Integrating cavity absorption meter.

Scattering effects have always been an important systematic problem in absorption measurements. A new integrating cavity absorption meter has been developed that, in principle, is rigorously independent of scattering effects. The theoretical basis for this integrating cavity device is developed and applied to a generic experimental device: a one-dimensional model is described that demonstrates qualitatively the observed deviations from ideal; details of an actual device are provided; and experimental results for the absorption coefficient of aqueous solutions with various absorptions and with various concentrations of scatterers are presented.

[1]  C. Patel,et al.  Optical absorptions of light and heavy water by laser optoacoustic spectroscopy. , 1979, Applied optics.

[2]  M. Hass,et al.  Measurement of very low absorption coefficients by laser calorimetry. , 1975, Applied optics.

[3]  Dale A. Kiefer,et al.  Spectral absorption by marine particles of coastal waters of Baja California1 , 1982 .

[4]  G. Plass,et al.  Interior radiances in optically deep absorbing media—I Exact solutions for one-dimensional model , 1973 .

[5]  Helmut Maske,et al.  Specific in vivo absorption coefficient of chlorophyll a at 675 nm , 1987 .

[6]  K. M. Adams,et al.  Real-time, in situ measurements of atmospheric optical absorption in the visible via photoacoustic spectroscopy—II. Validation for atmospheric elemental carbon aerosol , 1989 .

[7]  Annick Bricaud,et al.  Optical efficiency factors of some phytoplankters1 , 1983 .

[8]  E. Hulburt,et al.  Optics of distilled and natural water. , 1945, Journal of the Optical Society of America.

[9]  P Elterman Integrating cavity spectroscopy. , 1970, Applied optics.

[10]  S. Warren,et al.  Aerosol light absorption measurement techniques: Analysis and intercomparisons , 1967 .

[11]  M. Querry,et al.  Split-pulse laser method for measuring attenuation coefficients of transparent liquids: application to deionized filtered water in the visible region. , 1978, Applied optics.

[12]  Edward S. Fry,et al.  Integrating cavity absorption meter: measurement results , 1990, Defense, Security, and Sensing.

[13]  Edward S. Fry,et al.  Measurement Of The Absorption Coefficient Of Ocean Water Using Isotropic Illumination , 1988, Defense, Security, and Sensing.

[14]  H. Maske,et al.  Quantitative in vivo absorption spectra of phytoplankton: Detrital absorption and comparison with fluorescence excitation spectra' , 1987 .

[15]  G. Plass,et al.  Matrix operator theory of radiative transfer. 1: rayleigh scattering. , 1973, Applied optics.

[16]  J. Heintzenberg Size-segregated measurements of particulate elemental carbon and aerosol light absorption at remote arctic locations , 1982 .

[17]  C. Yentsch,et al.  Use of glass fiber filters for the rapid preparation of in vivo absorption spectra of photosynthetic bacteria , 1967, Journal of bacteriology.

[18]  J. Stone,et al.  Measurements of the Absorption of Light in Low-Loss Liquids , 1972 .

[19]  A. Clarke Integrating sandwich: a new method of measurement of the light absorption coefficient for atmospheric particles. , 1982, Applied optics.