Bulk Metallic Glasses with Functional Physical Properties

In this review, we report on the formation of a variety of novel, metallic, glassy materials that might well have applications as functional materials. The metallic glasses with excellent glass-forming ability, display many fascinating properties and features such as excellent wave-absoption ability, exceptionally low glass-transition temperatures (similar to 35-60 degrees C) approaching room temperature, ultralow elastic moduli comparable to that of human bone, high elasticity and high strength,superplasticity and poly-mer-like thermoplastic formability near room temperature an excellent magnetocaloric effect, hard magnetism and tunable magnetic properties, heavy-fermion behavior, superhydrophobicity and superoleophobicity, and polyamorphism, all of which are of interest not only for basic research but also for technological applications. A strategy based on elastic moduli correlations for fabrication of bulk metallic, glasses (BMCs) with controllable properties is presented. The work has implications in the search for novel metallic glasses with unique functional properties, for ad g our understanding of the nature and formation of glasses, and for extending the applications of the materials.

[1]  Weihua Wang,et al.  Kinetic nature of hard magnetic Nd_50Al_15Fe_15Co_20 bulk metallic glass with distinct glass transition , 2004 .

[2]  W. Johnson,et al.  A universal criterion for plastic yielding of metallic glasses with a (T/Tg) 2/3 temperature dependence. , 2005, Physical review letters.

[3]  H. Bai,et al.  Lutetium and thulium based rare earth bulk metallic glasses , 2008 .

[4]  S. Poon,et al.  Metallic glass ingots based on yttrium , 2003 .

[5]  W. Wang,et al.  Thulium-based bulk metallic glass , 2008 .

[6]  W. Wang,et al.  Elastic constants of Pd39Ni10Cu30P21 bulk metallic glass under high pressure , 2000 .

[7]  H. Erbil,et al.  Transformation of a Simple Plastic into a Superhydrophobic Surface , 2003, Science.

[8]  Xinjian Feng,et al.  Design and Creation of Superwetting/Antiwetting Surfaces , 2006 .

[9]  Weihua Wang,et al.  Metallic plastics based on misch metals , 2006 .

[10]  B. Wei,et al.  Domain structure of a Nd60Al10Fe20Co10 bulk metallic glass , 2001 .

[11]  Yue Wu,et al.  Correlation of atomic cluster symmetry and glass-forming ability of metallic glass. , 2007, Physical review letters.

[12]  H. Bai,et al.  Pressure effects on mechanical properties of bulk metallic glass , 2007 .

[13]  D. Zhao,et al.  Anomalous temperature dependent elastic moduli of Ce-based bulk metallic glass at low temperatures , 2007 .

[14]  Weihua Wang,et al.  Preliminary assessment of flow, notch toughness, and high temperature behavior of Cu60Zr20Hf10Ti10 bulk metallic glass , 2004 .

[15]  J Liu,et al.  Anomalous compression behavior in lanthanum/cerium-based metallic glass under high pressure , 2007, Proceedings of the National Academy of Sciences.

[16]  Weihua Wang,et al.  Erbium- and cerium-based bulk metallic glasses , 2006 .

[17]  T. C. Green,et al.  Shape-Controlled Synthesis of Colloidal Platinum Nanoparticles , 1996, Science.

[18]  Weihua Wang,et al.  Binary Cu–Zr Bulk Metallic Glasses , 2004 .

[19]  W. Johnson,et al.  Isoconfigurational elastic constants and liquid fragility of a bulk metallic glass forming alloy. , 2006, Physical review letters.

[20]  W. Barthlott,et al.  Purity of the sacred lotus, or escape from contamination in biological surfaces , 1997, Planta.

[21]  Weihua Wang,et al.  Aging and stability of cerium-based bulk metallic glass , 2006 .

[22]  W. Wang,et al.  Heavy-fermion behavior in cerium-based metallic glasses , 2007 .

[23]  Weihua Wang,et al.  Bulk Scandium-based Metallic Glasses , 2005 .

[24]  Wence Wang,et al.  Bulk metallic glasses based on rare-earth elements in lanthanum series , 2006 .

