Stability of Linoleic Acid Hydroperoxide in the Oil System

It is important to know the behavior of lipid peroxidation products in foods because lipid hydroperoxides are known to decrease food quality and safety. We have reported that the stability of linoleic acid hydroperoxide (hydroperoxyoctadecadienoic acid ; HPOD) in the water system. Although the hydroperoxides have been believed to be so unstable at high temperature that they decomposed immediately, the stability of HPOD at high temperature has not been exactly provided. In this study, we examined HPOD decomposition in the oil system kinetically. In tri-n-caprine as the model of oil

[1]  H. Takamura,et al.  Effects of Amino Acids, Sugars, and Ascorbic Acid on the Stability of Linoleic Acid Hydroperoxide in the Water Phase. , 1999, Bioscience, biotechnology, and biochemistry.

[2]  T. Yamamoto,et al.  Effects of Metal Ions and pH on the Stability of Linoleic Acid Hydroperoxide in the Water Phase. , 1997, Bioscience, biotechnology, and biochemistry.

[3]  H. Gardner Recent investigations into the lipoxygenase pathway of plants. , 1991, Biochimica et biophysica acta.

[4]  M. Hamberg Trihydroxyoctadecenoic acids in beer: qualitative and quantitative analysis , 1991 .

[5]  R. England,et al.  Acid-catalyzed transformation of 13(S)-hydroperoxylinoleic acid into epoxyhydroxyoctadecenoic and trihydroxyoctadecenoic acids , 1984 .

[6]  D. Weisleder,et al.  Acid catalysis of a linoleic acid hydroperoxide: formation of epoxides by an intramolecular cyclization of the hydroperoxide group , 1984 .

[7]  E. Frankel Analytical Methods Used in the Study of Autoxidation Processes , 1980 .

[8]  E. Frankel,et al.  Lipid oxidation. , 1980, Progress in lipid research.

[9]  W. Grosch,et al.  Occurrence and formation of bitter-tasting trihydroxy fatty acids in soybeans , 1979 .

[10]  K. Warner,et al.  Oxidized phosphatidylcholines from defatted soybean flakes taste bitter , 1976 .

[11]  H. Gardner Decomposition of linoleic acid hydroperoxides. Enzymic reactions compared with nonenzymic. , 1975, Journal of agricultural and food chemistry.

[12]  R. Schneider,et al.  Sensitivity of feeding tests in detecting carcinogenic properties in chemicals: examination of 7,12-dimethylbenz(a)anthracene and oxidized linoleate. , 1973, Food and cosmetics toxicology.

[13]  R. E. Johnson,et al.  A long-term nutritional study with fresh and mildly oxidized vegetable and animal fats , 1965 .

[14]  E. Frankel,et al.  Thermal dimerization of fatty ester hypdroperoxides , 1960 .