Na3(VO)(PO4)(CO3): a synthetic member of the bradleyite phosphate carbonate family with a new type of crystal structure

The synthesis and characterization of a (VO)2+ representative in the bradleyite family of compounds is reported. The character of the Na atom distribution in the structure allows considering Na3(VO)(PO4)(CO3) as a potential cathode material.

[1]  K. Abraham.  How Comparable Are Sodium-Ion Batteries to Lithium-Ion Counterparts? , 2020 .

[2]  S. Okada,et al.  Exploring Factors Limiting Three-Na+ Extraction from Na3V2(PO4)3 , 2020, Electrochemistry.

[3]  Xiaoqi Sun,et al.  The Development of Vanadyl Phosphate Cathode Materials for Energy Storage Systems: A Review. , 2020, Chemistry.

[4]  Xiulei Ji,et al.  NASICON‐Structured Materials for Energy Storage , 2017, Advanced materials.

[5]  E. Salager,et al.  Understanding Local Defects in Li-Ion Battery Electrodes through Combined DFT/NMR Studies: Application to LiVPO4F , 2017 .

[6]  Guohua Chen,et al.  In-situ hydrothermal synthesis of Na3MnCO3PO4/rGO hybrid as a cathode for Na-ion battery , 2016 .

[7]  S. Dou,et al.  Tuned In Situ Growth of Nanolayered rGO on 3D Na3V2(PO4)3 Matrices: A Step toward Long Lasting, High Power Na‐Ion Batteries , 2016 .

[8]  O. Volkova,et al.  A cesium copper vanadyl-diphosphate: Synthesis, crystal structure and physical properties , 2015 .

[9]  Xiaobo Ji,et al.  Investigation of the sodium ion pathway and cathode behavior in Na₃V₂(PO₄)₂F₃ combined via a first principles calculation. , 2014, Langmuir : the ACS journal of surfaces and colloids.

[10]  A. P. Shevchenko,et al.  Applied Topological Analysis of Crystal Structures with the Program Package ToposPro , 2014 .

[11]  Weifeng Huang,et al.  Detailed investigation of Na2.24FePO4CO3 as a cathode material for Na-ion batteries , 2014, Scientific Reports.

[12]  Mikael Höök,et al.  Lithium availability and future production outlooks , 2013 .

[13]  K. Kang,et al.  A new high-energy cathode for a Na-ion battery with ultrahigh stability. , 2013, Journal of the American Chemical Society.

[14]  Gerbrand Ceder,et al.  Synthesis, computed stability, and crystal structure of a new family of inorganic compounds: carbonophosphates. , 2012, Journal of the American Chemical Society.

[15]  Dong-Hwa Seo,et al.  A combined first principles and experimental study on Na3V2(PO4)2F3 for rechargeable Na batteries , 2012 .

[16]  Anubhav Jain,et al.  Novel mixed polyanions lithium-ion battery cathode materials predicted by high-throughput ab initio computations , 2011 .

[17]  Jean-Marie Tarascon,et al.  Crystal structure and electrochemical properties vs. Na+ of the sodium fluorophosphate Na1.5VOPO4F0.5 , 2006 .

[18]  M. Whittingham,et al.  Some transition metal (oxy)phosphates and vanadium oxides for lithium batteries , 2005 .

[19]  V. Blatov.  Voronoi–dirichlet polyhedra in crystal chemistry: theory and applications , 2004 .

[20]  W. H. Baur,et al.  Crystal Chemical Aspects of Vanadium: Polyhedral Geometries, Characteristic Bond Valences, and Polymerization of (VOn) Polyhedra , 2000 .

[21]  A. Khomyakov.  Bonshtedtite, Na3Fe(PO4)(CO3) — a new mineral , 1983 .

[22]  A. Khomyakov.  Sidorenkite, Na3Mn (PO4) (CO3), a new mineral , 1980 .

[23]  Vladislav A. Blatov,et al.  Crystallochemical tools in the search for cathode materials of rechargeable Na-ion batteries and analysis of their transport properties , 2018 .

[24]  J. Costa Pessoa.  Thirty years through vanadium chemistry. , 2015, Journal of inorganic biochemistry.

[25]  K. Kubota,et al.  Review-Practical Issues and Future Perspective for Na-Ion Batteries , 2015 .

[26]  O. Yakubovich,et al.  A new type of mixed anionic framework in microporous caesium titanium vanadyl(V) phosphate Cs2[Ti(VO2)3(PO4)3] , 2006 .