Nonenzymatic Electrochemical Sensing of Hydrogen Peroxide Based on Gold Nanolayers Covered with Snow-like Nanoparticles

"Gold nanolayers covered with snow-like nanoparticles were firstly synthesized by the sonoelectrodeposition method at a high negative potential. The nanostructure was then applied to prepare a highly sensitive nonenzymatic sensor for hydrogen peroxide. The catalytic activity and sensitivity of the gold nanostructure toward the electroreduction of hydrogen peroxide was excellent without surface fouling and deterioration effects. The current related to the reduction of hydrogen peroxide rapidly and linearly depended on the concentration with a sensitivity of 0.24 A mol-1 dm3 cm-2 and a detection limit of 7.9 i­mol dm-3. The present hydrogen peroxide sensor was fabricated by a simple preparation method without using any specific enzyme or reagent, with an excellent catalytic activity, high sensitivity and selectivity, long-term stability, and antifouling property."

[1]  M. Schmeisser,et al.  Hydrogen peroxide , 2019, Reactions Weekly.

[2]  Meifeng Chen,et al.  Electrochemical sensor based on graphene doped gold nanoparticles modified electrode for detection of diethylstilboestrol , 2015 .

[3]  W. Jin,et al.  Facile fabrication of a three-dimensional gold nanowire array for high-performance electrochemical sensing. , 2015, Journal of materials chemistry. B.

[4]  Yuhong Zheng,et al.  A sensitive electrochemical sensor for direct phoxim detection based on an electrodeposited reduced graphene oxide–gold nanocomposite , 2015 .

[5]  Chengzhou Zhu,et al.  Electrochemical Sensors and Biosensors Based on Nanomaterials and Nanostructures , 2014, Analytical chemistry.

[6]  Jeong-Woo Choi,et al.  Electrochemical Biosensor consisted of conducting polymer layer on gold nanodots patterned Indium Tin Oxide electrode for rapid and simultaneous determination of purine bases , 2014 .

[7]  H. Heli,et al.  Cobalt oxide nanoparticles anchored to multiwalled carbon nanotubes: Synthesis and application for enhanced electrocatalytic reaction and highly sensitive nonenzymatic detection of hydrogen peroxide , 2014 .

[8]  H. Heli,et al.  Enhanced electrocatalytic reduction and highly sensitive nonenzymatic detection of hydrogen peroxide using platinum hierarchical nanoflowers , 2014 .

[9]  Huayu Huang,et al.  Direct preparation of well-dispersed graphene/gold nanorod composites and their application in electrochemical sensors for determination of ractopamine , 2014 .

[10]  Junwei Su,et al.  A novel 3-D fabrication of platinum nanoparticles decorated micro carbon pillars electrode for high sensitivity detection of hydrogen peroxide , 2013 .

[11]  A. J. Wain,et al.  Imaging size effects on the electrocatalytic activity of gold nanoparticles using scanning electrochemical microscopy , 2013 .

[12]  Jun Wan,et al.  Nonenzymatic H2O2 Sensor Based on Pt Nanoflower Electrode , 2012, Journal of Cluster Science.

[13]  C. Chen,et al.  Platinum nanoparticle-decorated carbon nanotube clusters on screen-printed gold nanofilm electrode for enhanced electrocatalytic reduction of hydrogen peroxide , 2012 .

[14]  C. Liu,et al.  Bimetallic PtM (M=Pd, Ir) nanoparticle decorated multi-walled carbon nanotube enzyme-free, mediator-less amperometric sensor for H₂O₂. , 2012, Biosensors & bioelectronics.

[15]  Y. Chai,et al.  Non-enzymatic hydrogen peroxide amperometric sensor based on a glassy carbon electrode modified with an MWCNT/polyaniline composite film and platinum nanoparticles , 2012, Microchimica Acta.

[16]  Li Wang,et al.  Architecture of poly(o-phenylenediamine)–Ag nanoparticle composites for a hydrogen peroxide sensor , 2012 .

[17]  Yuandong Zhao,et al.  Recent advances in electrochemical sensing for hydrogen peroxide: a review. , 2012, The Analyst.

