Improvement of Resistive Switching Properties in $ \hbox{ZrO}_{2}$-Based ReRAM With Implanted Ti Ions

In this letter, the resistive switching properties of a ZrO2-based memory film with implanted Ti ions are investigated. The testing results demonstrate that doping Ti in ZrO2 can remove the electroforming process and reduce the variations of switching parameters such as set voltage and resistance in off state. Furthermore, the Ti-doped ZrO2 resistive switching memory also exhibits high device yield (nearly 100%), low operating voltage, fast speed, large on/off ratio (>104), and long retention time (>107 s). The formation and rupture of conducting filaments are suggested to be responsible for the resistive switching phenomenon. The doped Ti impurities can improve the formation of conducting filaments and switching behaviors.

[1]  D. Morgan,et al.  Electrical phenomena in amorphous oxide films , 1970 .

[2]  J. Stathis Percolation models for gate oxide breakdown , 1999 .

[3]  S. O. Park,et al.  Highly scalable nonvolatile resistive memory using simple binary oxide driven by asymmetric unipolar voltage pulses , 2004, IEDM Technical Digest. IEEE International Electron Devices Meeting, 2004..

[4]  I. Yoo,et al.  Resistance switching of the nonstoichiometric zirconium oxide for nonvolatile memory applications , 2005, IEEE Electron Device Letters.

[5]  S. O. Park,et al.  Electrical observations of filamentary conductions for the resistive memory switching in NiO films , 2006 .

[6]  L. Y. Chen,et al.  Reproducible unipolar resistance switching in stoichiometric ZrO2 films , 2007 .

[7]  C. Hu,et al.  Effect of Top Electrode Material on Resistive Switching Properties of $\hbox{ZrO}_{2}$ Film Memory Devices , 2007, IEEE Electron Device Letters.

[8]  K. Tsunoda,et al.  Low Power and High Speed Switching of Ti-doped NiO ReRAM under the Unipolar Voltage Source of less than 3 V , 2007, 2007 IEEE International Electron Devices Meeting.

[9]  Byung Joon Choi,et al.  Anode-interface localized filamentary mechanism in resistive switching of TiO2 thin films , 2007 .

[10]  Wenlian Li,et al.  Long lasting phosphorescent properties of Ti doped ZrO2 , 2007 .

[11]  B. Delley,et al.  Role of Oxygen Vacancies in Cr‐Doped SrTiO3 for Resistance‐Change Memory , 2007, 0707.0563.

[12]  Xiangkang Meng,et al.  Field-induced resistive switching based on space-charge-limited current , 2007 .

[13]  R. Waser,et al.  Characteristic electroforming behavior in Pt/TiO2/Pt resistive switching cells depending on atmosphere , 2008 .

[14]  Qi Liu,et al.  Nonpolar Nonvolatile Resistive Switching in Cu Doped $\hbox{ZrO}_{2}$ , 2008, IEEE Electron Device Letters.

[15]  Frederick T. Chen,et al.  Low power and high speed bipolar switching with a thin reactive Ti buffer layer in robust HfO2 based RRAM , 2008, 2008 IEEE International Electron Devices Meeting.

[16]  F. Zeng,et al.  Fully room-temperature-fabricated nonvolatile resistive memory for ultrafast and high-density memory application. , 2009, Nano letters.