The present-day atmosphere of Mars: Where does it come from?

Abstract Recent observations and missions to Mars have provided us with new insight into the past habitability of Mars and its history. At the same time they have raised many questions on the planet evolution. We show that even with the few data available we can propose a scenario for the evolution of the Martian atmosphere in the last three billion years. Our model is obtained with a back integration of the Martian atmosphere, and takes into account the effects of volcanic degassing, which constitutes an input of volatiles, and atmospheric escape into space. We focus on CO2, the predominant Martian atmospheric gas. Volcanic CO2 degassing rates are obtained for different models of numerical model crust production rates [Breuer, D., Spohn, T. 2003. Early plate tectonics versus single-plate tectonics on Mars: Evidence from magnetic field history and crust evolution. J. Geophys. Res. - Planets, 108, E7, 5072, Breuer, D., Spohn, T., 2006. Viscosity of the Martian mantle and its initial temperature: Constraints from crust formation history and the evolution of the magnetic field. Planet. Space Sci. 54 (2006) 153–169; Manga, M., Wenzel, M., Zaranek, S.E., 2006. Mantle Plumes and Long-lived Volcanism on Mars as Result of a Layered Mantle. American Geophysical Union Fall Meeting 2006, Abstract #P31C-0149.] and constrained on observation. By estimating the volatile contents of the lavas, the amount of volatiles released in the atmosphere is estimated for different scenarios. Both non-thermal processes (related to the solar activity) and thermal processes are studied and non-thermal processes are incorporated in our modelling of the escape [Chassefiere, E., Leblanc, F., Langlais, B., 2006, The combined effects of escape and magnetic field history at Mars. Planet. Space Sci. Volume 55, Issue 3, Pages 343–357.]. We used measurements from ASPERA and Mars Express and these models to estimate the amount of lost atmosphere. An evolution of the CO2 pressure consistent with its present state is then obtained. A crustal production rate of at least 0.01 km3/year is needed for the atmosphere to be at steady state. Moreover, we show that for most of the scenarios a rapid loss of the primary (and primordial) atmosphere due to atmospheric escape is required in the first 2 Gyr in order to obtain the present-day atmosphere. When CO2 concentration in the mantle is high enough (i.e. more than 800 ppm), our results imply that present-day atmosphere would have a volcanic origin and would have been created between 1 Gyr and 2 Gyr ago even for models with low volcanic activity. If the volcanic activity and the degassing are intense enough, then the atmosphere can even be entirely secondary and as young as 1 Gyr. However, with low activity and low CO2 concentration (less than 600 ppm), the present-day atmosphere is likely to be for the major part primordial.

[1]  P. A. J. Englert,et al.  Distribution of Hydrogen in the Near Surface of Mars: Evidence for Subsurface Ice Deposits , 2002, Science.

[2]  Carol R. Stoker,et al.  Thermal emission spectra of Mars (5.4–10.5 μm): Evidence for sulfates, carbonates, and hydrates , 1989 .

[3]  A. Seiff,et al.  Structure of the atmosphere of Mars in summer at mid-latitudes , 1977 .

[4]  Shane Byrne,et al.  A Sublimation Model for Martian South Polar Ice Features , 2003, Science.

[5]  Richard W. Zurek,et al.  Comparative aspects of the climate of Mars: an introduction to the current atmosphere. , 1992 .

[6]  R. Greeley,et al.  Magma Generation on Mars: Amounts, Rates, and Comparisons with Earth, Moon, and Venus , 1991, Science.

[7]  E. Chassefière,et al.  Hydrodynamic escape of hydrogen from a hot water-rich atmosphere: The case of Venus , 1996 .

[8]  David C. Catling,et al.  Mars Atmosphere History and Surface Interactions , 2007 .

[9]  K. Zahnle,et al.  Thick and thin models of the evolution of carbon dioxide on Mars , 2006 .

[10]  E. Chassefière Hydrodynamic Escape of Oxygen from Primitive Atmospheres: Applications to the Cases of Venus and Mars , 1996 .

[11]  Thomas W. Trull,et al.  C-He systematics in hotspot xenoliths: implications for mantle carbon contents and carbon recycling , 1993 .

[12]  J W Head,et al.  Internal structure and early thermal evolution of Mars from Mars Global Surveyor topography and gravity. , 2000, Science.

[13]  T. Encrenaz,et al.  The 2.4– spectrum of Mars observed with the infrared space observatory , 2000 .

[14]  M. Maggi,et al.  Mass composition of the escaping plasma at Mars , 2006 .

[15]  Y L Yung,et al.  Loss of atmosphere from Mars due to solar wind-induced sputtering , 1995, Science.

[16]  F. Leblanc,et al.  The combined effects of escape and magnetic field histories at Mars , 2007 .

[17]  P. Drossart,et al.  Perennial water ice identified in the south polar cap of Mars , 2004, Nature.

[18]  Adrian Lenardic,et al.  Melt propagation and volcanism in mantle convection simulations, with applications for Martian volcanic and atmospheric evolution , 2007 .

