Low power and high speed bipolar switching with a thin reactive Ti buffer layer in robust HfO2 based RRAM

A novel HfO2-based resistive memory with the TiN electrodes is proposed and fully integrated with 0.18 mum CMOS technology. By using a thin Ti layer as the reactive buffer layer into the anodic side of capacitor-like memory cell, excellent memory performances, such as low operation current (down to 25 muA), high on/off resistance ratio (above 1,000), fast switching speed (5 ns), satisfactory switching endurance (>106 cycles), and reliable data retention (10 years extrapolation at 200degC) have been demonstrated in our memory device. Moreover, the benefits of high yield, robust memory performance at high temperature (200degC), excellent scalability, and multi-level operation promise its application in the next generation nonvolatile memory.

[1]  John B. Shoven,et al.  I , Edinburgh Medical and Surgical Journal.

[2]  Thomas de Quincey [C] , 2000, The Works of Thomas De Quincey, Vol. 1: Writings, 1799–1820.

[3]  S. O. Park,et al.  Highly scalable nonvolatile resistive memory using simple binary oxide driven by asymmetric unipolar voltage pulses , 2004, IEDM Technical Digest. IEEE International Electron Devices Meeting, 2004..

[4]  Krishna C. Saraswat,et al.  Engineering chemically abrupt high-k metal oxide∕silicon interfaces using an oxygen-gettering metal overlayer , 2004 .

[5]  S. Haddad,et al.  Non-volatile resistive switching for advanced memory applications , 2005, IEEE InternationalElectron Devices Meeting, 2005. IEDM Technical Digest..

[6]  Dongsoo Lee,et al.  Excellent uniformity and reproducible resistance switching characteristics of doped binary metal oxides for non-volatile resistance memory applications , 2006, 2006 International Electron Devices Meeting.

[7]  C. Hu,et al.  Effect of Top Electrode Material on Resistive Switching Properties of $\hbox{ZrO}_{2}$ Film Memory Devices , 2007, IEEE Electron Device Letters.

[8]  K. Tsunoda,et al.  Low Power and High Speed Switching of Ti-doped NiO ReRAM under the Unipolar Voltage Source of less than 3 V , 2007, 2007 IEEE International Electron Devices Meeting.

[9]  M. Aoki,et al.  Reduction of Reset Current in NiO-ReRAM Brought about by Ideal Current Limiter , 2007, 2007 22nd IEEE Non-Volatile Semiconductor Memory Workshop.