Structural, Magnetic and Dynamic Mechanical Analysis of Magnetic Nanocomposite Foils by Polymer Ultrasonic Welding

The main goal of the work presented in this paper is to develop and characterize a manufacturing process that introduces a novel technology for manufacturing magnetic polyvinylchloride (PVC) nanocomposites, from stacked PVC foils, with intermediate sandwiched layers of uniformly dispersed ferro magnetic nanoparticles, by means of solid-state surface ultrasonic welding. Laboratory analysis of nanocomposite samples to investigate their behavior, is performed by microscopic, magnetic, and mechanical testing. Transmission electron microscopy (TEM) and scanning electron microscopy (SEM) are employed for measuring nanoparticle dispersions and their distribution in the polymer matrix. The magnetic properties of the composites are measured by a physical property measurement system (PPMS), while mechanical behavior is studied by dynamic mechanical analyzer (DMA) and a universal mechanical testing system. The resulting materials are nanocomposite foils with very high ferromagnetic behavior.

[1]  O. Rodríguez-Fernández,et al.  Preparation and characterization of a magneto-polymeric nanocomposite: Fe3O4 nanoparticles in a grafted, cross-linked and plasticized poly(vinyl chloride) matrix , 2008 .

[2]  O. Rodríguez-Fernández,et al.  Preparation and characterization of magnetic PVC nanocomposites , 2007 .

[3]  O. Marinică,et al.  Sterically stabilized water based magnetic fluids : Synthesis, structure and properties , 2007 .

[4]  Charles E. Wilkes,et al.  PVC Handbook , 2005 .

[5]  Carlos Luna,et al.  MAGNETIC NANOPARTICLES, SYNTHESIS, ORDERING AND PROPERTIES , 2004 .

[6]  Jae Heung Lee,et al.  Enhancement of the thermal stability, mechanical properties and morphologies of recycled PVC/clay nanocomposites , 2004 .

[7]  Y. Mai,et al.  Rheological And Mechanical Properties Of Pvc/Caco3 Nanocomposites Prepared By In Situ Polymerization , 2004 .

[8]  L. Vékás,et al.  Magnetizable colloids on strongly polar carriers – preparation and manifold characterization , 2004 .

[9]  S. Odenbach Ferrofluids—magnetically controlled suspensions , 2003 .

[10]  L. Vékás,et al.  Preparation and magnetic properties of concentrated magnetic fluids on alcohol and water carrier liquids , 2002 .

[11]  C. Mijangos,et al.  Preparation and characterization of polystyrene‐based magnetic nanocomposites. Thermal, mechanical and magnetic properties , 2001 .

[12]  B. Goswami,et al.  Studies on the Process of Ultrasonic Bonding of Nonwovens: Part 1 — Theoretical Analysis , 2001 .

[13]  H. V. Swygenhoven,et al.  Influence of grain size and oxidation on the magnetic properties of nanostructured Fe and Ni , 1997 .

[14]  R. E. Watson,et al.  Magnetocaloric effect in superparamagnets , 1992 .

[15]  Timothy G. Gutowski,et al.  Ultrasonic welding of PEEK graphite APC-2 composites , 1989 .

[16]  A. Benatar,et al.  Ultrasonic welding of thermoplastics in the near‐field , 1989 .

[17]  Madhan Shridhar Phadke,et al.  Quality Engineering Using Robust Design , 1989 .

[18]  M. S. Phadke,et al.  Quality Engineering using Design of Experiments , 1989 .

[19]  P. Dawson,et al.  Heating and bonding mechanisms in ultrasonic welding of thermoplastics , 1983 .