[25]  O. Senkov Correlation between fragility and glass-forming ability of metallic alloys , 2007 .

[26]  J. Lewandowski,et al.  Understanding the Glass-forming Ability of Cu_50Zr_50 Alloys in Terms of a Metastable Eutectic , 2005 .

[27]  W. Wang,et al.  Structural investigation of a mechanically alloyed AlFe system , 1991 .

[28]  Weihua Wang,et al.  Formation of cerium-based bulk metallic glasses , 2006 .

[29]  Is the Fragility of a Liquid Embedded in the Properties of Its Glass? , 2003, Science.

[30]  Weihua Wang,et al.  Microstructure- and property-controllable NdAlNiCuFe alloys by varying Fe content , 2005 .

[31]  Weihua Wang,et al.  Bulk metallic glasses based on heavy rare earth dysprosium , 2005 .

[32]  Spin-dependent current in resonant tunneling diode with ferromagnetic GaMnN layers , 2009 .

[33]  M. Seibt,et al.  Microstructure-controlled magnetic properties of the bulk glass-forming alloy Nd60Fe30Al10 , 2002 .

[34]  Mingwei Chen,et al.  Experimental characterization of shear transformation zones for plastic flow of bulk metallic glasses , 2008, Proceedings of the National Academy of Sciences.

[35]  D. Turnbull Under what conditions can a glass be formed , 1969 .

[36]  W. Johnson,et al.  Diffusion mechanisms in metallic supercooled liquids and glasses , 1999, Nature.

[37]  Wei Wei,et al.  Formation and properties of new heavy rare-earth-based bulk metallic glasses , 2005 .

[38]  Weihua Wang,et al.  Carbon-nanotube-reinforced Zr52.5Cu17.9Ni14.6Al10Ti5 bulk metallic glass composites , 2002 .

[39]  Weihua Wang,et al.  Formation, properties, thermal characteristics, and crystallization of hard magnetic Pr–Al–Fe–Cu bulk metallic glasses , 2003 .

[40]  Weihua Wang,et al.  Glass-forming Mg–Cu–RE (RE = Gd, Pr, Nd, Tb, Y, and Dy) alloys with strong oxygen resistance in manufacturability , 2004 .

[41]  T. Shen,et al.  Magnetocaloric effect in bulk amorphous Pd40Ni22.5Fe17.5P20 alloy , 2002 .

[42]  Peter X. Ma,et al.  Scaffolds for tissue fabrication , 2004 .

[43]  Weihua Wang,et al.  Periodic corrugation on dynamic fracture surface in brittle bulk metallic glass , 2006 .

[44]  Weihua Wang,et al.  Formation and properties of Pr-based bulk metallic glasses , 2006 .

[45]  Weihua Wang,et al.  Anomalous thermal stability of Nd–Fe–Co–Al bulk metallic glass , 2002 .

[46]  J. Klinger,et al.  Anisotropic heat conduction of fresh hexagonal ice single crystals at low temperature , 1982 .

[47]  K. Binder,et al.  Spin glasses: Experimental facts, theoretical concepts, and open questions , 1986 .

[48]  D. Melville The physics exhibition, 1969 , 1969 .

[49]  J. T. Krause,et al.  Correlation between young's modulus and thermal properties of metallic glasses , 1977 .

[50]  F. Murnaghan The Compressibility of Media under Extreme Pressures. , 1944, Proceedings of the National Academy of Sciences of the United States of America.

[51]  H. Bai,et al.  Enhance plasticity of bulk metallic glasses by geometric confinement , 2007 .

[52]  T. Ebbesen,et al.  Exceptionally high Young's modulus observed for individual carbon nanotubes , 1996, Nature.

[53]  A. Sokolov,et al.  Correlation of fragility and Poisson's ratio: Difference between metallic and nonmetallic glass formers , 2006 .

[54]  W. Wang,et al.  Amorphous metallic plastic. , 2005, Physical review letters.

