Deoxygenative Silylation of C(sp3)–O Bonds with Hydrosilane by Cooperative Catalysis of Gold Nanoparticles and Solid Acids

[1]  H. Miura,et al.  Diverse Alkyl-Silyl Cross-Coupling via Homolysis of Unactivated C(sp3)-O Bonds with the Cooperation of Gold Nanoparticles and Amphoteric Zirconium Oxides. , 2023, Journal of the American Chemical Society.

[2]  Runsen Zhang,et al.  Cross-cutting scenarios and strategies for designing decarbonization pathways in the transport sector toward carbon neutrality , 2022, Nature Communications.

[3]  Q. Song,et al.  Synthesis of α-Aminosilanes by 1,2-Metalate Rearrangement Deoxygenative Silylation of Aromatic Amides. , 2022, Organic letters.

[4]  A. Osman,et al.  Strategies to achieve a carbon neutral society: a review , 2022, Environmental Chemistry Letters.

[5]  M. Obersteiner,et al.  The meaning of net zero and how to get it right , 2021, Nature Climate Change.

[6]  T. Marks,et al.  Efficient Polyester Hydrogenolytic Deconstruction via Tandem Catalysis. , 2021, Angewandte Chemie.

[7]  S. Newman,et al.  Nickel-Catalyzed Reductive Deoxygenation of Diverse C–O Bond-Bearing Functional Groups , 2021, ACS Catalysis.

[8]  Daniel C W Tsang,et al.  Technologies and perspectives for achieving carbon neutrality , 2021, Innovation.

[9]  H. Miura,et al.  Electrophilic C(sp2)−H Silylation by Supported Gold Catalysts , 2021 .

[10]  Y. Nakao,et al.  Selective C-O Bond Reduction and Borylation of Aryl Ethers Catalyzed by a Rhodium-Aluminum Heterobimetallic Complex. , 2021, Journal of the American Chemical Society.

[11]  H. Miura,et al.  Metal–support cooperation in Al(PO3)3-supported platinum nanoparticles for the selective hydrogenolysis of phenols to arenes , 2021, Nature Catalysis.

[12]  Y. Kondo,et al.  Di-tert-butyl Peroxide (DTBP)-Mediated Oxysilylation of Unsaturated Carboxylic Acids for the Synthesis of Silyl Lactones. , 2020, Organic letters.

[13]  N. Garg,et al.  Activation of C-O and C-N Bonds Using Non-Precious-Metal Catalysis. , 2020, ACS catalysis.

[14]  Chao‐Jun Li,et al.  Transformations of Less-Activated Phenols and Phenol Derivatives via C-O Cleavage. , 2020, Chemical reviews.

[15]  T. Marks,et al.  Polyethylene Terephthalate Deconstruction Catalyzed by a Carbon-Supported Single-Site Molybdenum-dioxo Complex. , 2020, Angewandte Chemie.

[16]  L. Avram,et al.  Hydrogenative Depolymerization of Nylons , 2020, Journal of the American Chemical Society.

[17]  C. Mora,et al.  The tree-lined path to carbon neutrality , 2020, Nature Reviews Earth & Environment.

[18]  M. Willis,et al.  Silyl Radical-Mediated Activation of Sulfamoyl Chlorides Enables Direct Access to Aliphatic Sulfonamides from Alkenes. , 2019, Journal of the American Chemical Society.

[19]  T. Loh,et al.  Copper‐Catalyzed Asymmetric Silylation of Propargyl Dichlorides: Access to Enantioenriched Functionalized Allenylsilanes , 2019, Angewandte Chemie.

[20]  A. Ballesteros,et al.  Propargylsilanes as Reagents for Synergistic Gold(I)-Catalyzed Propargylation of Carbonyl Compounds: Isolation and Characterization of σ-Gold(I) Allenyl Intermediates. , 2019, Angewandte Chemie.

[21]  I. Lykakis,et al.  Nanogold(0)-Catalyzed Addition of Heteroelement σ Linkages to Functional Groups , 2019, Synthesis.

[22]  Y. Diskin‐Posner,et al.  Highly Selective, Efficient Deoxygenative Hydrogenation of Amides Catalyzed by a Manganese Pincer Complex via Metal–Ligand Cooperation , 2018, ACS catalysis.

[23]  T. Cantat,et al.  Depolymerization of Waste Plastics to Monomers and Chemicals Using a Hydrosilylation Strategy Facilitated by Brookhart’s Iridium(III) Catalyst , 2018, ACS Sustainable Chemistry & Engineering.

