Nutrient Inputs to the Laurentian Great Lakes by Source and Watershed Estimated Using SPARROW Watershed Models1

Abstract Nutrient input to the Laurentian Great Lakes continues to cause problems with eutrophication. To reduce the extent and severity of these problems, target nutrient loads were established and Total Maximum Daily Loads are being developed for many tributaries. Without detailed loading information it is difficult to determine if the targets are being met and how to prioritize rehabilitation efforts. To help address these issues, SPAtially Referenced Regressions On Watershed attributes (SPARROW) models were developed for estimating loads and sources of phosphorus (P) and nitrogen (N) from the United States (U.S.) portion of the Great Lakes, Upper Mississippi, Ohio, and Red River Basins. Results indicated that recent U.S. loadings to Lakes Michigan and Ontario are similar to those in the 1980s, whereas loadings to Lakes Superior, Huron, and Erie decreased. Highest loads were from tributaries with the largest watersheds, whereas highest yields were from areas with intense agriculture and large point sources of nutrients. Tributaries were ranked based on their relative loads and yields to each lake. Input from agricultural areas was a significant source of nutrients, contributing ∼33-44% of the P and ∼33-58% of the N, except for areas around Superior with little agriculture. Point sources were also significant, contributing ∼14-44% of the P and 13-34% of the N. Watersheds around Lake Erie contributed nutrients at the highest rate (similar to intensively farmed areas in the Midwest) because they have the largest nutrient inputs and highest delivery ratio.

[1]  David M. Wolock,et al.  STATSGO soil characteristics for the conterminous United States , 1997 .

[2]  Molly A Maupin,et al.  Nutrient Loadings to Streams of the Continental United States from Municipal and Industrial Effluent1 , 2011, Journal of the American Water Resources Association.

[3]  Gregory E Schwarz,et al.  Incorporating Uncertainty Into the Ranking of SPARROW Model Nutrient Yields From Mississippi/Atchafalaya River Basin Watersheds1 , 2009, Journal of the American Water Resources Association.

[4]  Myint Tin Comparison of Some Ratio Estimators , 1965 .

[5]  J. Depinto,et al.  Impact of phosphorus availability on modelling phytoplankton dynamics , 1986, Hydrobiological Bulletin.

[6]  David L. Lorenz,et al.  County-level estimates of nutrient inputs to the landsurface of the conterminous United States, 1982-2001 , 2006 .

[7]  Anne B. Hoos,et al.  Spatial analysis of instream nitrogen loads and factors controlling nitrogen delivery to streams in the southeastern United States using spatially referenced regression on watershed attributes (SPARROW) and regional classification frameworks , 2009 .

[8]  Robert Perciasepe,et al.  National Strategy For The Development Of Regional Nutrient Criteria , 1998 .

[9]  E. Elliott,et al.  Nitrogen isotopes as indicators of NO(x) source contributions to atmospheric nitrate deposition across the midwestern and northeastern United States. , 2007, Environmental science & technology.

[10]  T. Lavery,et al.  Estimates of the atmospheric deposition of sulfur and nitrogen species: Clean Air Status and Trends Network 1990-2000. , 2002, Environmental science & technology.

[11]  Mark B. David,et al.  Dynamic modeling of nitrogen losses in river networks unravels the coupled effects of hydrological and biogeochemical processes , 2009 .

[12]  D. Robertson Regionalized loads of sediment and phosphorus to lakes Michigan and Superior—high flow and long-term average , 1997 .

[13]  Thomas M. Isenhart,et al.  Optimizing the placement of riparian practices in a watershed using terrain analysis , 2003 .

[14]  M. V. Vander Zanden,et al.  Nitrogen stable isotopes in streams: effects of agricultural sources and transformations. , 2009, Ecological applications : a publication of the Ecological Society of America.

[15]  JW Brakebill,et al.  Digital Hydrologic Networks Supporting Applications Related to Spatially Referenced Regression Modeling1 , 2011, Journal of the American Water Resources Association.

[16]  J. Vallentyne Algal bowl; lakes and man , 1974 .

[17]  D. Robertson,et al.  Water Quality and Hydrology of Whitefish (Bardon) Lake, Douglas County, Wisconsin, With Special Emphasis on Responses of an Oligotrophic Seepage Lake to Changes in Phosphorus Loading and Water Level , 2009 .

[18]  Gregory E Schwarz,et al.  Differences in phosphorus and nitrogen delivery to the Gulf of Mexico from the Mississippi River Basin. , 2008, Environmental science & technology.

