Size parameter effect of dielectric small particle mediated nano-hole patterning on silicon wafer by femtosecond laser

By use of a polystyrene particle with a fundamental (800 nm) and a second-harmonic (400 nm) wave of a femtosecond Ti:sapphire laser, nano-hole patterning properties on a silicon wafer were experimentally compared by keeping the size parameter constant. With the 800-nm wave, the patterned hole diameter ranged from 100 to 250 nm and the depth ranged from 20 to 100 nm. With the 400-nm wave, the hole diameter ranged from 50 to 200 nm while the depth ranged from 10 to 60 nm. The patterned diameter and the depth of patterned nano-holes were also controllable by the laser fluence. By the 3D finite-difference time-domain method it is numerically predicted that if the size parameter is kept at π approximately, the nano-hole patterning is efficiently performed even in the ultraviolet region of the spectrum.

[1]  W. M. Haynes CRC Handbook of Chemistry and Physics , 1990 .

[2]  A. Weinreb,et al.  Optical Properties of Polystyrene Films in the Far Ultraviolet , 1968 .

[3]  L. Zhang,et al.  Laser writing of a subwavelength structure on silicon (100) surfaces with particle-enhanced optical irradiation , 2000 .

[4]  R. H. Boundy,et al.  Styrene, its polymers, copolymers, and derivatives , 1952 .

[5]  Minoru Obara,et al.  Nano-dimple processing of silicon surfaces by femtosecond laser irradiation with dielectric particle templates in the Mie scattering domain , 2009 .

[6]  Wolfgang Kautek,et al.  Ablation experiments on polyimide with femtosecond laser pulses , 1999 .

[7]  Hsuen‐Li Chen,et al.  Using colloidal lithography to fabricate and optimize sub-wavelength pyramidal and honeycomb structures in solar cells. , 2007, Optics express.

[8]  M. Hong,et al.  Near-field enhanced femtosecond laser nano-drilling of glass substrate , 2008 .

[9]  Kuniaki Nagayama,et al.  Stripe patterns formed on a glass surface during droplet evaporation , 1995 .

[10]  D. Bäuerle,et al.  Laser-induced nanopatterning of silicon with colloidal monolayers , 2007 .

[11]  Jun Q. Lu,et al.  Determination of complex refractive index of polystyrene microspheres from 370 to 1610 nm , 2003, Physics in medicine and biology.

[12]  Minoru Obara,et al.  Friction characteristics of submicrometre-structured surfaces fabricated by particle-assisted near-field enhancement with femtosecond laser , 2007 .

[13]  Allen Taflove,et al.  Computational Electrodynamics the Finite-Difference Time-Domain Method , 1995 .

[14]  Luping P. Shi,et al.  Direct femtosecond laser nanopatterning of glass substrate by particle-assisted near-field enhancement , 2006 .

[15]  E. T. Arakawa,et al.  Optical properties of polystyrene from the near-infrared to the x-ray region and convergence of optical sum rules , 1977 .

[16]  G. Mie Beiträge zur Optik trüber Medien, speziell kolloidaler Metallösungen , 1908 .

[17]  Yoshimasa Kawata,et al.  Nanofabrication induced by near-field exposure from a nanosecond laser pulse , 2001 .

[18]  P. Leiderer,et al.  Optical near-fields of triangular nanostructures , 2007 .

[19]  Stephen Y. Chou,et al.  Nano-compact disks with 400 Gbit/in2 storage density fabricated using nanoimprint lithography and read with proximal probe , 1997 .

[20]  Minoru Obara,et al.  Fabrication of Hexagonally Arrayed Nanoholes Using Femtosecond Laser Pulse Ablation with Template of Subwavelength Polystyrene Particle Array , 2005 .

[21]  T. Sakai,et al.  Positive and negative nanohole-fabrication on glass surface by femtosecond laser with template of polystyrene particle array , 2007 .

[22]  B. Luk’yanchuk,et al.  Plasmonic laser nanoablation of silicon by the scattering of femtosecond pulses near gold nanospheres , 2007 .

[23]  Richard K. Chang,et al.  Local fields at the surface of noble-metal microspheres , 1981 .

[24]  P. Leiderer,et al.  Local field enhancement effects for nanostructuring of surfaces , 2001, Journal of microscopy.

[25]  P. Leiderer,et al.  Optical field enhancement effects in laser-assisted particle removal , 2001 .

[26]  Z. B. Wang,et al.  Theoretical and experimental investigation of the near field under ordered silica spheres on substrate , 2009 .

[27]  Wei Guo,et al.  Chemical-assisted laser parallel nanostructuring of silicon in optical near fields , 2008, Nanotechnology.

[28]  Z. B. Wang,et al.  Parallel nanostructuring of GeSbTe film with particle mask , 2004 .

[29]  Minoru Obara,et al.  Nanostructuring of silicon surface by femtosecond laser pulse mediated with enhanced near-field of gold nanoparticles , 2006 .

[30]  T. Chong,et al.  Angle effect in laser nanopatterning with particle-mask , 2004 .

[31]  Jörg Krüger,et al.  Femtosecond pulse laser processing of TiN on silicon , 2000 .

[32]  Shaochen Chen,et al.  Nanoscale surface modification of glass using a 1064 nm pulsed laser , 2003 .

[33]  T. Ikawa,et al.  Azobenzene polymer surface deformation due to the gradient force of the optical near field of monodispersed polystyrene spheres , 2001 .

[34]  C. Peng,et al.  Ridge waveguide as a near field aperture for high density data storage , 2004 .

[35]  Minoru Obara,et al.  Near field properties in the vicinity of gold nanoparticles placed on various substrates for precise nanostructuring , 2006 .