[18]  Jagriti Narang,et al.  A non-enzymatic sensor for hydrogen peroxide based on polyaniline, multiwalled carbon nanotubes and gold nanoparticles modified Au electrode. , 2011, The Analyst.

[19]  Younghun Kim,et al.  Amperometric sensing of hydrogen peroxide via highly roughened macroporous Gold-/Platinum nanoparticles electrode , 2011 .

[20]  Y. Chai,et al.  Nonenzymatic glucose sensor based on a glassy carbon electrode modified with chains of platinum hollow nanoparticles and porous gold nanoparticles in a chitosan membrane , 2011 .

[21]  Xuping Sun,et al.  Hydrothermal synthesis of well-stable silver nanoparticles and their application for enzymeless hydrogen peroxide detection , 2011 .

[22]  Xuan-Hung Pham,et al.  Electrocatalytic reduction of hydrogen peroxide by silver particles patterned on single-walled carbon nanotubes , 2010 .

[23]  Y. Chai,et al.  Direct electrocatalytic reduction of hydrogen peroxide at a glassy carbon electrode modified with polypyrrole nanowires and platinum hollow nanospheres , 2010 .

[24]  Yan Shi,et al.  Novel nonenzymatic hydrogen peroxide sensor based on iron oxide-silver hybrid submicrospheres. , 2010, Talanta.

[25]  Jun‐Jie Zhu,et al.  Fabrication of a novel nonenzymatic hydrogen peroxide sensor based on Se/Pt nanocomposites , 2010 .

[26]  Huafeng Yang,et al.  Graphene/AuNPs/chitosan nanocomposites film for glucose biosensing. , 2010, Biosensors & bioelectronics.

[27]  R. Compton,et al.  Hydrogen Peroxide Electroreduction at a Silver-Nanoparticle Array: Investigating Nanoparticle Size and Coverage Effects , 2009 .

[28]  Ruo Yuan,et al.  A Novel Nonenzymatic Hydrogen Peroxide Sensor Based on a Polypyrrole Nanowire-Copper Nanocomposite Modified Gold Electrode , 2008, Sensors.

[29]  S. Dong,et al.  Direct electrochemistry and electrocatalysis of horseradish peroxidase immobilized in sol-gel-derived ceramic-carbon nanotube nanocomposite film. , 2007, Biosensors & bioelectronics.

[30]  Ying Wang,et al.  A highly sensitive hydrogen peroxide amperometric sensor based on MnO2 nanoparticles and dihexadecyl hydrogen phosphate composite film , 2006 .

[31]  Kang Wang,et al.  Highly Ordered Platinum‐Nanotubule Arrays for Amperometric Glucose Sensing , 2005 .

[32]  J. Solla-Gullón,et al.  Gold nanoparticles synthesized in a water-in-oil microemulsion: electrochemical characterization and effect of the surface structure on the oxygen reduction reaction , 2004 .

[33]  C. Minero,et al.  New processes in the environmental chemistry of nitrite. 2. The role of hydrogen peroxide. , 2003, Environmental science & technology.

[34]  Tianyan You,et al.  Characterization of platinum nanoparticle-embedded carbon film electrode and its detection of hydrogen peroxide. , 2003, Analytical chemistry.

[35]  L. Guczi,et al.  Gold nanoparticles deposited on SiO2/Si100: correlation between size, electron structure, and activity in CO oxidation. , 2003, Journal of the American Chemical Society.

[36]  Dario Kriz,et al.  Amperometric determination of L-lactate based on entrapment of lactate oxidase on a transducer surface with a semi-permeable membrane using a SIRE technology based biosensor. Application: tomato paste and baby food. , 2002, Journal of agricultural and food chemistry.

[37]  Joseph Wang,et al.  Metal-dispersed carbon paste electrodes , 1992 .

[38]  Eugene A. Irene,et al.  The Influence of Silicon Surface Cleaning Procedures on Silicon Oxidation , 1987 .

[39]  G. Vojta,et al.  Fractal Concepts in Surface Growth , 1996 .

[40]  Erik Nielsen,et al.  Statistics for analytical chemistry , 1987 .