2-Amino-5-methylpyridinium nicotinate

In the title compound, C6H9N2 +·C6H4NO2 −, the 2-amino-5-methylpyridinium cation is essentially planar, with a maximum deviation of 0.023 (2) Å. In the crystal, the cations and anions are linked via strong N—H⋯O hydrogen bonds, forming a two dimensional network parallel to (100). In addition, π⋯π interactions involving the pyridinium and pyridine rings, with centroid–centroid distances of 3.6383 (8) Å, are observed.

[1]  A. Kvick,et al.  2-Amino-5-methylpyridine , 1977 .

[2]  Alan R. Katritzky,et al.  Comprehensive Heterocyclic Chemistry IV , 1996 .

[3]  C. Stannek,et al.  Characterization of a G protein-coupled receptor for nicotinic acid. , 2001, Molecular pharmacology.

[4]  A. T. Soldatenkov,et al.  Heterocycles in life and society , 1997 .

[5]  Steve Scheiner,et al.  Hydrogen Bonding: A Theoretical Perspective , 1997 .

[6]  Olga Kennard,et al.  Tables of bond lengths determined by X-ray and neutron diffraction. Part 1. Bond lengths in organic compounds , 1987 .

[7]  B. Mikami,et al.  Crystallization and preliminary X-ray crystallographic analysis of nicotinic acid mononucleotide adenylyltransferase from Pseudomonas aeruginosa. , 2004, Acta crystallographica. Section D, Biological crystallography.

[8]  G. G. Stokes "J." , 1890, The New Yale Book of Quotations.

[9]  Anthony L. Spek,et al.  Structure validation in chemical crystallography , 2009, Acta crystallographica. Section D, Biological crystallography.

[10]  Raymond E. Davis,et al.  Patterns in Hydrogen Bonding: Functionality and Graph Set Analysis in Crystals , 1995 .

[11]  Professor Dr. George A. Jeffrey,et al.  Hydrogen Bonding in Biological Structures , 1991, Springer Berlin Heidelberg.

[12]  M. Biesemans,,et al.  (2-Methylthio-3-Pyridinecarboxylato)-diethyltin and -di-n-butyltin compounds: synthesis, spectroscopic characterization and in vitro antitumour activity. X-ray crystal structure of bis[diethyl(2-methylthio-3-Pyridinecarboxylato)tin] oxide and of diethyltin bis(2-methylthio-3-pyridinecarboxylate) , 1992 .

[13]  G. Sheldrick A short history of SHELX. , 2008, Acta crystallographica. Section A, Foundations of crystallography.

[14]  G. A. Jeffrey,et al.  An Introduction to Hydrogen Bonding , 1997 .