[19]  R. E. Arvidson,et al.  Phyllosilicates on Mars and implications for early martian climate , 2005, Nature.

[20]  F. Fanale,et al.  Carbon dioxide: Adsorption on palagonite and partitioning in the Martian regolith , 1987 .

[21]  R. J. Reid,et al.  Results from the Mars Pathfinder camera. , 1997, Science.

[22]  Igor V. Sokolov,et al.  Three‐dimensional, multispecies, high spatial resolution MHD studies of the solar wind interaction with Mars , 2004 .

[23]  T. Spohn,et al.  Water, Life, and Planetary Geodynamical Evolution , 2007 .

[24]  R. A. Hanel,et al.  Investigation of the Martian environment by infrared spectroscopy on Mariner 9 , 1972 .

[25]  Robert B. Singer,et al.  High-resolution reflectance spectra of Mars in the 2.3-μm region: evidence for the mineral scapolite , 1990 .

[26]  A. Jambon Chapter 12. EARTH DEGASSING AND LARGE-SCALE GEOCHEMICAL CYCLING OF VOLATILE ELEMENTS , 1994 .

[27]  K. Kuramoto Accretion, core formation, H and C evolution of the Earth and Mars , 1997 .

[28]  F. Leblanc,et al.  Sputtering of the Martian atmosphere by solar wind pick-up ions , 2001 .

[29]  J. Luhmann,et al.  Dayside pickup oxygen ion precipitation at Venus and Mars: Spatial distributions, energy deposition and consequences , 1991 .

[30]  A. Nagy,et al.  The Ancient Oxygen Exosphere of Mars: Implications for Atmosphere Evolution , 1991 .

[31]  T. Grove,et al.  Early hydrous melting and degassing of the Martian interior , 2006 .

[32]  D. R. Rushneck,et al.  The composition of the atmosphere at the surface of Mars , 1977 .

[33]  David E. Smith,et al.  Ancient Geodynamics and Global-Scale Hydrology on Mars , 2001, Science.

[34]  Jean-Pierre Bibring,et al.  Sulfates in Martian Layered Terrains: The OMEGA/Mars Express View , 2005, Science.

[35]  J. Fox CO2+ dissociative recombination: A source of thermal and nonthermal C on Mars , 2004 .

[36]  T. Encrenaz,et al.  Mars Surface Diversity as Revealed by the OMEGA/Mars Express Observations , 2005, Science.

[37]  J. Gooding,et al.  Volatile compounds in shergottite and nakhlite meteorites , 1990 .

[38]  R. Greeley Release of Juvenile Water on Mars: Estimated Amounts and Timing Associated with Volcanism , 1987, Science.

[39]  F. Leblanc,et al.  Role of molecular species in pickup ion sputtering of the Martian atmosphere , 2002 .

[40]  Claude J. Allègre,et al.  Carbon geodynamic cycle , 1982, Nature.

[41]  Epilogue: The Origins of Life in the Solar System and Future Exploration , 2007 .

[42]  William K. Hartmann,et al.  Cratering Chronology and the Evolution of Mars , 2001 .

[43]  R. Greeley,et al.  Geomorphologic Evidence for Liquid Water , 2001 .

[44]  T. Spohn,et al.  Early plate tectonics versus single-plate tectonics on Mars: Evidence from magnetic field history and crust evolution , 2003 .

[45]  Ness,et al.  Magnetic Field and Plasma Observations at Mars: Initial Results of the Mars Global Surveyor Mission , 1998, Science.

[46]  Bruce M. Jakosky,et al.  Atmospheric loss since the onset of the Martian geologic record: Combined role of impact erosion and sputtering , 1998 .

[47]  Usa,et al.  SUBMITTED TO APJ Preprint typeset using L ATEX style emulateapj EVOLUTION OF THE SOLAR ACTIVITY OVER TIME AND EFFECTS ON PLANETARY ATMOSPHERES: I. HIGH-ENERGY IRRADIANCES (1–1700 A) , 2004 .

[48]  Stephen R. Lewis,et al.  Improved general circulation models of the Martian atmosphere from the surface to above 80 km , 1999 .

[49]  C. Pillinger,et al.  Carbon abundance and isotopic studies of Shergotty and other shergottite meteorites , 1986 .

[50]  I. Wright,et al.  Magmatic carbon in Martian meteorites: attempts to constrain the carbon cycle on Mars , 2004, International Journal of Astrobiology.

[51]  R. Phillips,et al.  Thermal and crustal evolution of Mars , 2002 .

[52]  W. Hartmann,et al.  Geological Processes and Evolution , 2001 .

[53]  Christophe Delacourt,et al.  Evidence for Precipitation on Mars from Dendritic Valleys in the Valles Marineris Area , 2004, Science.

[54]  M. Grady,et al.  Martian atmospheric carbon dioxide and weathering products in SNC meteorites , 1985 .

[55]  T. Encrenaz The Atmosphere of Mars as Constrained by Remote Sensing , 2001 .

[56]  T. Spohn,et al.  Viscosity of the Martian mantle and its initial temperature: Constraints from crust formation history and the evolution of the magnetic field , 2006 .