The effects of high pressure and high temperature on some physical properties of ocean sediments

A series of laboratory experiments was conducted with four ocean sediments, two biogenic oozes and two clays. Permeability and thermal conductivity were directly measured as a function of porosity, and the testing program was designed to identify any dependence of these physical properties upon hydrostatic pressure and temperature. The results show no discernible effects of pressure, within the range of 2–60 MPa, upon the permeability of any of the samples. Temperature effects, from 22° to 220°C, upon this property are accounted for by applying a viscosity correction to the permeating seawater. Previous investigations have suggested the existence of a pressure-induced and/or a temperature-induced breakdown of the absorbed water which surrounds clay particles, thereby promoting an increase in sediment permeability. Our experimental findings cannot confirm this phenomenon and fail to provide a satisfactory solution to the conflicting data which now exist between the pore water velocities inferred from nonlinear thermal profiles of ocean sediments and those fluid velocities derived from Darcy's law and laboratory permeability data. The effects of sizeable variations in pressure and temperature upon sediment thermal conductivity are found to reflect closely the behavior of the conductivity of the liquid phase alone under these same changes in environmental conditions. This is not surprising due to the relatively narrow range of high porosities encountered in this study. Empirical equations are developed which allow sediment thermal conductivity to be calculated as a function of temperature and void ratio. A hydrostatic pressure correction term is also presented.

[1]  B. Herman,et al.  Heat transfer in the oceanic crust of the Brazil Basin , 1981 .

[2]  E. Ratcliffe The thermal conductivities of ocean sediments , 1960 .

[3]  W. Schwartz Gunnar Larsen and George V. Chilingar, Diagenesis in Sediments (Developments in Sedimentology Vol. 8). 551 S., 146 Abb., 45 Tab., 1 Taf., Amsterdam‐London‐New York 1967: Elsevier Publ. Co. Dfl 87.50 , 1969 .

[4]  W. Menke,et al.  Evidence for excess pore pressures in southwest Indian Ocean sediments , 1981 .

[5]  Percy Williams Bridgman,et al.  The physics of high pressure , 1931 .

[6]  R. Horne The physical chemistry and structure of sea water , 1965 .

[7]  David L. Williams,et al.  A major geothermal anomaly in the Gulf of California , 1975, Nature.

[8]  James K. Mitchell,et al.  Fundamentals of soil behavior , 1976 .

[9]  J. Bear Dynamics of Fluids in Porous Media , 1975 .

[10]  H. Clark,et al.  The thermal conductivity of rocks and its dependence upon temperature and composition; Part II , 1940 .

[11]  William R. Bryant,et al.  Permeability of Unconsolidated and Consolidated Marine Sediments, Gulf of Mexico , 1975 .

[12]  David L. Williams,et al.  The Galapagos Spreading Center at 86°W: A detailed geothermal field study , 1981 .

[13]  W. Seyfried,et al.  Hydrothermal chemistry of seawater from 25 degrees to 350 degrees C , 1978 .

[14]  S. D. Hamann Physico-chemical effects of pressure , 1957 .

[15]  Roger N. Anderson,et al.  Geothermal Convection Through Oceanic Crust and Sediments in the Indian Ocean , 1979, Science.

[16]  D. Zasłavsky,et al.  The Water Pressure in the Electrical Double Layer , 1972 .

[17]  H. Olphen An Introduction to Clay Colloid Chemistry , 1977 .

[18]  David L. Williams,et al.  The Galapagos Spreading Centre: Lithospheric Cooling and Hydrothermal Circulation , 1974 .

[19]  G. R. Hadley,et al.  Thermophysical properties of deep ocean sediments , 1984 .

[20]  A. E. Maxwell,et al.  The measurement of thermal conductivity of deep‐sea sediments by a needle‐probe method , 1959 .

[21]  O. Stern ZUR THEORIE DER ELEKTROLYTISCHEN DOPPELSCHICHT , 1924, Zeitschrift für Elektrochemie und angewandte physikalische Chemie.

[22]  E. Verwey,et al.  Theory of the stability of lyophobic colloids. , 1955, The Journal of physical and colloid chemistry.

[23]  D. R. Anderson,et al.  Report to the Radioactive Waste Management Committee on the first international workshop on seabed disposal of high-level wastes, Woods Hole, Massachusetts, February 16--20, 1976 , 1976 .

[24]  S. Brinkley,et al.  The Effect of Pressure upon the Dielectric Constants of Liquids , 1943 .

[25]  J. Keenan Steam tables : thermodynamic properties of water including vapor, liquid, and solid phases : International System of units--S.I. , 1969 .

[26]  C. E. Weaver Geothermal alteration of clay minerals and shales: diagenesis , 1979 .

[27]  E. Davis,et al.  Heat flow measured over the Juan de Fuca Ridge: Evidence for widespread hydrothermal circulation in a highly heat transportive crust , 1977 .

[28]  W. Zisman The Effect of Pressure on the Electrical Conductance of Salt Solutions in Water , 1932 .

[29]  M. Langseth Towards a submarine hydrology , 1980, Nature.

[30]  G. Bolt,et al.  Analysis of the validity of the Gouy-Chapman theory of the electric double layer , 1955 .

[31]  D. Mason,et al.  The Thermal Conductivities of Mg2Si and Mg2Ge , 1963 .

[32]  J. F. Burst,et al.  Diagenesis of Gulf Coast Clayey Sediments and Its Possible Relation to Petroleum Migration , 1966 .

[33]  K. Macdonald,et al.  Temperature coefficient of the thermal conductivities of ocean sediments , 1972 .

[34]  Joseph E. Bowles,et al.  Engineering Properties of Soils and Their Measurement , 1978 .

[35]  J. Jaeger,et al.  The measurement of thermal conductivity and diffusivity with cylindrical probes , 1958 .

[36]  D. Calnan,et al.  Low-Gradient Permeability Testing of Fine-Grained Marine Sediments , 1981 .

[37]  P. H. Roth,et al.  Experimental Evidence for the Selective Dissolution and Overgrowth of Calcareous Nannofossils During Diagenesis , 1973 .

[38]  K. Horai,et al.  Thermal conductivity of rock‐forming minerals , 1971 .

[39]  R. Lowell,et al.  Thermal Conductivity of Water at High Pressures , 1959 .