Conventional E-glass fibre light guides: self-sensing composite based on sol–gel cladding

The aim of this study was to modify conventional reinforcing E-glass fibres to enable them to act as optical waveguides and subsequently as sensor devices. This required the glass fibres to be coated with a relatively homogeneous coating with a corresponding refractive index that was lower than the E-glass fibre (1.56). Although a range of coating materials are available, this study focused on using materials that are generally used as sizing agents for glass fibres to improve the adhesion to the matrix. Two different methods based on conventional sol–gel processing were used to obtain crack-free coatings. In the first method, tetraethoxysilane (TEOS) and polyvinyl alcohol were used as precursors. In the second method, acid-catalysed solutions of TEOS mixed with 3-glycidoxypropyltrimethoxysilane were used as precursors. UV–visible transmission results showed that the films had low absorption and high transparency in the visible range. The refractive indices of the films were found to be a function of the molar fractions of the major chemical components. A simple impregnation procedure was used to apply the coating to the E-glass fibre bundles. The light transmission characteristics of the coated fibres along with their mechanical properties were evaluated. The sol–gel coatings were shown to be effective in converting the conventional E-glass fibres into light guides.

[1]  Lisa C. Klein,et al.  Sol-gel optics: processing and applications , 1994 .

[2]  Seung‐Man Yang,et al.  Preparation of silica-based hybrid materials coated on polypropylene film , 1999 .

[3]  P. Prasad,et al.  Fabrication of channel waveguides from sol-gel-processed polyvinylpyrrolidone/ SiO(2) composite materials. , 1996, Applied optics.

[4]  W. Ren,et al.  New method for making porous SiO2 thin films , 1999 .

[5]  Y. Chan,et al.  OPTICAL AND MECHANICAL PROPERTIES OF TIO2/SIO2/ORGANICALLY MODIFIED SILANE COMPOSITE FILMS PREPARED BY SOL–GEL PROCESSING , 2000 .

[6]  B. E. Yoldas Hydrolysis of titanium alkoxide and effects of hydrolytic polycondensation parameters , 1986 .

[7]  Lisa C. Klein,et al.  Sol-Gel Optics , 1994 .

[8]  Mike Gilmore Fibre optic cabling: Theory, design, and installation practice , 1991 .

[9]  Shlomo Ruschin,et al.  Sol‐gel glass waveguides prepared at low temperature , 1993 .

[10]  G. Scherer Aging and drying of gels , 1988 .

[11]  M. Anderson,et al.  Microporous silica membranes deposited on porous supports by filtration , 1996 .

[12]  Koji Nakane,et al.  Formation of a compatible composite of silica/poly(vinyl alcohol) through the sol-gel process and a calcinated product of the composite , 1996, Journal of Materials Science.

[13]  Renata Reisfeld,et al.  Organic fluorescent dyes trapped in silica and silica-titania thin films by the sol-gel method: photophysical, film and cage properties , 1985 .

[14]  Gerard Franklyn Fernando,et al.  A Chemical Sensor Based on Conventional Reinforcing E-Glass Fibres , 2001 .

[15]  B. Novak,et al.  "Inverse" organic-inorganic composite materials. 3. High glass content "nonshrinking" sol-gel composites via poly(silicic acid esters) , 1993 .

[16]  Yen Wei,et al.  Organic-inorganic hybrid materials: relations of thermal and mechanical properties with structures , 1998 .

[17]  K. Uematsu,et al.  Chemical effects of DCCA to the sol-gel reaction process , 1994 .

[18]  Sumio Sakka,et al.  Dependence of the elastic moduli of porous silica gel prepared by the sol-gel method on heat-treatment , 1990 .

[19]  D. Roylance INTRODUCTION TO COMPOSITE MATERIALS , 2000 .

[20]  D. Uhlmann,et al.  Optical loss study of MPEOU-based polyceram planar waveguides. , 1995, Applied optics.

[21]  Yen Wei,et al.  A fast convenient method to prepare hybrid sol-gel materials with low volume-shrinkages , 1996 .

[22]  V. Srivastava Acousto-ultrasonic evaluation of interface bond strength of coated glass fibre-reinforced epoxy resin composites , 1995 .

[23]  Gerard Franklyn Fernando,et al.  A multi-mode extrinsic Fabry-Pérot interferometric strain sensor , 1997 .

[24]  Gerard Franklyn Fernando,et al.  In situ self-sensing fibre reinforced composites , 1997 .

[25]  Yi Hu,et al.  Rubber-like elasticity of organically modified silicates , 1992, Journal of Materials Science.

[26]  M. Castaings,et al.  Lamb and SH waves generated and detected by air-coupled ultrasonic transducers in composite material plates , 2001 .