[24]  S. Saravanamurugan,et al.  Control of selectivity in hydrosilane-promoted heterogeneous palladium-catalysed reduction of furfural and aromatic carboxides , 2018, Communications Chemistry.

[25]  Z. Yao,et al.  Radical Hydrosilylation of Alkynes Catalyzed by Eosin Y and Thiol under Visible Light Irradiation. , 2018, Organic letters.

[26]  Xiaoxu Yang,et al.  Dichotomy of Manganese Catalysis via Organometallic or Radical Mechanism: Stereodivergent Hydrosilylation of Alkynes. , 2018, Angewandte Chemie.

[27]  Jie Wu,et al.  Visible-Light-Mediated Metal-Free Hydrosilylation of Alkenes through Selective Hydrogen Atom Transfer for Si-H Activation. , 2017, Angewandte Chemie.

[28]  M. Szostak,et al.  Iron-Catalyzed C-O Bond Activation: Opportunity for Sustainable Catalysis. , 2017, ChemSusChem.

[29]  S. Luo,et al.  Iron-Catalyzed Intermolecular 1,2-Difunctionalization of Styrenes and Conjugated Alkenes with Silanes and Nucleophiles. , 2017, Angewandte Chemie.

[30]  T. Hiyama,et al.  Recent Progress in the Cross-Coupling Reaction Using Triorganosilyl-Type Reagents , 2017, Synlett.

[31]  I. Chatterjee,et al.  B(C6 F5 )3 -Catalyzed Chemoselective Defunctionalization of Ether-Containing Primary Alkyl Tosylates with Hydrosilanes. , 2017, Angewandte Chemie.

[32]  M. Stratakis,et al.  Gold-Nanoparticle-Catalyzed Silaboration of Oxetanes and Unactivated Epoxides , 2016 .

[33]  B. Yoo,et al.  Deoxygenative silylation of aromatic carbonyl compounds with HSiCl3 in the presence of quaternary phosphonium chloride: A facile route to arylmethyltrichlorosilane , 2016 .

[34]  G. Huber,et al.  Catalytic Transformation of Lignin for the Production of Chemicals and Fuels. , 2015, Chemical reviews.

[35]  Zheng Xu,et al.  Recent Advances in Transition-Metal-Catalyzed Silylations of Arenes with Hydrosilanes: C–X Bond Cleavage or C–H Bond Activation Synchronized with Si–H Bond Activation , 2015, Synthesis.

[36]  F. Chemla,et al.  Ring‐Opening of N‐tert‐Butanesulfinylethynylaziridines with Lithium Tris(dimethylphenylsilyl)zincate: Stereoselective Access to 4‐Amino‐1‐allenylsilanes , 2015 .

[37]  M. Stratakis,et al.  Ligandless Regioselective Hydrosilylation of Allenes Catalyzed by Gold Nanoparticles. , 2015, Organic letters.

[38]  N. Chatani,et al.  Cross-Couplings Using Aryl Ethers via C-O Bond Activation Enabled by Nickel Catalysts. , 2015, Accounts of chemical research.

[39]  K. Tomishige,et al.  Catalytic total hydrodeoxygenation of biomass-derived polyfunctionalized substrates to alkanes. , 2015, ChemSusChem.

[40]  I. Lykakis,et al.  Efficient hydrosilylation of carbonyl compounds by 1,1,3,3-tetramethyldisiloxane catalyzed by Au/TiO2 , 2014 .

[41]  Nick Cox,et al.  NHC–copper hydrides as chemoselective reducing agents: catalytic reduction of alkynes, alkyl triflates, and alkyl halides , 2014 .

[42]  Nick Cox,et al.  Copper-catalyzed reduction of alkyl triflates and iodides: an efficient method for the deoxygenation of primary and secondary alcohols. , 2014, Angewandte Chemie.

[43]  H. Kominami,et al.  Visible-light-induced hydrogen and oxygen formation over Pt/Au/WO₃ photocatalyst utilizing two types of photoabsorption due to surface plasmon resonance and band-gap excitation. , 2014, Journal of the American Chemical Society.

[44]  B. König,et al.  Reductive Deoxygenation of Alcohols: Catalytic Methods Beyond Barton–McCombie Deoxygenation , 2013 .

[45]  K. Tomishige,et al.  Catalytic Reduction of Biomass-Derived Furanic Compounds with Hydrogen , 2013 .

