Guest-dependent pressure induced gate-opening effect enables effective separation of propene and propane in a flexible MOF

[1]  Chongxiong Duan,et al.  Efficient adsorptive separation of C3H6 over C3H8 on flexible and thermoresponsive CPL-1 , 2017 .

[2]  R. Krishna,et al.  Efficient separation of ethylene from acetylene/ethylene mixtures by a flexible-robust metal–organic framework , 2017 .

[3]  R. Krishna.  Screening metal–organic frameworks for mixture separations in fixed-bed adsorbers using a combined selectivity/capacity metric , 2017 .

[4]  R. Krishna,et al.  Flexible-Robust Metal-Organic Framework for Efficient Removal of Propyne from Propylene. , 2017, Journal of the American Chemical Society.

[5]  Wei Zhou,et al.  Optimized Separation of Acetylene from Carbon Dioxide and Ethylene in a Microporous Material. , 2017, Journal of the American Chemical Society.

[6]  T. Maji,et al.  Separation/purification of ethylene from an acetylene/ethylene mixture in a pillared-layer porous metal-organic framework. , 2017, Chemical communications.

[7]  P. Sozzani,et al.  Recognition of 1,3-Butadiene by a Porous Coordination Polymer. , 2016, Angewandte Chemie.

[8]  R. Krishna,et al.  Flexible Metal–Organic Frameworks with Discriminatory Gate‐Opening Effect for the Separation of Acetylene from Ethylene/Acetylene Mixtures , 2016 .

[9]  M. Eddaoudi,et al.  A metal-organic framework–based splitter for separating propylene from propane , 2016, Science.

[10]  Ryan P. Lively,et al.  Seven chemical separations to change the world , 2016, Nature.

[11]  R. Krishna,et al.  Exploiting the gate opening effect in a flexible MOF for selective adsorption of propyne from C1/C2/C3 hydrocarbons , 2016 .

[12]  Craig M. Brown,et al.  Methane storage in flexible metal–organic frameworks with intrinsic thermal management , 2015, Nature.

[13]  Wei‐Xiong Zhang,et al.  Efficient purification of ethene by an ethane-trapping metal-organic framework , 2015, Nature Communications.

[14]  R. Krishna.  Methodologies for evaluation of metal–organic frameworks in separation applications , 2015 .

[15]  R. Krishna,et al.  Microporous metal–organic framework with dual functionalities for highly efficient removal of acetylene from ethylene/acetylene mixtures , 2015, Nature Communications.

[16]  R. Krishna,et al.  Transient breakthroughs of CO2/CH4 and C3H6/C3H8 mixtures in fixed beds packed with Ni-MOF-74 , 2014 .

[17]  Zu-Jin Lin,et al.  Metal-organic frameworks based on flexible ligands (FL-MOFs): structures and applications. , 2014, Chemical Society reviews.

[18]  S. Kaskel,et al.  Flexible metal-organic frameworks. , 2014, Chemical Society reviews.

[19]  S. Sakaki,et al.  DRIFT and Theoretical Studies of Ethylene/Ethane Separation on Flexible and Microporous [Cu2(2,3-pyrazinedicarboxylate)2(pyrazine)]n: DRIFT and Theoretical Studies of Ethylene/Ethane Separation , 2014 .

[20]  S. Sakaki,et al.  DRIFT and Theoretical Studies of Ethylene/Ethane Separation on Flexible and Microporous [Cu2(2,3‐pyrazinedicarboxylate)2(pyrazine)]n , 2014 .

[21]  J. Möllmer,et al.  Structural flexibility of a copper-based metal–organic framework: sorption of C4-hydrocarbons and in situ XRD , 2014 .

[22]  Guanghua Li,et al.  Assembly of Two Flexible Metal–Organic Frameworks with Stepwise Gas Adsorption and Highly Selective CO2 Adsorption , 2014 .

[23]  R. Krishna.  The Maxwell–Stefan description of mixture diffusion in nanoporous crystalline materials , 2014 .

[24]  J. Caro,et al.  Ethene/ethane and propene/propane separation via the olefin and paraffin selective metal-organic framework adsorbents CPO-27 and ZIF-8. , 2013, Langmuir : the ACS journal of surfaces and colloids.

[25]  J. Long,et al.  Selective adsorption of ethylene over ethane and propylene over propane in the metal–organic frameworks M2(dobdc) (M = Mg, Mn, Fe, Co, Ni, Zn) , 2013 .

[26]  Kai-Jie Chen,et al.  Turning on the flexibility of isoreticular porous coordination frameworks for drastically tunable framework breathing and thermal expansion , 2013 .

[27]  Seth M. Cohen,et al.  Synthesis, breathing, and gas sorption study of the first isoreticular mixed-linker phosphonate based metal-organic frameworks. , 2013, Chemical communications.

[28]  X. You,et al.  Fine-tuning pore size by shifting coordination sites of ligands and surface polarization of metal-organic frameworks to sharply enhance the selectivity for CO2. , 2013, Journal of the American Chemical Society.

[29]  W. Zhou,et al.  Microporous metal-organic frameworks for storage and separation of small hydrocarbons. , 2012, Chemical communications.

[30]  Hong-Cai Zhou,et al.  Methane storage in advanced porous materials. , 2012, Chemical Society reviews.

[31]  J. Marrot,et al.  A lithium-organic framework with coordinatively unsaturated metal sites that reversibly binds water. , 2012, Chemical communications.

