Why Scale Forms in the Oil Field and Methods To Predict It

Predicting potential scaling problems can be difficult, and numerous saturation indices and computer algorithms have been developed to determine if, when, and where scaling will occur. The Langelier, Stiff-Davis, and the Oddo-Tomson saturation indices, all widely used in the oil field, are compared and contrasted relative to calcium carbonate scale. New saturation indices for barium, strontium, and calcium sulfate scale formation are introduced and discussed, along with an updated version of the Oddo-Tomson calcium carbonate index. An updated version of the CaCO[sub 3] saturation index is presented that includes correction terms for fugacity effects and changes in the solubility of CO[sub 2] in oil and gas wells as function of temperature, pressure, water cut, and hydrocarbons present. The CaCO[sub 3] saturation index does not require a measured pH and can accommodate the presence of weak acids, such as H[sub 2]S, and wake organic acids in the system. The sulfate scale production methods (for gypsum, hemihydrate, and anhydrite) are easy to use, reliable, and designed for field use by an operator who may be untrained in chemistry. The prediction methods can be applied to any production well where calcium carbonate, calcium sulfate, strontium sulfate, or barium sulfate scale occurs.