ionic Liquid Thruster , 2004 .

[35]  Carole Rossi,et al.  Prediction of the performance of a Si-micromachined microthruster by computing the subsonic gas flow inside the thruster , 2000 .

[36]  Zhang Gaofei,et al.  MEMS-based propulsion arrays with solid propellant , 2004 .

[37]  Denis Lagrange,et al.  Final characterizations of MEMS-based pyrotechnical microthrusters , 2005 .