[32]  Qiang Zhao,et al.  Adsorption CO2, CH4 and N2 on two different spacing flexible layer MOFs , 2012 .

[33]  Y. Chabal,et al.  Tuning the gate opening pressure of Metal-Organic Frameworks (MOFs) for the selective separation of hydrocarbons. , 2012, Journal of the American Chemical Society.

[34]  A. Rodrigues,et al.  Propane/propylene separation by adsorption using shaped copper trimesate MOF , 2012 .

[35]  Jie Su,et al.  A Family of Flexible Lanthanide Bipyridinedicarboxylate Metal-Organic Frameworks Showing Reversible Single-Crystal to Single-Crystal Transformations , 2012 .

[36]  Andreas Schneemann,et al.  Directing the breathing behavior of pillared-layered metal-organic frameworks via a systematic library of functionalized linkers bearing flexible substituents. , 2012, Journal of the American Chemical Society.

[37]  A. Rodrigues,et al.  Propylene/propane separation by vacuum swing adsorption using Cu-BTC spheres , 2012 .

[38]  Rajamani Krishna,et al.  Hydrocarbon Separations in a Metal-Organic Framework with Open Iron(II) Coordination Sites , 2012, Science.

[39]  S. Nguyen,et al.  High propene/propane selectivity in isostructural metal-organic frameworks with high densities of open metal sites. , 2012, Angewandte Chemie.

[40]  Hong-Cai Zhou,et al.  Metal-organic frameworks for separations. , 2012, Chemical reviews.

[41]  F. Kapteijn,et al.  Understanding the anomalous alkane selectivity of ZIF-7 in the separation of light alkane/alkene mixtures. , 2011, Chemistry.

[42]  S. Nguyen,et al.  Kinetic separation of propene and propane in metal-organic frameworks: controlling diffusion rates in plate-shaped crystals via tuning of pore apertures and crystallite aspect ratios. , 2011, Journal of the American Chemical Society.

[43]  Alexandre F. P. Ferreira,et al.  Suitability of Cu-BTC extrudates for propane–propylene separation by adsorption processes , 2011 .

[44]  S. Kitagawa,et al.  Modification of flexible part in Cu(2+) interdigitated framework for CH(4)/CO(2) separation. , 2010, Chemical communications.

[45]  F. Kapteijn,et al.  Ethane/ethene separation turned on its head: selective ethane adsorption on the metal-organic framework ZIF-7 through a gate-opening mechanism. , 2010, Journal of the American Chemical Society.

[46]  D. Dubbeldam,et al.  Analysis of the ITQ-12 Zeolite Performance in Propane−Propylene Separations Using a Combination of Experiments and Molecular Simulations , 2010 .

[47]  C. Serre,et al.  Controlled reducibility of a metal-organic framework with coordinatively unsaturated sites for preferential gas sorption. , 2010, Angewandte Chemie.

[48]  Alírio E. Rodrigues,et al.  Vacuum Pressure Swing Adsorption to Produce Polymer-Grade Propylene , 2010 .

[49]  A. Rodrigues,et al.  Molecular simulation of propane/propylene separation on the metal-organic framework CuBTC , 2010 .

[50]  T. Nakagawa,et al.  Metal-ion-dependent gas sorptivity of elastic layer-structured MOFs. , 2009, Chemistry.

[51]  A. Rodrigues,et al.  Adsorption of propane, propylene and isobutane on a metal–organic framework: Molecular simulation and experiment , 2009 .

[52]  H. Noguchi,et al.  Elastic layer-structured metal organic frameworks (ELMs). , 2009, Journal of colloid and interface science.

[53]  Hong-Cai Zhou,et al.  Selective gas adsorption and separation in metal-organic frameworks. , 2009, Chemical Society reviews.

[54]  C. Serre,et al.  Large breathing effects in three-dimensional porous hybrid matter: facts, analyses, rules and consequences. , 2009, Chemical Society reviews.

[55]  Alírio E. Rodrigues,et al.  Design of a gas phase simulated moving bed for propane/propylene separation , 2009 .

[56]  C. Serre,et al.  Hydrocarbon adsorption in the flexible metal organic frameworks MIL-53(Al, Cr). , 2008, Journal of the American Chemical Society.

[57]  François-Xavier Coudert,et al.  Thermodynamics of guest-induced structural transitions in hybrid organic-inorganic frameworks. , 2008, Journal of the American Chemical Society.

[58]  Alírio E. Rodrigues,et al.  Propane/Propylene Separation by Pressure Swing Adsorption Using Zeolite 4A , 2005 .

[59]  Kazuya Saito,et al.  A contrivance for a dynamic porous framework: cooperative guest adsorption based on square grids connected by amide-amide hydrogen bonds. , 2004, Journal of the American Chemical Society.

[60]  A. Rodrigues,et al.  Vacuum Swing Adsorption for Propylene/Propane Separation with 4A Zeolite , 2001 .

[61]  Jerry March,et al.  March's Advanced Organic Chemistry: Reactions, Mechanisms, and Structure , 2001 .

[62]  R. T. Yang,et al.  Olefin/paraffin separations by adsorption: π‐Complexation vs. kinetic separation , 1998 .

[63]  R. Eldridge,et al.  Olefin/paraffin separation technology: a review , 1993 .

[64]  A. Streitwieser,et al.  Carbon acidity. 58. Hydrogen isotope exchange kinetics of propylene with lithium cyclohexylamide , 1981 .