论文信息 - A 1:1 adduct of hexamethylenetetramine and 4-hydroxy-3-methoxybenzaldehyde.

A 1:1 adduct of hexamethylenetetramine and 4-hydroxy-3-methoxybenzaldehyde.

In the title complex, C6H12N4*C8H8O3, the hexamethylenetetramine molecule accepts a single intermolecular O-H...N hydrogen bond from the hydroxy group of the 4-hydroxy-3-methoxybenzaldehyde moiety. The non-centrosymmetric crystal structure is built from alternating molecular sheets of 4-hydroxy-3-methoxybenzaldehyde and hexamethylenetetramine molecules, and is stabilized by intermolecular O-H...N, C-H...O and C-H...pi interactions.

B. Poh | H. Fun | A. Usman | C. Karalai | S. Chantrapromma

[1] M. Nardelli,et al. PARST95 – an update to PARST: a system of Fortran routines for calculating molecular structure parameters from the results of crystal structure analyses , 1995 .

[2] D. Cremer,et al. General definition of ring puckering coordinates , 1975 .

[3] T. H. Jordan,et al. Molecular and Crystal Structure of Hexamethylenetetramine Triphenol , 1970 .

[4] S. Wallwork. Hydrogen‐bond radii , 1962 .