Novel Miniature and Selective Combustion-Type CMOS Gas Sensor for Gas-Mixture Analysis—Part 1: Emphasis on Chemical Aspects

There is an ongoing effort to fabricate miniature, low cost, sensitive, and selective gas sensors for domestic and industrial uses. This paper presents a miniature combustion-type gas sensor (GMOS) based on a thermal sensor, where a micromachined CMOS–SOI transistor integrated with a catalytic reaction plate acts as a sensing element. This study emphasizes GMOS performance modeling, technological aspects, and sensing-selectivity issues. Two deposition techniques of a Pt catalytic layer suitable for wafer-level processing were compared, magnetron sputtering and nanoparticle inkjet printing. Both techniques have been useful for the fabrication of GMOS sensor, with good sensitivity to ethanol and acetone in the air. However, a printed Pt nanoparticle catalyst provides almost twice as much sensitivity as compared to that of the sputtered catalyst. Moreover, sensing selectivity in the ethanol/acetone gas mixture was demonstrated for the GMOS with a Pt nanoparticle catalyst. These advantages of GMOS allow for the fabrication of a low-cost gas sensor that requires a low power, and make it a promising technology for future smartphones, wearables, and Internet of Things (IoT) applications.

[1]  C. H. Bartholomew,et al.  Catalyst Deactivation: Causes, Mechanisms, and Treatment , 2010 .

[2]  Robert Bogue,et al.  Recent developments in MEMS sensors: a review of applications, markets and technologies , 2013 .

[3]  T. A. Jones,et al.  The principles of the detection of flammable atmospheres by catalytic devices , 1973 .

[4]  K. Ihokura,et al.  The Stannic Oxide Gas SensorPrinciples and Applications , 1994 .

[5]  Y. Nemirovsky,et al.  Nanometric CMOS-SOI-NEMS Transistor for Uncooled THz Sensing , 2013, IEEE Transactions on Electron Devices.

[6]  Florin Udrea,et al.  CMOS Interfacing for Integrated Gas Sensors: A Review , 2010, IEEE Sensors Journal.

[7]  H. Wise,et al.  Catalytic oxidation studies with platinum and palladium , 1971 .

[8]  Hiroyuki Fujita,et al.  Integrated Chemical Microsensor Systems in CMOS Technology , 2005 .

[9]  Walter Lang,et al.  Ligand-Linked Nanoparticles-Based Hydrogen Gas Sensor with Excellent Homogeneous Temperature Field and a Comparative Stability Evaluation of Different Ligand-Linked Catalysts † , 2019, Sensors.

[10]  Maximilian Fleischer,et al.  Solid State Gas Sensors - Industrial Application , 2012 .

[11]  Y. Nemirovsky,et al.  CMOS-SOI-MEMS Transistor for Uncooled IR Imaging , 2009, IEEE Transactions on Electron Devices.

[12]  Walter Lang,et al.  A fast and sensitive catalytic gas sensors for hydrogen detection based on stabilized nanoparticles as catalytic layer , 2014 .

[13]  Y. Nemirovsky,et al.  Catalytic Gas Sensor Based on Micro Machined CMOS Transistor , 2019, 2019 IEEE International Conference on Microwaves, Antennas, Communications and Electronic Systems (COMCAS).

[14]  Walter Lang,et al.  A miniaturized catalytic gas sensor for hydrogen detection based on stabilized nanoparticles as catalytic layer , 2013 .

[15]  D. Frank-Kamenetskii,et al.  Diffusion and heat exchange in chemical kinetics , 1955 .

[16]  Calvin H. Bartholomew,et al.  Fundamentals of Industrial Catalytic Processes: Bartholomew/Fundamentals , 2005 .

[17]  A. Hierlemann Integrated chemical microsensor systems in CMOS-technology , 2005, The 13th International Conference on Solid-State Sensors, Actuators and Microsystems, 2005. Digest of Technical Papers. TRANSDUCERS '05..

[18]  Y. Nemirovsky,et al.  Micro-machined CMOS-SOI transistor (TMOS) thermal sensor operating in air , 2017, 2017 IEEE International Conference on Microwaves, Antennas, Communications and Electronic Systems (COMCAS).

[19]  Y. Nemirovsky,et al.  CMOS-SOI-MEMS Uncooled Infrared Security Sensor With Integrated Readout , 2016, IEEE Journal of the Electron Devices Society.

[20]  E. A. Symons Catalytic Gas Sensors , 1992 .

[21]  J.B. Miller,et al.  Catalytic sensors for monitoring explosive atmospheres , 2001, IEEE Sensors Journal.

[22]  O. Ahmed Future Building Gas Sensing Applications , 2012 .

[23]  G. Korotcenkov Handbook of Gas Sensor Materials: Properties, Advantages and Shortcomings for Applications Volume 1: Conventional Approaches , 2013 .

[24]  G. Sberveglieri,et al.  Gas sensors : principles, operation and developments , 1992 .

[25]  Y. Nemirovsky,et al.  Modeling the Performance of Nano Machined CMOS Transistors for Uncooled IR Sensing , 2017, IEEE Transactions on Electron Devices.

[26]  Ghenadii Korotcenkov,et al.  Handbook of Gas Sensor Materials: Properties, Advantages and Shortcomings for Applications Volume 2: New Trends and Technologies , 2013 .

[27]  Y. Nemirovsky,et al.  A New Pellistor-Like Gas Sensor Based on Micromachined CMOS Transistor , 2018, IEEE Transactions on Electron Devices.

[28]  S. Morrison,et al.  Semiconductor gas sensors , 1985 .

[29]  D. Barrettino,et al.  CMOS Hotplate Chemical Microsensors , 2007 .

[30]  J. Riegel,et al.  Analysis of combustible gases in air with calorimetric gas sensors based on semiconducting BaTiO3 ceramics , 1990 .