Optically Clear and Resilient Free-Form μ-Optics 3D-Printed via Ultrafast Laser Lithography

We introduce optically clear and resilient free-form micro-optical components of pure (non-photosensitized) organic-inorganic SZ2080 material made by femtosecond 3D laser lithography (3DLL). This is advantageous for rapid printing of 3D micro-/nano-optics, including their integration directly onto optical fibers. A systematic study of the fabrication peculiarities and quality of resultant structures is performed. Comparison of microlens resiliency to continuous wave (CW) and femtosecond pulsed exposure is determined. Experimental results prove that pure SZ2080 is ∼20 fold more resistant to high irradiance as compared with standard lithographic material (SU8) and can sustain up to 1.91 GW/cm2 intensity. 3DLL is a promising manufacturing approach for high-intensity micro-optics for emerging fields in astro-photonics and atto-second pulse generation. Additionally, pyrolysis is employed to homogeneously shrink structures up to 40% by removing organic SZ2080 constituents. This opens a promising route towards downscaling photonic lattices and the creation of mechanically robust glass-ceramic microstructures.

[1]  D. Bäuerle Laser Processing and Chemistry , 1996 .

[2]  S. Juodkazis,et al.  Photophysics and photochemistry of a laser manipulated microparticle , 1999 .

[3]  Elsa M. Garmire,et al.  Photonics: Linear and Nonlinear Interactions of Laser Light and Matter , 2001 .

[4]  Saulius Juodkazis,et al.  Surface nanostructuring of borosilicate glass by femtosecond nJ energy pulses , 2003 .

[5]  Boris N. Chichkov,et al.  Inorganic–Organic Hybrid Polymers for Information Technology: from Planar Technology to 3D Nanostructures , 2003 .

[6]  B N Chichkov,et al.  Femtosecond laser-induced two-photon polymerization of inorganic-organic hybrid materials for applications in photonics. , 2003, Optics letters.

[7]  Saulius Juodkazis,et al.  Intrinsic single- and multiple-pulse laser-induced damage in silicate glasses in the femtosecond-to-nanosecond region , 2004 .

[8]  Satoshi Kawata,et al.  Two-photon photopolymerization and 3D lithographic microfabrication , 2005 .

[9]  David J. Hagan,et al.  Two-photon absorption cross-sections of common photoinitiators , 2004 .

[10]  J. Bland-Hawthorn,et al.  Multimode fiber devices with single-mode performance. , 2005, Optics letters.

[11]  Dong-Yol Yang,et al.  Recent developments in the use of two‐photon polymerization in precise 2D and 3D microfabrications , 2006 .

[12]  Martin Wegener,et al.  New Route to Three‐Dimensional Photonic Bandgap Materials: Silicon Double Inversion of Polymer Templates , 2006 .

[13]  Kurt Busch,et al.  Shrinkage Precompensation of Holographic Three‐Dimensional Photonic‐Crystal Templates , 2006 .

[14]  Dong Yol Yang,et al.  Improvement of spatial resolution in nano-stereolithography using radical quencher , 2006 .

[15]  Stephen Barlow,et al.  65 nm feature sizes using visible wavelength 3-D multiphoton lithography. , 2007, Optics express.

[16]  S. Linden,et al.  Photonic metamaterials by direct laser writing and silver chemical vapour deposition. , 2008, Nature materials.

[17]  Min Gu,et al.  Engineering stop gaps of inorganic-organic polymeric 3D woodpile photonic crystals with post-thermal treatment. , 2008, Optics express.

[18]  C. Fotakis,et al.  Ultra-low shrinkage hybrid photosensitive material for two-photon polymerization microfabrication. , 2008, ACS nano.

[19]  J. Gottmann,et al.  Micro- and nanostructures inside sapphire by fs-laser irradiation and selective etching , 2008, 2008 Conference on Lasers and Electro-Optics and 2008 Conference on Quantum Electronics and Laser Science.

[20]  Shoji Maruo,et al.  Recent progress in multiphoton microfabrication , 2008 .

[21]  Olga G. Kosareva,et al.  Can we reach very high intensity in air with femtosecond PW laser pulses? , 2009 .

[22]  R. Gadonas,et al.  Organic dye doped microstructures for optically active functional devices fabricated via two-photon polymerization technique , 2010 .

[23]  Saulius Juodkazis,et al.  Freestanding and movable photonic microstructures fabricated by photopolymerization with femtosecond laser pulses , 2010 .

[24]  Mangirdas Malinauskas,et al.  A femtosecond laser-induced two-photon photopolymerization technique for structuring microlenses , 2010 .

[25]  B. Chichkov,et al.  Multiphoton polymerization of hybrid materials , 2010 .

[26]  Georg von Freymann,et al.  The Materials Challenge in Diffraction‐Unlimited Direct‐Laser‐Writing Optical Lithography , 2010, Advanced materials.

[27]  R. Gadonas,et al.  Femtosecond laser polymerization of hybrid/integrated micro-optical elements and their characterization , 2010 .

[28]  Martin Wegener,et al.  Direct laser writing of three-dimensional submicron structures using a continuous-wave laser at 532 nm , 2010 .

[29]  Saulius Juodkazis,et al.  Mechanisms of three-dimensional structuring of photo-polymers by tightly focussed femtosecond laser pulses. , 2010, Optics express.

