Exact Large Deviation Functional of a Stationary Open Driven Diffusive System: The Asymmetric Exclusion Process

AbstractWe consider the asymmetric exclusion process (ASEP) in one dimension on sites i=1,...,N, in contact at sites i=1 and i=N with infinite particle reservoirs at densities ρa and ρb. As ρa and ρb are varied, the typical macroscopic steady state density profile ¯ρ(x), x∈[a,b], obtained in the limit N=L(b−a)→∞, exhibits shocks and phase transitions. Here we derive an exact asymptotic expression for the probability of observing an arbitrary macroscopic profile $$\rho (x):{\text{ }}P_N (\{ \rho (x)\} ) \sim \exp [ - L\mathcal{F}_{[a,b]} (\{ \rho (x)\} ;\rho _a ,\rho _b )]$$ , so that $$\mathcal{F}$$ is the large deviation functional, a quantity similar to the free energy of equilibrium systems. We find, as in the symmetric, purely diffusive case q=1 (treated in an earlier work), that $$\mathcal{F}$$ is in general a non-local functional of ρ(x). Unlike the symmetric case, however, the asymmetric case exhibits ranges of the parameters for which $$\mathcal{F}(\{ \rho (x)\} )$$ is not convex and others for which $$\mathcal{F}(\{ \rho (x)\} )$$ has discontinuities in its second derivatives at ρ(x)=¯ρ(x). In the latter ranges the fluctuations of order $$1/\sqrt N $$ in the density profile near ¯ρ(x) are then non-Gaussian and cannot be calculated from the large deviation function.

[1]  Fabian H.L. Essler,et al.  Representations of the quadratic algebra and partially asymmetric diffusion with open boundaries , 1995 .

[2]  Eytan Domany,et al.  An exact solution of a one-dimensional asymmetric exclusion model with open boundaries , 1992 .

[3]  Stefano Olla,et al.  Large deviations for Gibbs random fields , 1988 .

[4]  E. Domany,et al.  Phase transitions in an exactly soluble one-dimensional exclusion process , 1993, cond-mat/9303038.

[5]  T. Liggett,et al.  Stochastic Interacting Systems: Contact, Voter and Exclusion Processes , 1999 .

[6]  Krug,et al.  Boundary-induced phase transitions in driven diffusive systems. , 1991, Physical review letters.

[7]  W. B. Li,et al.  Concentration Fluctuations in a Polymer Solution under a Temperature Gradient , 1998 .

[8]  K. Mallick,et al.  Shocks in the asymmetry exclusion model with an impurity , 1996 .

[9]  Beate Schmittmann,et al.  Statistical mechanics of driven diffusive systems , 1995 .

[10]  Bernard Derrida,et al.  Exact diffusion constant for one-dimensional asymmetric exclusion models , 1993 .

[11]  V. Popkov,et al.  Steady-state selection in driven diffusive systems with open boundaries , 1999, cond-mat/0002242.

[12]  Herbert Spohn,et al.  Long range correlations for stochastic lattice gases in a non-equilibrium steady state , 1983 .

[13]  T. R. Kirkpatrick,et al.  Generic Long-Range Correlations in Molecular Fluids , 1994 .

[14]  Tomohiro Sasamoto One-dimensional partially asymmetric simple exclusion process with open boundaries: Orthogonal polynomials approach , 2001 .

[15]  B. Derrida,et al.  Large Deviation of the Density Profile in the Symmetric Simple Exclusion Process , 2001 .

[16]  H. Spohn Large Scale Dynamics of Interacting Particles , 1991 .

[17]  P. Mazur,et al.  Non-equilibrium thermodynamics, , 1963 .

[18]  M. Cross,et al.  Pattern formation outside of equilibrium , 1993 .

[19]  B. Derrida,et al.  Exact solution of a 1d asymmetric exclusion model using a matrix formulation , 1993 .

[20]  E. R. Speer,et al.  Large Deviation of the Density Profile in the Steady State of the Open Symmetric Simple Exclusion Process , 2002 .

[21]  R Schmitz,et al.  FLUCTUATIONS IN NONEQUILIBRIUM FLUIDS , 1988 .

[22]  S K Pogosyan,et al.  Large deviations for Gibbs random fields , 1981 .

[23]  Stefano Olla,et al.  Hydrodynamics and large deviation for simple exclusion processes , 1989 .

[24]  Bernard Derrida,et al.  Exact correlation functions in an asymmetric exclusion model with open boundaries , 1993 .

[25]  Ludger Santen,et al.  The Asymmetric Exclusion Process Revisited: Fluctuations and Dynamics in the Domain Wall Picture , 2001 .

[26]  J. Krug,et al.  Minimal current phase and universal boundary layers in driven diffusive systems. , 2001, Physical review. E, Statistical, nonlinear, and soft matter physics.

[27]  R. A. Blythe,et al.  Exact solution of a partially asymmetric exclusion model using a deformed oscillator algebra , 2000 .

[28]  R. Ellis,et al.  Entropy, large deviations, and statistical mechanics , 1985 .

[29]  B. Derrida,et al.  Free energy functional for nonequilibrium systems: an exactly solvable case. , 2001, Physical review letters.

[30]  S. Sandow,et al.  Partially asymmetric exclusion process with open boundaries. , 1994, Physical review. E, Statistical physics, plasmas, fluids, and related interdisciplinary topics.

[31]  C. Landim,et al.  Fluctuations in stationary nonequilibrium states of irreversible processes. , 2001, Physical review letters.

[32]  C. Landim,et al.  Macroscopic Fluctuation Theory for Stationary Non-Equilibrium States , 2001, cond-mat/0108040.

[33]  Maury Bramson Front propagation in certain one-dimensional exclusion models , 1988 .

[34]  Sven Sandow,et al.  Finite-dimensional representations of the quadratic algebra: Applications to the exclusion process , 1997 .

[35]  B Derrida,et al.  Exact free energy functional for a driven diffusive open stationary nonequilibrium system. , 2002, Physical review letters.