Optimal control of population and coherence in three-level Λ systems

Optimal control theory (OCT) implementations for an efficient population transfer and creation of maximum coherence in a three-level system are considered. We demonstrate that the half-stimulated Raman adiabatic passage scheme for creation of the maximum Raman coherence is the optimal solution according to the OCT. We also present a comparative study of several implementations of OCT applied to the complete population transfer and creation of the maximum coherence. Performance of the conjugate gradient method, the Zhu–Rabitz method and the Krotov method has been analysed.

[1]  Elijah Polak,et al.  Computational methods in optimization , 1971 .

[2]  R. Bellman,et al.  Computational Methods in Optimization (Mathematics and Science in Engineering) , 1972 .

[3]  J. Eberly,et al.  Optical resonance and two-level atoms , 1975 .

[4]  R. Harney,et al.  Optical resonance and two-level atoms , 1978, IEEE Journal of Quantum Electronics.

[5]  H. Rabitz,et al.  Optimal control of quantum-mechanical systems: Existence, numerical approximation, and applications. , 1988, Physical review. A, General physics.

[6]  Samuel H. Tersigni,et al.  Wavepacket dancing: Achieving chemical selectivity by shaping light pulses , 1989 .

[7]  William H. Press,et al.  Numerical recipes , 1990 .

[8]  H. Rabitz,et al.  Quantum mechanical optimal control of physical observables in microsystems , 1990 .

[9]  Bruce W. Shore,et al.  Theory of Coherent Atomic Excitation , 1991 .

[10]  Bruce W. Shore,et al.  The Theory of Coherent Atomic Excitation , 1991 .

[11]  Jan Broeckhove,et al.  Time-dependent quantum molecular dynamics , 1992 .

[12]  David J. Tannor,et al.  Control of Photochemical Branching: Novel Procedures for Finding Optimal Pulses and Global Upper Bounds , 1992 .

[13]  David J. Tannor,et al.  Controlled dissociation of I2 via optical transitions between the X and B electronic states , 1993 .

[14]  Y. Band,et al.  Is adiabatic passage population transfer a solution to an optimal control problem , 1994 .

[15]  Shapiro Theory of two-photon adiabatic passage: Absorption to and emission from N states. , 1996, Physical review. A, Atomic, molecular, and optical physics.

[16]  Population transfer through an autoionizing state by pulse delay , 1996 .

[17]  M. Shapiro,et al.  Two‐photon dissociation/ionization beyond the adiabatic approximation , 1996 .

[18]  David J. Tannor,et al.  Simple and robust extension of the stimulated Raman adiabatic passage technique toN-level systems , 1997 .

[19]  David J. Tannor,et al.  Laser cooling of internal degrees of freedom. II , 1997 .

[20]  Population transfer through the continuum using laser-controlled Stark shifts , 1997 .

[21]  N. Vitanov,et al.  Adiabatic population transfer in multistate chains via dressed intermediate states , 1998 .

[22]  H. Rabitz,et al.  RAPIDLY CONVERGENT ITERATION METHODS FOR QUANTUM OPTIMAL CONTROL OF POPULATION , 1998 .

[23]  B. Shore,et al.  Coherent population transfer among quantum states of atoms and molecules , 1998 .

[24]  Herschel Rabitz,et al.  A RAPID MONOTONICALLY CONVERGENT ITERATION ALGORITHM FOR QUANTUM OPTIMAL CONTROL OVER THE EXPECTATION VALUE OF A POSITIVE DEFINITE OPERATOR , 1998 .

[25]  Zare,et al.  Laser control of chemical reactions , 1998, Science.

[26]  D. Tannor,et al.  OPTIMAL PULSE SEQUENCES FOR POPULATION TRANSFER IN MULTILEVEL SYSTEMS , 1999 .

[27]  Stuart A. Rice,et al.  Optical Control of Molecular Dynamics , 2000 .

[28]  Nonadiabatic dynamics in the dark subspace of a multilevel stimulated Raman adiabatic passage process , 2001 .

[29]  H Rabitz,et al.  Selective Bond Dissociation and Rearrangement with Optimally Tailored, Strong-Field Laser Pulses , 2001, Science.

[30]  Optimal control approach for a degenerate STIRAP , 2002 .

[31]  R. Kosloff,et al.  Optimal control theory for unitary transformations , 2003, quant-ph/0309011.

[32]  Paul Brumer,et al.  Principles of the Quantum Control of Molecular Processes , 2003 .

[33]  Navin Khaneja,et al.  Effective Hamiltonians by optimal control: solid-state NMR double-quantum planar and isotropic dipolar recoupling. , 2006, The Journal of chemical physics.

[34]  H. Rabitz,et al.  Design of infrared laser pulses for the deexcitation of highly excited homonuclear diatomic molecules. , 2006, The Journal of chemical physics.

[35]  Thierry Paul,et al.  Quantum computation and quantum information , 2007, Mathematical Structures in Computer Science.

[36]  Regina de Vivie-Riedle,et al.  Femtosecond lasers for quantum information technology. , 2007, Chemical reviews.

[37]  S. Malinovskaya,et al.  Chirped-pulse adiabatic control in coherent anti-Stokes Raman scattering for imaging of biological structure and dynamics. , 2007, Optics letters.

[38]  Marlan O Scully,et al.  Optimizing the Laser-Pulse Configuration for Coherent Raman Spectroscopy , 2007, Science.

[39]  P. Král,et al.  Colloquium: Coherently controlled adiabatic passage , 2007 .

[40]  Jane A Dickerson,et al.  Current Applications of Liquid Chromatography / Mass Spectrometry in Pharmaceutical Discovery After a Decade of Innovation , 2008 .

[41]  S. Malinovskaya,et al.  Optimal coherence via chirped pulse adiabatic passage in the presence of dephasing , 2008 .

[42]  Alex Brown,et al.  Optimal Control Theory for Manipulating Molecular Processes , 2008 .

[43]  Christiane P. Koch,et al.  Protecting coherence in optimal control theory : State-dependent constraint approach , 2008, 0803.0921.

[44]  Marcos Dantus,et al.  Coherent mode-selective Raman excitation towards standoff detection. , 2008, Optics express.

[45]  R. Kosut,et al.  Coherent Control of Decoherence , 2005, Science.

[46]  Harjinder Singh,et al.  OPTIMALLY CONTROLLED VIBRATIONAL POPULATION TRANSFER IN A DIATOMIC QUANTUM SYSTEM , 2009 .

[47]  Yaron Silberberg,et al.  Quantum coherent control for nonlinear spectroscopy and microscopy. , 2009, Annual review of physical chemistry.

[48]  S. Malinovskaya,et al.  Quantum dynamics manipulation using optimal control theory in the presence of laser field noise , 2010 .

[49]  V. Malinovsky,et al.  Principles of Laser Spectroscopy and Quantum Optics , 2011 .