[30]  T A Birks,et al.  Ultrafast laser inscription of an integrated photonic lantern. , 2011, Optics express.

[31]  B. Lebeau,et al.  Hybrid materials for optics and photonics. , 2011, Chemical Society reviews.

[32]  S. Juodkazis,et al.  Three-dimensional micro-/nano-structuring via direct write polymerization with picosecond laser pulses. , 2011, Optics express.

[33]  Stavros Pissadakis,et al.  3D microoptical elements formed in a photostructurable germanium silicate by direct laser writing , 2012 .

[34]  C. Fotakis,et al.  Diffusion-assisted high-resolution direct femtosecond laser writing. , 2012, ACS nano.

[35]  Hermann Seitz,et al.  A review on 3D micro-additive manufacturing technologies , 2012, The International Journal of Advanced Manufacturing Technology.

[36]  A. Couairon,et al.  Sharply autofocused ring-Airy beams transforming into non-linear intense light bullets , 2013, Nature Communications.

[37]  M. Malinauskas,et al.  Fabrication, replication, and characterization of microlenses for optofluidic applications , 2013, Photonics West - Micro and Nano Fabricated Electromechanical and Optical Components.

[38]  Saulius Juodkazis,et al.  Nano-groove and 3D fabrication by controlled avalanche using femtosecond laser pulses , 2013 .

[39]  Aleksandr Ovsianikov,et al.  Initiation efficiency and cytotoxicity of novel water-soluble two-photon photoinitiators for direct 3D microfabrication of hydrogels , 2013 .

[40]  Mangirdas Malinauskas,et al.  Monolithic generators of pseudo-nondiffracting optical vortex beams at the microscale , 2013 .

[41]  Jaroslaw Jacak,et al.  120 nm resolution and 55 nm structure size in STED-lithography. , 2013, Optics express.

[42]  J. Fischer,et al.  Three-dimensional multi-photon direct laser writing with variable repetition rate. , 2013, Optics express.

[43]  N. D. Lai,et al.  Submicrometer 3D structures fabrication enabled by one-photon absorption direct laser writing. , 2013, Optics express.

[44]  S. Hengsbach,et al.  Direct laser writing of auxetic structures: present capabilities and challenges , 2014 .

[45]  Mangirdas Malinauskas,et al.  Direct laser writing of microstructures on optically opaque and reflective surfaces , 2014 .

[46]  G. Batavičiūtė,et al.  Characterization of photopolymers used in laser 3D micro/nanolithography by means of laser-induced damage threshold (LIDT) , 2014 .

[47]  Andrea Toma,et al.  Suitable photo-resists for two-photon polymerization using femtosecond fiber lasers , 2014 .

[48]  A. Couairon,et al.  Superfilamentation in air. , 2014, Physical review letters.

[49]  Mangirdas Malinauskas,et al.  Augmentation of direct laser writing fabrication throughput for three-dimensional structures by varying focusing conditions , 2014 .

[50]  Mangirdas Malinauskas,et al.  Effect of the photoinitiator presence and exposure conditions on laser-induced damage threshold of ORMOSIL (SZ2080) , 2015 .

[51]  Mangirdas Malinauskas,et al.  Tuning the refractive index in 3D direct laser writing lithography: towards GRIN microoptics , 2015 .

[52]  Mangirdas Malinauskas,et al.  Preclinical study of SZ2080 material 3D microstructured scaffolds for cartilage tissue engineering made by femtosecond direct laser writing lithography , 2015, Biofabrication.

[53]  Optimization of hybrid polymer materials for 2PP and fabrication of individually designed hybrid microoptical elements thereof , 2015 .

[54]  Martin Schwentenwein,et al.  Additive Manufacturing of Dense Alumina Ceramics , 2015 .

[55]  Maria Farsari,et al.  Direct laser writing , 2015 .

[56]  Ady Arie,et al.  Shaping of light beams by 3D direct laser writing on facets of nonlinear crystals. , 2015, Optics letters.

[57]  Kestutis Staliunas,et al.  Spatial filtering with photonic crystals , 2015 .

[58]  S. Juodkazis 3D printed micro-optics , 2016, Nature Photonics.

[59]  Harald Giessen,et al.  Two-photon direct laser writing of ultracompact multi-lens objectives , 2016, Nature Photonics.

[60]  Saulius Juodkazis,et al.  Ultrafast laser processing of materials: from science to industry , 2016, Light: Science & Applications.

[61]  H. Giessen,et al.  Sub-micrometre accurate free-form optics by three-dimensional printing on single-mode fibres , 2016, Nature Communications.

[62]  S. Juodkazis,et al.  Nanoscale Precision of 3D Polymerization via Polarization Control , 2016, 1603.06748.

[63]  Z. Eckel,et al.  Additive manufacturing of polymer-derived ceramics , 2016, Science.

[64]  Lan Jiang,et al.  Performance comparison of acrylic and thiol-acrylic resins in two-photon polymerization. , 2016, Optics express.

[65]  Saulius Juodkazis,et al.  Silk patterns made by direct femtosecond laser writing. , 2016, Biomicrofluidics.

[66]  Bilal Gökce,et al.  Plasmon assisted 3D microstructuring of gold nanoparticle-doped polymers , 2016, Nanotechnology.