Evaluation of anodic TA2O5 as the dielectric layer for EWOD devices

We report that anodic tantalum pentoxide (Ta2O5) exhibits severe polarity and frequency dependencies that, when used as the dielectric material for electrowetting on dielectric (EWOD) devices, in many cases result in long-term performance that is worse than when conventional dielectrics (e.g., SiO2) are used. This rather disappointing news is nevertheless relevant to the community and calls for critical assessment. Here, we find that under direct current (DC) actuation Ta2O5 is attractive for EWOD only if the droplet is negatively biased, and that under alternating current (AC) it is acceptable only for low frequencies.

[1]  R. F. Schwarz,et al.  Ion size effect and mechanism of electrolytic rectification , 1960 .

[2]  D. Muth Ellipsometer Study of Anodic Oxides Formed on Sputtered Tantalum and Tantalum–Aluminum Alloy Films , 1969 .

[3]  L. Young Anodization Constants for Tantalum , 1977 .

[4]  H. Groult,et al.  Dielectric properties of anodic oxide films on tantalum , 1995 .

[5]  C. Kim,et al.  Electrowetting and electrowetting-on-dielectric for microscale liquid handling , 2002 .

[6]  S. Cho,et al.  Low voltage electrowetting-on-dielectric , 2002 .

[7]  Jeong‐Yeol Yoon,et al.  Preventing Biomolecular Adsorption in Electrowetting-Based Biofluidic Chips. , 2003, Analytical chemistry.

[8]  김준원,et al.  EWOD(Electrowetting-on-Dielectric) ACTUATED OPTICAL MICROMIRROR , 2006 .

[9]  Chih-Sheng Yu,et al.  Electrowetting-Based Total Internal Reflection Chip for Optical Switch and Display , 2007, IEEE/LEOS International Conference on Optical MEMS and Their Applications Conference.

[10]  Richard B. Fair,et al.  Digital microfluidics: is a true lab-on-a-chip possible? , 2007 .

[11]  J. Stevenson,et al.  Room-Temperature Fabrication of Anodic Tantalum Pentoxide for Low-Voltage Electrowetting on Dielectric (EWOD) , 2008, Journal of Microelectromechanical Systems.

[12]  P. Sen,et al.  A Fast Liquid-Metal Droplet Microswitch Using EWOD-Driven Contact-Line Sliding , 2009, Journal of microelectromechanical systems.

[13]  C. Kim,et al.  A micro extensional filament rheometer enabled by EWOD , 2010, IEEE/LEOS International Conference on Optical MEMS.