A Triboelectric Energy Harvester Using Low-Cost, Flexible, and Biocompatible Ethylene Vinyl Acetate (EVA)

In this paper, we propose a triboelectric energy harvester (EH) using ethylene vinyl acetate (EVA) polymer for the first time. EVA acts as a polymer with positive electrification properties against metals such as gold and aluminum. The EVA sheet provides us with a low-cost EH as the usage of already roll-to-roll-patterned sheet enables us to avoid the common expensive patterning methods for introducing the required roughness to the EH device. Moreover, the biocompatibility and flexibility of EVA makes it a suitable candidate for future implantation of this EH inside body. The transparency of EVA helps us to design the EVA-based EHs in different configurations for the characterization with two types of setups. The proposed new mass-tapping and detachment setups for the EVA EHs bring us more effective methods to quantitatively investigate important properties of EH while resembling the daily motions of a living being rather than using motorized characterization methods.

[1]  U. Frick,et al.  [Implant materials]. , 1983, Zahntechnik; Zeitschrift fur Theorie und Praxis der wissenschaftlichen Zahntechnik.

[2]  Zhong Lin Wang,et al.  Water-solid surface contact electrification and its use for harvesting liquid-wave energy. , 2013, Angewandte Chemie.

[3]  Zhong Lin Wang,et al.  Triboelectric nanogenerator built inside clothes for self-powered glucose biosensors , 2013 .

[4]  Jeffrey T Borenstein,et al.  Biodegradable microfluidic scaffolds for tissue engineering from amino alcohol-based poly(ester amide) elastomers , 2010, Organogenesis.

[5]  W. Kao,et al.  Drug release kinetics and transport mechanisms of non-degradable and degradable polymeric delivery systems , 2010, Expert opinion on drug delivery.

[6]  Long Lin,et al.  Simulation method for optimizing the performance of an integrated triboelectric nanogenerator energy harvesting system , 2014 .

[7]  Zhong Lin Wang,et al.  Triboelectric nanogenerator built inside shoe insole for harvesting walking energy , 2013 .

[8]  Justin C. Williams,et al.  Flexible polyimide-based intracortical electrode arrays with bioactive capability , 2001, IEEE Transactions on Biomedical Engineering.

[9]  Padmavathy Tallury,et al.  Poly(ethylene-co-vinyl acetate) copolymer matrix for delivery of chlorhexidine and acyclovir drugs for use in the oral environment: effect of drug combination, copolymer composition and coating on the drug release rate. , 2007, Dental materials : official publication of the Academy of Dental Materials.

[10]  Yadong Jiang,et al.  Fully enclosed cylindrical single-electrode-based triboelectric nanogenerator. , 2014, ACS applied materials & interfaces.

[11]  Weiqing Yang,et al.  Broadband Vibrational Energy Harvesting Based on a Triboelectric Nanogenerator , 2014 .

[12]  R. Adhikari,et al.  Biodegradable synthetic polymers for tissue engineering. , 2003, European cells & materials.

[13]  I. O. Salyer,et al.  Structure and property relationships in ethylene–vinyl acetate copolymers , 1971 .

[14]  Jun Chen,et al.  Harmonic‐Resonator‐Based Triboelectric Nanogenerator as a Sustainable Power Source and a Self‐Powered Active Vibration Sensor , 2013, Advanced materials.

[15]  R. Langer,et al.  Zero-order controlled-release polymer matrices for micro- and macromolecules. , 1983, Journal of pharmaceutical sciences.

[16]  Zhong Lin Wang,et al.  Rotary triboelectric nanogenerator based on a hybridized mechanism for harvesting wind energy. , 2013, ACS nano.

[17]  Xiao-Sheng Zhang,et al.  Wearable electrode-free triboelectric generator for harvesting biomechanical energy , 2015 .

[18]  Joon B. Park Tissue Response to Implants , 1979 .

[19]  Zhong Lin Wang,et al.  Sliding-triboelectric nanogenerators based on in-plane charge-separation mechanism. , 2013, Nano letters.

[20]  D. Beebe,et al.  PDMS absorption of small molecules and consequences in microfluidic applications. , 2006, Lab on a chip.

[21]  Long Lin,et al.  Motion charged battery as sustainable flexible-power-unit. , 2013, ACS nano.

[22]  S. Sethuraman,et al.  Biomedical Applications of Nondegradable Polymers , 2014 .

[23]  A. Gobbi,et al.  Doping of a dielectric layer as a new alternative for increasing sensitivity of the contactless conductivity detection in microchips. , 2011, Lab on a chip.

[24]  Ruomeng Yu,et al.  Electret film-enhanced triboelectric nanogenerator matrix for self-powered instantaneous tactile imaging. , 2014, ACS applied materials & interfaces.

[25]  Myeong-Lok Seol,et al.  Nature-replicated nano-in-micro structures for triboelectric energy harvesting. , 2014, Small.

[26]  Zhong Lin Wang,et al.  Transparent triboelectric nanogenerators and self-powered pressure sensors based on micropatterned plastic films. , 2012, Nano letters.

[27]  Sihong Wang,et al.  Freestanding Triboelectric‐Layer‐Based Nanogenerators for Harvesting Energy from a Moving Object or Human Motion in Contact and Non‐contact Modes , 2014, Advanced materials.

[28]  Zhong Lin Wang,et al.  Toward large-scale energy harvesting by a nanoparticle-enhanced triboelectric nanogenerator. , 2013, Nano letters.

[29]  Weiqi Wang,et al.  High-performance triboelectric nanogenerator with enhanced energy density based on single-step fluorocarbon plasma treatment , 2014 .

[30]  Zhong Lin Wang,et al.  Flexible triboelectric generator , 2012 .

[31]  Sabu Thomas,et al.  Dynamic mechanical behavior of high‐density polyethylene/ethylene vinyl acetate copolymer blends: The effects of the blend ratio, reactive compatibilization, and dynamic vulcanization , 2003 .

[32]  Tay Investigation of contact electrification based broadband energy harvesting mechanism using elastic PDMS microstructures , 2014 .

[33]  A. Diaz,et al.  A semi-quantitative tribo-electric series for polymeric materials: the influence of chemical structure and properties , 2004 .

[34]  Yong Qin,et al.  An electrospun nanowire-based triboelectric nanogenerator and its application in a fully self-powered UV detector. , 2014, Nanoscale.

[35]  Chengkuo Lee,et al.  Development of a Broadband Triboelectric Energy Harvester With SU-8 Micropillars , 2015, Journal of Microelectromechanical Systems.