The efficacy of heating low-pressure H2 in a microwave discharge

The relative ease with which a low-pressure hydrogen stream may be heated in an electrical discharge suggests that such a system be considered in current efforts to develop thrusters for spacecraft orbit raising purposes. In this work a detailed model of a microwave discharge in flowing, low-pressure hydrogen is used to interpret and clarify experimental measurements of atom concentration, electron energy, and electron density. The radially averaged, constant-pressure model accurately reproduces the experimental data and also calculated the rates of a number of gas-heating and wall-heating processes as well as rates of energy deposition into coolant and working fluid streams. The calculated gas-heating rates indicate that the gas heating is due primarily to the thermalization of the energetic atoms produced by dissociation of H2 via excitation of theb3∑u+ state. The calculations also indicate that the energy flux to the quartz tube is significantly influenced by Lyman and Werner band radiation and by heterogeneous atomic recombination processes and, to a much lesser degree, by electron-ion recombination processes. The fraction of power input which is ultimately transferred to the gas stream is a decreasing function of the power input and varies from 0.24 to 0.12.

[1]  H. G. Poole Atomic Hydrogen. I. The Calorimetry of Hydrogen Atoms , 1937 .

[2]  S. Corrigan Dissociation of Molecular Hydrogen by Electron Impact , 1965 .

[3]  Y. Yung,et al.  Laboratory studies of uv emissions of H2 by electron impact. The Werner- and Lyman-band systems , 1982 .

[4]  E. Ekinci,et al.  Hydrogen Dissociation in a Microwave Discharge , 1977 .

[5]  H. Brunet,et al.  Properties of the positive column of a glow discharge in flowing hydrogen , 1981 .

[6]  W. Fite,et al.  COLLISIONS OF ELECTRONS WITH HYDROGEN ATOMS. III. ELASTIC SCATTERING , 1958 .

[7]  M. Capitelli,et al.  A joint vibro-electronic mechanism in the dissociation of molecular hydrogen in nonequilibrium plasmas , 1978 .

[8]  H. P. Broida,et al.  Microwave Discharge Cavities Operating at 2450 MHz , 1964 .

[9]  M. Hawley,et al.  Measurement of energy distribution in flowing hydrogen microwave plasmas , 1985 .

[10]  D. Rapp,et al.  Total Cross Sections for Ionization and Attachment in Gases by Electron Impact. I. Positive Ionization , 1965 .

[11]  R. J. Spindler Franck-Condon factors for band systems of molecular hydrogen. I. , 1969 .

[12]  W. Fite,et al.  COLLISIONS OF ELECTRONS WITH HYDROGEN ATOMS. II. EXCITATION OF LYMAN-ALPHA RADIATION , 1958 .

[13]  R. E. Roberts,et al.  Classical mechanics of recombination via the resonance complex mechanism: H + H + M → H2 + M for M = H, H2, He, and Ar , 1974 .

[14]  W. Stwalley The dissociation energy of the hydrogen molecule using long-range forces , 1970 .

[15]  J. Kasper,et al.  An experimental rate constant for H + H2 (ν″ = 1) → H + H2 (ν″ = 0) , 1972 .

[16]  J. Ducuing,et al.  Vibrational relaxation of ortho and para-H2 in the range 400-50 K , 1975 .

[17]  W. Sharp,et al.  Angular distributions of electrons elastically scattered from H 2 , 1981 .

[18]  Shoon-Kyung Kim,et al.  Theory of Atomic Recombination on Surfaces , 1971 .