[19]  Gregory E Schwarz,et al.  A Multi-Agency Nutrient Dataset Used to Estimate Loads, Improve Monitoring Design, and Calibrate Regional Nutrient SPARROW Models1 , 2011, Journal of the American Water Resources Association.

[20]  N. Duan Smearing Estimate: A Nonparametric Retransformation Method , 1983 .

[21]  S. Effler,et al.  Phosphorus Bioavailability and P-Cycling in Cannonsville Reservoir , 1998 .

[22]  Kenneth H. Reckhow,et al.  Nonlinear regression modeling of nutrient loads in streams: A Bayesian approach , 2005 .

[23]  ``Nutrient Inputs to the Laurentian Great Lakes by Source and Watershed Estimated Using SPARROW Watershed Models'' by Dale M. Robertson and David A. Saad2 , 2013 .

[24]  Pixie A. Hamilton,et al.  SPARROW MODELING - Enhancing Understanding of the Nation's Water Quality , 2009 .

[25]  Andrew N. Sharpley,et al.  The Transport of Bioavailable Phosphorus in Agricultural Runoff , 1992 .

[26]  Amy S. Ludtke,et al.  Data from selected U.S. Geological Survey National Stream Water Quality Monitoring Networks , 1998 .

[27]  Richard A. Smith,et al.  Section 3. The SPARROW Surface Water-Quality Model: Theory, Application and User Documentation , 2006 .

[28]  David A. Kovacic,et al.  Nitrogen Balance in and Export from an Agricultural Watershed , 1997 .

[29]  Melvin J. Dubnick Army Corps of Engineers , 1998 .

[30]  J. Brakebill,et al.  Application of spatially referenced regression modeling for the evaluation of total nitrogen loading in the Chesapeake Bay watershed , 1999 .

[31]  Kevin P. McGunagle,et al.  Lake Erie Total Phosphorus Loading Analysis and Update: 1996–2002 , 2005 .

[32]  Gertrud K. Nürnberg,et al.  Quantifying anoxia in lakes , 1995 .

[33]  James R. Bence,et al.  Dynamics of the Lake Michigan food web, 1970-2000 , 2002 .

[34]  C. Neal,et al.  Quantifying phosphorus retention and release in rivers and watersheds using extended end-member mixing analysis (E-EMMA). , 2011, Journal of environmental quality.

[35]  F. P. Kapinos,et al.  Hydrologic unit maps , 1987 .

[36]  Jean-Francois Lamarque,et al.  NITROGEN DEPOSITION ONTO THE UNITED STATES AND WESTERN EUROPE: SYNTHESIS OF OBSERVATIONS AND MODELS , 2005 .

[37]  D. Baker,et al.  Trends in agriculture in the LEASEQ watersheds, 1975-1995. Lake Erie Agricultural Systems for Environmental Quality. , 2002, Journal of environmental quality.

[38]  B. Lesht,et al.  Great Lakes Total Phosphorus Model: Post Audit and Regionalized Sensitivity Analysis , 1991 .

[39]  G. Mcrae,et al.  Great Lakes Water Quality Board. Report on Great Lakes Water Quality. 1987 Appendix B Great Lakes Surveillance Volume 2 , 1989 .

[40]  Dale M Robertson,et al.  Linkages Between Nutrients and Assemblages of Macroinvertebrates and Fish in Wadeable Streams: Implication to Nutrient Criteria Development , 2007, Environmental management.

[41]  D. Schindler Evolution of phosphorus limitation in lakes. , 1977, Science.

[42]  Seungbong Han,et al.  Landscape Planning for Agricultural Nonpoint Source Pollution Reduction III: Assessing Phosphorus and Sediment Reduction Potential , 2009, Environmental management.

[43]  G. McMahon,et al.  Methods for Estimating Annual Wastewater Nutrient Loads in the Southeastern United States , 2007 .

[44]  Scott C. Martin,et al.  Algal-Available Phosphorus in Suspended Sediments from Lower Great Lakes Tributaries , 1981 .

[45]  J. Selegean,et al.  Assessing Sediment Loading from Agricultural Croplands in the Great Lakes Basin , 2005 .

[46]  Gregory E. Schwarz,et al.  Regional interpretation of water‐quality monitoring data , 1997 .

[47]  D. Baker,et al.  Phosphorus budgets and riverine phosphorus export in northwestern Ohio watersheds. , 2002, Journal of environmental quality.

[48]  Anne B. Hoos,et al.  Data to support statistical modeling of instream nutrient load based on watershed attributes, southeastern United States, 2002 , 2008 .

[49]  T. Young Algal-availability of particulate phosphorus from diffuse and point sources in the lower Great Lakes basin , 1982, Hydrobiologia.