论文信息 - [μ-Bis(diphenylphosphanyl)ethane-1:2κ2 P:P′]nonacarbonyl-1κ3 C,2κ3 C,3κ3 C-[tris(4-(methoxyphenyl)arsane-3κAs]-triangulo-triruthenium(0) chloroform monosolvate

[μ-Bis(diphenylphosphanyl)ethane-1:2κ2 P:P′]nonacarbonyl-1κ3 C,2κ3 C,3κ3 C-[tris(4-(methoxyphenyl)arsane-3κAs]-triangulo-triruthenium(0) chloroform monosolvate

The asymmetric unit of the title triangulo-triruthenium compound, [Ru3(C21H21AsO3)(C26H24P2)(CO)9]·CHCl3, consists of one molecule of the triangulo-triruthenium complex and one chloroform solvent molecule. The bis(diphenylphosphanyl)ethane ligand bridges an Ru—Ru bond and the monodentate arsane ligand bonds to the third Ru atom. Both the arsane and phosphine ligands are equatorial with respect to the Ru3 triangle. Additionally, each Ru atom carries one equatorial and two axial terminal carbonyl ligands. The three arsane-substituted benzene rings make dihedral angles of 52.72 (19), 63.03 (19) and 88.19 (19)° with each other. The dihedral angles between the two benzene rings are 85.8 (2) and 89.2 (2)° for the two diphenylphosphanyl groups. In the crystal, molecules are linked together into a three-dimensional network via intermolecular C—H⋯O hydrogen bonds. Weak intermolecular C—H⋯π interactions further stabilize the crystal structure.

Chin Sing Yeap | Siti Syaida Sirat | H. Fun | O. Shawkataly | I. Khan

[1] G. Sheldrick. A short history of SHELX. , 2008, Acta crystallographica. Section A, Foundations of crystallography.

[2] H. Fun,et al. Sb–C Bond Cleavage Reaction on a Triruthenium Cluster and the Formation of a Bridging Phenylacyl Unit , 2004 .

[3] K. Sivakumar,et al. Synthesis and spectral studies on Ru3(CO)12−n(μ-Ph2AsCH2AsPh2)(L) (n = 3, L : PPh3, PCy2Ph,P(OCH3)3); n = 4, L = Ph2PCH2PPh2) : crystal and molecular structures of Ru3(CO)9(μ-Ph2AsCH2AsPh2)(PCy2Ph) and Ru3(CO)8(μ-Ph2AsCH2AsCH2AsPh2)μ-Ph2PCH2PPh2) , 1998 .

[4] M. Liddell,et al. Cluster chemistry: LVI. Stereochemistry of group 15 ligand-substituted derivatives of M3(CO)12 (M = Ru, Os) B. X-Ray structures of six complexes M3(CO)10(L)2 (M = Ru, L = PPh3, PPh(OMe)2, and P(OCH2CF3)3; M = Os, L = PPh3, PPh(OMe)2 and P(OMe)3) , 1988 .

[5] M. Liddell,et al. Cluster chemistry. LVII: Stereochemistry of group 15 ligand-substituted derivatives of M3(CO)12 (M=Ru, Os). C. X-ray structures of Ru3(CO)9(L)3 (L=PMe2(CH2Ph), PMe2Ph, AsMe2Ph, PPh(OMe)2, P(OEt)3, and P(OCH2CF3)3) and Os3(CO)9(PPh3)3 , 1988 .

[6] A. M. Glazer,et al. A nitrogen‐gas‐stream cryostat for general X‐ray diffraction studies , 1986 .

[7] J. Matisons,et al. Cluster Chemistry: XVII.Radical ion-initiated synthesis of ruthenium cluster carbonyls containing tertiary phosphines, phosphites, arsines, SbPh3, or isocyanides☆ , 1983 .