Solid state dye solar cell modules

Abstract We fabricated the first solid state dye solar cell (SDSC) module using poly(3-hexilthiophene) (P3HT) as Hole Transport Material for the dye regeneration process. Integrated interconnections were obtained following the “Monolithic” architecture for series connections. The fabricated SDSC module has a conversion efficiency of 2.0% on active area. These results represent a promising starting point for an effective up-scaling of SDSC devices.

[1]  Peng Wang,et al.  An organic D-π-A dye for record efficiency solid-state sensitized heterojunction solar cells. , 2011, Nano letters.

[2]  Hidetoshi Miura,et al.  Organic Dye for Highly Efficient Solid‐State Dye‐Sensitized Solar Cells , 2005 .

[3]  T. Brown,et al.  Laser processing of TiO2 films for dye solar cells: a thermal, sintering, throughput and embodied energy investigation , 2014 .

[4]  D. Schroder Semiconductor Material and Device Characterization , 1990 .

[5]  Rainer Kern,et al.  New interdigital design for large area dye solar modules using a lead‐free glass frit sealing , 2006 .

[6]  Michael Grätzel,et al.  The Effect of Hole Transport Material Pore Filling on Photovoltaic Performance in Solid‐State Dye‐Sensitized Solar Cells , 2011 .

[7]  J. Noh,et al.  Chemical management for colorful, efficient, and stable inorganic-organic hybrid nanostructured solar cells. , 2013, Nano letters.

[8]  Takanori Sutou,et al.  Efficient dye-sensitized solar cell sub-modules , 2010 .

[9]  P. M. Sommeling,et al.  Reproducible manufacturing of dye‐sensitized solar cells on a semi‐automated baseline , 2003 .

[10]  Aldo Di Carlo,et al.  Electrochemistry in reverse biased dye solar cells and dye/electrolyte degradation mechanisms. , 2012, Chemphyschem : a European journal of chemical physics and physical chemistry.

[11]  M. Grätzel,et al.  A low-cost, high-efficiency solar cell based on dye-sensitized colloidal TiO2 films , 1991, Nature.

[12]  A. Di Carlo,et al.  Blocking layer optimisation of poly(3-hexylthiopene)based solid state dye sensitized solar cells , 2013 .

[13]  A. Reale,et al.  Series-Connection Designs for Dye Solar Cell Modules , 2011, IEEE Transactions on Electron Devices.

[14]  Anders Hagfeldt,et al.  Symmetric and unsymmetric donor functionalization. comparing structural and spectral benefits of chromophores for dye-sensitized solar cells , 2009 .

[15]  Aldo Di Carlo,et al.  Realization of high performance large area Z‐series‐interconnected opaque dye solar cell modules , 2013 .

[16]  Anders Hagfeldt,et al.  Comparing spiro-OMeTAD and P3HT hole conductors in efficient solid state dye-sensitized solar cells. , 2012, Physical chemistry chemical physics : PCCP.

[17]  Aldo Di Carlo,et al.  Physical and electrochemical analysis of an indoor-outdoor ageing test of large-area dye solar cell devices. , 2012, Chemphyschem : a European journal of chemical physics and physical chemistry.

[18]  G. K. Reeves,et al.  Obtaining the specific contact resistance from transmission line model measurements , 1982, IEEE Electron Device Letters.

[19]  Henry J. Snaith,et al.  How should you measure your excitonic solar cells , 2012 .

[20]  Bin Liu,et al.  Highly Efficient Nanoporous TiO2‐Polythiophene Hybrid Solar Cells Based on Interfacial Modification Using a Metal‐Free Organic Dye , 2009 .

[21]  Henry J. Snaith,et al.  The renaissance of dye-sensitized solar cells , 2012, Nature Photonics.

[22]  Josef Salbeck,et al.  Solid-state dye-sensitized mesoporous TiO2 solar cells with high photon-to-electron conversion efficiencies , 1998, Nature.

[23]  Martin A. Green,et al.  Crystalline and thin-film silicon solar cells: state of the art and future potential , 2003 .

[24]  Dieter K. Schroder,et al.  Semiconductor Material and Device Characterization: Schroder/Semiconductor Material and Device Characterization, Third Edition , 2005 .

[25]  Michael Grätzel,et al.  Porphyrin-Sensitized Solar Cells with Cobalt (II/III)–Based Redox Electrolyte Exceed 12 Percent Efficiency , 2011, Science.

[26]  J. Teuscher,et al.  Efficient Hybrid Solar Cells Based on Meso-Superstructured Organometal Halide Perovskites , 2012, Science.

[27]  Yang Huang,et al.  Design of DSC panel with efficiency more than 6 , 2005 .

[28]  Henry J. Snaith,et al.  Facile infiltration of semiconducting polymer into mesoporous electrodes for hybrid solar cells , 2011 .

[29]  Aldo Di Carlo,et al.  Reverse bias degradation in dye solar cells , 2012 .

[30]  R. Tscharner,et al.  Photovoltaic technology: the case for thin-film solar cells , 1999, Science.

[31]  M. Grätzel,et al.  Charge Generation and Photovoltaic Operation of Solid‐State Dye‐Sensitized Solar Cells Incorporating a High Extinction Coefficient Indolene‐Based Sensitizer , 2009 .

[32]  Peter Lund,et al.  Review of stability for advanced dye solar cells , 2010 .