论文信息 - N-(3-Chlorophenyl)-4-methylbenzamide hemihydrate

N-(3-Chlorophenyl)-4-methylbenzamide hemihydrate

In the title compound, C14H12ClNO·0.5H2O, the water molecule is located on a twofold axis of symmetry. The meta-Cl atom in the aniline ring is positioned anti to the N—H bond. The two benzene rings make a dihedral angle of 40.40 (11)°. The crystal structure is stabilized by intermolecular N—H⋯O and O—H⋯O hydrogen bonds, which link the molecules into chains along the a axis.

B. Thimme Gowda | Jozef Kožíšek | Vinola Z. Rodrigues | Lenka Kucková

[1] B. Thimme Gowda,et al. N-(2-Chlorophenyl)-4-methylbenzamide , 2011, Acta crystallographica. Section E, Structure reports online.

[2] Erdal Bedir,et al. Two New Iridoid Glucosides from Verbascum salviifolium Boiss. , 2005 .

[3] B. Thimme Gowda,et al. Kinetics of oxidation of acidic amino acids and their monoamides by N‐chloroarylsulphonamides in aqueous acidic medium , 2004 .

[4] Owen Johnson,et al. CIF applications. XV. enCIFer: a program for viewing, editing and visualizing CIFs , 2004 .

[5] Christopher Glidewell,et al. A triclinic polymorph of benzanilide: disordered molecules form hydrogen-bonded chains. , 2003, Acta crystallographica. Section C, Crystal structure communications.

[6] J. S. Reid,et al. The Analytical Calculation of Absorption in Multifaceted Crystals , 1995 .

[7] Jim Simpson,et al. A monoclinic polymorph of N-(3-chlorophenyl)benzamide , 2010, Acta crystallographica. Section E, Structure reports online.

[8] B. Thimme Gowda,et al. N‐(4‐Fluorophenyl)methanesulfonamide , 2007 .

[9] 良二上田. J. Appl. Cryst.の発刊に際して , 1970 .

[10] G. Sheldrick. A short history of SHELX. , 2008, Acta crystallographica. Section A, Foundations of crystallography.