[46]  J. Hartwig,et al.  A heterogeneous nickel catalyst for the hydrogenolysis of aryl ethers without arene hydrogenation. , 2012, Journal of the American Chemical Society.

[47]  Akira Ohnuma,et al.  Gold-titanium(IV) oxide plasmonic photocatalysts prepared by a colloid-photodeposition method: correlation between physical properties and photocatalytic activities. , 2012, Langmuir : the ACS journal of surfaces and colloids.

[48]  M. Oestreich,et al.  Copper(I)-catalyzed regio- and chemoselective single and double addition of nucleophilic silicon to propargylic chlorides and phosphates. , 2012, Organic letters.

[49]  M. Oestreich,et al.  Copper(I)-catalyzed regioselective propargylic substitution involving Si-B bond activation. , 2011, Organic letters.

[50]  I. Lykakis,et al.  Oxidative cycloaddition of 1,1,3,3-tetramethyldisiloxane to alkynes catalyzed by supported gold nanoparticles. , 2011, Journal of the American Chemical Society.

[51]  Da‐Gang Yu,et al.  Activation of "inert" alkenyl/aryl C-O bond and its application in cross-coupling reactions. , 2011, Chemistry.

[52]  M. Brookhart,et al.  Hydrosilation of Carbonyl-Containing Substrates Catalyzed by an Electrophilic η-Silane Iridium(III) Complex. , 2010, Organometallics.

[53]  Da‐Gang Yu,et al.  Exploration of new C-O electrophiles in cross-coupling reactions. , 2010, Accounts of chemical research.

[54]  H. Ohmiya,et al.  Selective synthesis of allenes and alkynes through ligand-controlled, palladium-catalyzed decarboxylative hydrogenolysis of propargylic formates. , 2010, Organic letters.

[55]  H. Ohmiya,et al.  General and functional group-tolerable approach to allenylsilanes by rhodium-catalyzed coupling between propargylic carbonates and a silylboronate. , 2009, Organic letters.

[56]  B. Lipshutz,et al.  (NHC)CuH-catalyzed entry to allenes via propargylic carbonate S(N)2'-reductions. , 2009, Organic letters.

[57]  Y. Sasaki,et al.  The synthesis of allenes by Cu(I)-catalyzed regio- and stereoselective reduction of propargylic carbonates with hydrosilanes. , 2009, Chemical communications.

[58]  P. White,et al.  Scope and mechanism of the iridium-catalyzed cleavage of alkyl ethers with triethylsilane. , 2008, Journal of the American Chemical Society.

[59]  J. Panek,et al.  Preparation and use of enantioenriched allenylsilanes for the stereoselective synthesis of homopropargylic ethers. , 2007, Organic letters.

[60]  B. Lipshutz,et al.  Small but Effective: Copper Hydride Catalyzed Synthesis of α‐Hydroxyallenes , 2007 .

[61]  H. Sundén,et al.  Palladium pincer complex catalyzed stannyl and silyl transfer to propargylic substrates: synthetic scope and mechanism. , 2005, Journal of the American Chemical Society.

[62]  H. Sundén,et al.  Palladium pincer complex-catalyzed trimethyltin substitution of functionalized propargylic substrates. An efficient route to propargyl- and allenyl-stannanes. , 2004, Journal of the American Chemical Society.

[63]  A. Studer,et al.  Radical transfer hydrosilylation/cyclization using silylated cyclohexadienes. , 2001, Organic letters.

[64]  S. Weinreb,et al.  Novel Intramolecular Ene Reactions of Allenyl silanes , 1995 .

[65]  C. Masse,et al.  Diastereoselective Reactions of Chiral Allyl and Allenyl Silanes with Activated C:X .pi.-Bonds , 1995 .

[66]  C. Chatgilialoglu.  Organosilanes as radical-based reducing agents in synthesis , 1992 .

[67]  R. West,et al.  Stereochemistry and Mechanism of Silane Addition to Olefins. I. Addition of Trichlorosilane to 1-Methylcyclohexene Under Free Radical and Thermal Conditions , 1962 .

[68]  H. Miura,et al.  Practical Synthesis of Allyl, Allenyl, and Benzyl Boronates through SN1′-Type Borylation under Heterogeneous Gold Catalysis , 2021 .

[69]  E. Iglesia,et al.  Experimental and theoretical assessment of the mechanism and site requirements for ketonization of carboxylic acids on oxides , 2017 .

[70]  H. Nishihara,et al.  Efficient synthesis of arylsilanes by Cross-coupling of aromatic compounds with hydrosilanes as silicon sources , 2009 .