[55]  Weihua Wang,et al.  Heavy rare earth based bulk metallic glasses with high thermal stability , 2006 .

[56]  Kesong Liu,et al.  Superamphiphobic CaLi-based bulk metallic glasses , 2009 .

[57]  Jeppe C. Dyre,et al.  Colloquium : The glass transition and elastic models of glass-forming liquids , 2006 .

[58]  Charles R. Martin,et al.  Nanomaterials: A Membrane-Based Synthetic Approach , 1994, Science.

[59]  P. Anderson,et al.  Through the Glass Lightly , 1995, Science.

[60]  J. Eckert,et al.  Equation of state of Zr 41 Ti 14 Cu 12.5 Ni 10 Be 22.5 bulk metallic glass , 2000 .

[61]  Weihua Wang,et al.  Enhancement of the soft magnetic properties of FeCoZrMoWB bulk metallic glass by microalloying , 2004 .

[62]  D. Zhao,et al.  Magnetic transitions in Dy-microalloyed Fe-based bulk metallic glasses , 2005 .

[63]  C. Dong,et al.  Composition rule of bulk metallic glasses and quasicrystals using electron concentration criterion , 2003 .

[64]  Weihua Wang,et al.  Interdiffusion in nanometer-scale multilayers investigated by in situ low-angle x-ray diffraction , 1999 .

[65]  N. Hur,et al.  Reentrant spin glass behavior in Cr-doped perovskite manganite. , 2002, Physical review letters.

[66]  Weihua Wang,et al.  Multiple spin-glass-like behaviors in a Pr-based bulk metallic glass , 2006 .

[67]  Weihua Wang,et al.  Correlations between elastic moduli and properties in bulk metallic glasses , 2006 .

[68]  Weihua Wang,et al.  Compressive deformation of a bulk Ce-based metallic glass , 2006 .

[69]  W. H. Li,et al.  Simple phenomenological determination of contact stiffness and elastic modulus of Ce-based bulk metallic glasses through nanoindentation , 2007 .

[70]  Weihua Wang,et al.  Role of addition in formation and properties of Zr-based bulk metallic glasses , 2002 .

[71]  H. Bai,et al.  Low-temperature specific-heat anomalies associated with the boson peak in CuZr-based bulk metallic glasses , 2006 .

[72]  W. Wang,et al.  Understanding exceptional thermodynamic and kinetic stability of amorphous sulfur obtained by rapid compression , 2009 .

[73]  A. Załuska,et al.  Lithium–beryllium hydrides: the lightest reversible metal hydrides , 2000 .

[74]  D. Zhao,et al.  Temperature dependence of elastic moduli in bulk metallic glasses down to liquid nitrogen temperature , 2007 .

[75]  Mingwei Chen,et al.  Mechanical Behavior of Metallic Glasses: Microscopic Understanding of Strength and Ductility , 2008 .

[76]  A. L. Greer,et al.  Bulk Metallic Glasses: At the Cutting Edge of Metals Research , 2007 .

[77]  D. Zhao,et al.  CaLi-based bulk metallic glasses with multiple superior properties , 2008 .

[78]  V. Franco,et al.  A Finemet-type alloy as a low-cost candidate for high-temperature magnetic refrigeration , 2006 .

[79]  Weihua Wang Roles of minor additions in formation and properties of bulk metallic glasses , 2007 .

[80]  Tao Zhang,et al.  Formation and mechanical properties of (Ce–La–Pr–Nd)–Co–Al bulk glassy alloys with superior glass-forming ability , 2006 .

[81]  X. Bohigas,et al.  Magnetocaloric effect in random magnetic anisotropy materials , 2002 .

[82]  Weihua Wang,et al.  Bulk metallic glasses , 2004 .

[83]  Weihua Wang,et al.  Microstructure, decomposition, and crystallization in Zr41Ti14Cu12.5Ni10Be22.5 bulk metallic glass , 1998 .

[84]  T. Egami Glass transition and viscosity in metallic glasses and liquids , 2007 .

[85]  Turnbull,et al.  Elastic behavior and vibrational anharmonicity of a bulk Pd40Ni40P20 metallic glass. , 1986, Physical review. B, Condensed matter.

[86]  Weihua Wang,et al.  Enhanced thermal stability and microhardness in Zr-Ti-Cu-Ni-Be bulk amorphous alloy by carbon addition , 1997 .

[87]  J. L. Ding,et al.  Multi-magnetic phase behaviour of the Nd60Fe30Al10 amorphous hard magnetic alloy , 2001 .

[88]  Weihua Wang,et al.  Supersoftening of transverse phonons in Zr41Ti14Cu12.5Ni10Be22.5 bulk metallic glass , 2000 .

[89]  Michael Newton,et al.  Progess in superhydrophobic surface development. , 2008, Soft matter.

[90]  X. Zu,et al.  Large magnetic entropy change of Gd-based ternary bulk metallic glass in liquid-nitrogen temperature range , 2008 .

[91]  Weihua Wang,et al.  Intrinsic plasticity or brittleness of metallic glasses , 2005 .

[92]  Gang Wang,et al.  Super Plastic Bulk Metallic Glasses at Room Temperature , 2007, Science.

[93]  Non-Fermi-liquid behavior in U and Ce alloys: Criticality, disorder, dissipation, and Griffiths-McCoy singularities , 2000, cond-mat/0003085.

[94]  Qian Zhang,et al.  Irradiation induced amorphization in metallic multilayers and calculation of glass-forming ability from atomistic potential in the binary metal systems , 2000 .

[95]  Weihua Wang,et al.  Elastic constants and their pressure dependence of Zr41Ti14Cu12.5Ni9Be22.5C1 bulk metallic glass , 1999 .

[96]  X. Hui,et al.  Thermal stability and magnetocaloric properties of GdDyAlCo bulk metallic glasses , 2008 .

[97]  J. T. Krause,et al.  Elastic constants, hardness and their implications to flow properties of metallic glasses , 1975 .

[98]  Weihua Wang,et al.  Structural evolution and property changes in Nd60Al10Fe20Co10 bulk metallic glass during crystallization , 2002 .

[99]  D. Zhao,et al.  Formation and properties of Zr48Nb8Cu14Ni12Be18 bulk metallic glass , 2003 .

[100]  W. L. Wang,et al.  Doping-induced formation of bulk nanocrystalline alloy from metallic glass with controllable microstructure and properties , 2006 .

[101]  Remo Guidieri Res , 1995, RES: Anthropology and Aesthetics.

[102]  Weihua Wang,et al.  Nanocrystallization of ZrTiCuNiBeC bulk metallic glass under high pressure , 1999 .

[103]  A. Stoica,et al.  Power-law scaling and fractal nature of medium-range order in metallic glasses. , 2009, Nature materials.

[104]  A. L. Greer,et al.  Metallic glasses…on the threshold , 2009 .

[105]  Roughness effect on the measurement of interface stress , 2000 .

[106]  W. Wang,et al.  Nanoscale periodic morphologies on the fracture surface of brittle metallic glasses. , 2007, Physical review letters.

[107]  Jan Genzer,et al.  Recent developments in superhydrophobic surfaces and their relevance to marine fouling: a review , 2006, Biofouling.

[108]  Weihua Wang,et al.  Formation and properties of RE55Al25Co20 (RE = Y, Ce, La, Pr, Nd, Gd, Tb, Dy, Ho and Er) bulk metallic glasses , 2008 .

[109]  Weihua Wang,et al.  Properties of Ce-based bulk metallic glass-forming alloys , 2004 .

[110]  T. Hufnagel,et al.  Mechanical behavior of amorphous alloys , 2007 .

[111]  Weihua Wang,et al.  Excellent Wave Absorption by Zirconium‐Based Bulk Metallic Glass Composites Containing Carbon Nanotubes , 2003 .

[112]  Weihua Wang,et al.  Stability of ZrTiCuNiBe bulk metallic glass upon isothermal annealing near the glass transition temperature , 2002 .

