In order to prepare for the next generation technology manufacturing, ASML and TEL are working together to investigate the process performance of the LITHIUSi+/ TWINSCAN XT:1700i lithocluster through decreasing critical dimension patterning. In this evaluation, process performance with regards to critical dimension uniformity and defectivity are compared at different critical dimensions in order to determine areas of concentration for equipment and process development. Specifically, design of experiments were run using immersion rinse processing at 60nm hp and 45nm hp. Defects were classified to generate a pareto for each technology node to see if there is any change in the defect types as critical dimensions are shrinking. Similarly, critical dimension uniformity was compared through technology nodes to see if any budget contributions have increased sensitivities to the smaller patterning features. Preliminary gauge studies were performed for the 45nm hp evaluation, as metrology at this design rule is not yet fully proven. More work is necessary to obtain complete understanding of metrology capabilities as this is crucial to discern precise knowledge of processing results. While preliminary results show no adverse impact moving forward, this work is a first screening of 45nm immersion processing and more work is needed to fully characterize and optimize the process to enable robust manufacturing at 45nm hp.