论文信息 - Improved preparations of ionic liquids using microwave irradiation

Improved preparations of ionic liquids using microwave irradiation

Controlled, multimode microwave irradiation has been employed in a generic solvent-free process to prepare a wide range of ionic liquids based on nitrogen-containing heterocycles. The developed method offers a flexible, small to large-scale approach to prepare ionic liquids, in either sealed or open vessels, in a faster and greener process than any previously described.

Maggel Deetlefs | K. Seddon | Maggel Deetlefs | Kenneth R. Seddon

[1] C. Gordon. New developments in catalysis using ionic liquids , 2001 .

[2] M. Grätzel,et al. Hydrophobic, Highly Conductive Ambient-Temperature Molten Salts. , 1996, Inorganic chemistry.

[3] R. Varma,et al. An improved preparation of 1,3-dialkylimidazolium tetrafluoroborate ionic liquids using microwaves☆ , 2002 .

[4] P. Wasserscheid,et al. Ionic Liquids-New "Solutions" for Transition Metal Catalysis. , 2000, Angewandte Chemie.

[5] Raymond J. Giguere,et al. Application of commercial microwave ovens to organic synthesis. , 1986 .

[6] A. Loupy,et al. Solvent-free microwave-assisted Beckmann rearrangement of benzaldehyde and 2-hydroxyacetophenone oximes , 1999 .

[7] A. Loupy,et al. Reactivity and selectivity under microwaves in organic chemistry. Relation with medium effects and reaction mechanisms , 2001 .

[8] J. Tierney,et al. Microwave assisted organic synthesis-a review , 2001 .

[9] R. Gedye,et al. The use of microwave ovens for rapid organic synthesis , 1986 .

[10] K. Seddon,et al. Influence of chloride, water, and organic solvents on the physical properties of ionic liquids , 2000 .

[11] Jean-Louis Luche,et al. Microwave activation in phase transfer catalysis , 1999 .