[113]  K. Gschneidner,et al.  Influence of the crystalline electrical field on the magnetocaloric effect of DyAl 2 , ErAl 2 , and DyNi 2 , 1998 .

[114]  Weihua Wang,et al.  Magnetocaloric effect in Gd-based bulk metallic glasses , 2006 .

[115]  Weihua Wang,et al.  Response of acoustic and elastic properties to pressure and crystallization of Ce-based bulk metallic glass , 2005 .

[116]  Baixin Liu,et al.  Interatomic potentials of the binary transition metal systems and some applications in materials physics , 2008 .

[117]  Weihua Wang,et al.  Microstructure studies of Zr41Ti14Cu12.5Ni10Be22.5 bulk amorphous alloy by electron diffraction intensity analysis , 1997 .

[118]  W. Wang,et al.  Soft ytterbium-based bulk metallic glasses with strong liquid characteristic by design , 2009 .

[119]  W. L. Wang,et al.  Tb nanocrystalline array assembled directly from alloy melt , 2004 .

[120]  Weihua Wang,et al.  Relationship between glass transition temperature and Debye temperature in bulk metallic glasses , 2003 .

[121]  Weihua Wang,et al.  Giant enhancement of magnetocaloric effect in metallic glass matrix composite , 2008 .

[122]  Weihua Wang,et al.  Evolution of nanoscale morphology on fracture surface of brittle metallic glass , 2006 .

[123]  W. H. Li,et al.  Binary Ni-Nb bulk metallic glasses , 2006 .

[124]  Douglas C. Hofmann,et al.  Designing metallic glass matrix composites with high toughness and tensile ductility , 2008, Nature.

[125]  X. Bian,et al.  Prediction of glass-forming ability of metallic liquids , 2007 .

[126]  S. Sen,et al.  Observation of a pressure-induced first-order polyamorphic transition in a chalcogenide glass at ambient temperature. , 2006, Physical review letters.

[127]  J. Klein,et al.  Sliding friction with polymer brushes. , 2003, Physical review letters.

[128]  John J. Lewandowski,et al.  Mechanical Properties of Bulk Metallic Glasses , 2007 .

[129]  S. Schneider,et al.  Random anisotropy and domain-wall pinning process in the magnetic properties of rapidly quenched Nd60Fe30Al10 , 2003 .

[130]  W. Johnson,et al.  Mechanical properties of Zr_57Nb_5Al_10Cu_15.4Ni_12.6 metallic glass matrix particulate composites , 1999 .

[131]  Weihua Wang,et al.  Bulk metallic glasses based on binary cerium and lanthanum elements , 2007 .

[132]  G. Stewart Non-Fermi-liquid behavior in d- and f-electron metals , 2006 .

[133]  Weihua Wang,et al.  The excess wing of bulk metallic glass forming liquids , 2006 .

[134]  Robert D. Shull,et al.  Reduction of hysteresis losses in the magnetic refrigerant Gd5Ge2Si2 by the addition of iron , 2004, Nature.

[135]  H. P. Lee,et al.  Molecular dynamics simulation of a solid platinum nanowire under uniaxial tensile strain: Temperature and strain-rate effects , 2005 .

[136]  T. Schweizer,et al.  Metallic glass/polymer composites by co-processing at similar viscosities , 2007 .

[137]  Weihua Wang,et al.  Elastic property and its response to pressure in a typical bulk metallic glass , 2004 .

[138]  Weihua Wang,et al.  Superior glass-forming ability through microalloying in cerium-based alloys , 2006 .

[139]  Weihua Wang,et al.  A bulk metallic glass based on heavy rare earth gadolinium , 2005 .

[140]  Weihua Wang,et al.  Magnetocaloric effect of Ho-, Dy-, and Er-based bulk metallic glasses in helium and hydrogen liquefaction temperature range , 2007 .

[141]  Weihua Wang,et al.  Critical and slow dynamics in a bulk metallic glass exhibiting strong random magnetic anisotropy , 2008 .

[142]  Weihua Wang,et al.  Nd65Al10Fe25-xCox (x=0,5,10) bulk metallic glasses with wide supercooled liquid regions , 2001 .

[143]  Weihua Wang,et al.  Soft bulk metallic glasses based on cerium , 2004 .

[144]  W. Wang,et al.  Glass forming properties of Zr-based bulk metallic alloys , 2003 .

[145]  W. L. Wang,et al.  A highly glass-forming alloy with low glass transition temperature , 2003 .

[146]  Weihua Wang,et al.  Role of small atoms in the formation and properties of Zr-Ti-Cu-Ni-Be bulk amorphous alloys , 1998 .

[147]  Wence Wang Elastic moduli and behaviors of metallic glasses , 2005 .

[148]  W. Wang,et al.  Responses of glassy structure and properties to pressure and devitrification , 2003 .

[149]  C. Shek,et al.  Mechanical heterogeneity and mechanism of plasticity in metallic glasses , 2009 .

[150]  Osamu Shimomura,et al.  A first-order liquid–liquid phase transition in phosphorus , 2000, Nature.

[151]  T. Egami Universal criterion for metallic glass formation , 1997 .

[152]  Jian Xu,et al.  Formation of Bulk Metallic Glasses and Their Composites , 2007 .

[153]  A. Takeuchi,et al.  Gd–Co–Al and Gd–Ni–Al bulk metallic glasses with high glass forming ability and good mechanical properties , 2007 .

[154]  Yong Liu,et al.  Artificial neural network modeling of reduced glass transition temperature of glass forming alloys , 2008 .

[155]  A. Macfarlane,et al.  A World of Glass , 2004, Science.

[156]  A. Inoue,et al.  Carbon‐Nanotube‐Reinforced Zr‐Based Bulk Metallic Glass Composites and Their Properties , 2004 .

[157]  Weihua Wang,et al.  Equation of state of bulk metallic glasses studied by an ultrasonic method , 2001 .

[158]  P. L. Lee,et al.  Polyamorphism in a metallic glass. , 2007, Nature materials.

[159]  Weihua Wang,et al.  Hard and fragile holmium-based bulk metallic glasses , 2006 .

[160]  Rusong Wang,et al.  Shear modulus as a dominant parameter in glass transitions: Ultrasonic measurement of the temperature dependence of elastic properties of glasses , 2007 .

[161]  Shihui Bao,et al.  A new criterion for evaluating the glass-forming ability of bulk glass forming alloys , 2008 .

[162]  W. Wang,et al.  Fracture of brittle metallic glasses: brittleness or plasticity. , 2005, Physical review letters.

[163]  J. Eckert,et al.  Magnetic properties of Nd60-xYxFe30Al10 (x=0,10,30) melt-spun ribbons containing two amorphous magnetic phases , 2002 .

[164]  Youwei Du,et al.  Large Magnetic Entropy Change in Perovskite-Type Manganese Oxides , 1997 .

[165]  D. Thouless,et al.  Stability of the Sherrington-Kirkpatrick solution of a spin glass model , 1978 .

[166]  W. Wang,et al.  Ultrasonic investigation of Pd39Ni10Cu30P21 bulk metallic glass upon crystallization , 2000 .

[167]  Weihua Wang,et al.  Pressure Dependence of Elastic Constants and Debye Temperature for Zr_50.5Ti_4.8Cu_19.0Ni_11.4Al_14.3 Bulk Metallic Glass , 2002 .

[168]  J. Eckert,et al.  Coercivity mechanism in Nd 60 Fe 30 Al 10 and Nd 60 Fe 20 Co 10 Al 10 alloys , 2002 .

[169]  T. G. Nieh,et al.  Unified equation for the strength of bulk metallic glasses , 2006 .

[170]  Weihua Wang,et al.  Bulk metallic superconductive La60Cu20Ni10Al10 glass , 2005 .

[171]  Jianzhong Jiang,et al.  La-based bulk metallic glasses with critical diameter up to 30 mm , 2007 .

[172]  D. Zhao,et al.  Iron Based Alloy with Hierarchical Structure and Superior Mechanical Performance , 2008 .