Influence of annealing treatment on the corrosion resistance of lean duplex stainless steel 2101

Abstract The effect of annealing temperatures in the range 1000–1200 °C on the microstructure and corrosion behavior of 2101 lean duplex stainless steel was investigated. The results demonstrated that the volume fraction of austenite phase decreased with increasing annealing temperature. However, lower values for the pitting potential ( E pit ) and the critical pitting temperature (CPT) were obtained after annealing at higher temperatures. Pitting was initiated preferentially in the ferrite/austenite boundaries or inside the ferrite domains, indicating that the ferrite phase had inferior pitting corrosion resistance as compared to the austenite phase in as-received steel. Moreover, the PRE values of the ferrite phase fell with the annealing temperature, while the values for the austenite phase rose. No equal PRE values in the ferrite and austenite phase were found for this steel in the range of annealing temperatures. This was determined by evaluating the PRE values of both phases from EDS results and the Thermo-Calc database.

[1]  P. Uggowitzer,et al.  Partitioning of chromium and molybdenum in super duplex stainless steels with respect to nitrogen and nickel content , 1998 .

[2]  A. Wilson,et al.  Influence of isothermal phase transformations on toughness and pitting corrosion of super duplex stainless steel SAF 2507 , 1993 .

[3]  R. Jargelius-Pettersson,et al.  Application of the Pitting Resistance Equivalent Concept to Some Highly Alloyed Austenitic Stainless Steels , 1998 .

[4]  Preet M. Singh,et al.  Role of Microstructure on the Corrosion Susceptibility of UNS S32101 Duplex Stainless Steel , 2008 .

[5]  Mariano Marcos,et al.  Influence of chemical composition on the pitting corrosion resistance of non-standard low-Ni high-Mn–N duplex stainless steels , 2003 .

[6]  Jan-Olof Andersson,et al.  The Thermo-Calc databank system☆ , 1985 .

[7]  C. Tuck,et al.  The effect of phase compositions on the pitting corrosion of 25 Cr duplex stainless steel in chloride solutions , 1996 .

[8]  G. T. Burstein,et al.  The effect of specimen size on the measured pitting potential of stainless steel , 1996 .

[9]  Rolf Sandström,et al.  Fracture toughness of the lean duplex stainless steel LDX 2101 , 2006 .

[10]  A. Wilson,et al.  Mechanical properties, microstructural stability and kinetics of σ-phase formation in 29Cr-6Ni-2Mo-0.38N superduplex stainless steel , 2000 .

[11]  J. King,et al.  Elemental partitioning and microstructural development in duplex stainless steel weld metal , 1991 .

[12]  G. Herbsleb Der Einfluß von Schwefeldioxid, Schwefelwasserstoff und Kohlenmonoxid auf die Lochkorrosion von austenitischen Chrom-Nickel-Stählen mit bis zu 4 Massen-% Molybdän in 1 M Natriumchlorid-Lösung , 1982 .

[13]  K. Mitsuda,et al.  Corrosion Simulation Tests of Phosphoric Acid Fuel Cells , 1990 .

[14]  M. Liljas,et al.  Development of a Lean Duplex Stainless Steel , 2008 .

[15]  J. Lai,et al.  Effect of solution treatment on the transformation behaviour of cold-rolled duplex stainless steels , 1995 .

[16]  Zhang Wei,et al.  Effect of ageing on precipitation and impact energy of 2101 economical duplex stainless steel , 2009 .

[17]  H. Hänninen Corrosion Properties of HNS , 1999 .

[18]  Some Modes of Speech of Empirical Science , 1936 .

[19]  R. Newman,et al.  Evolution of current transients and morphology of metastable and stable pitting on stainless steel near the critical pitting temperature , 2006 .