论文信息 - Magnetic circular dichroism of M and R centres in KCl. II. The technique of moments in the R-centre problem

Magnetic circular dichroism of M and R centres in KCl. II. The technique of moments in the R-centre problem

For pt.I. see ibid., vol.6, 2733-44 (1973). The zeroth and first moments of the magnetic circular dichroism of the R1, R2 and RM bands of R centres have been calculated in the frame of Silsbee's model. The experimental results of Merle d'Aubigne and Duval (1968) as well as those of the first paper of this series are interpreted, yielding the following values of the involved parameters: Jahn-Teller constant, k2=1.25+or-0.25, effective mean energy of the Gamma 3 lattice vibration, h(cross) omega E=(120+or-20) cm-1; spin-orbit constant of the R1-band excited state, lambda 1=(-27+or-4) cm-1.

J. Margerie | G. Binet | Y. M. d’Aubigné

[1] J. Margerie,et al. Magnetic circular dichroism of M and R centres in KCl: I. Experiment , 1973 .

[2] R. Buisson,et al. Influence of Strains on Paramagnetic-Resonance Spectrum for Strongly Coupled Ions-Application to V 3+ in MgO , 1972 .

[3] P. Duval,et al. Dichroïsme circulaire des centres R dans KCl , 1968 .

[4] I. Shepherd. Magnetic Circular Dichroism of the R2 Band in KCl and KF , 1968 .

[5] R. H. Silsbee,et al. R Center in KCl: Electron-Spin-Resonance Studies of the Ground State , 1966 .

[6] R. H. Silsbee. R CENTER IN KCl STRESS EFFECTS IN OPTICAL ABSORPTION , 1965 .

[7] C. Henry,et al. EFFECT OF APPLIED FIELDS ON THE OPTICAL PROPERTIES OF COLOR CENTERS , 1964 .

[8] H. C. Longuet-Higgins,et al. Studies of the Jahn-Teller effect .II. The dynamical problem , 1958, Proceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences.