Ru(II) polypyridine complexes: photophysics, photochemistry, eletrochemistry, and chemiluminescence

[1]  K. R. Seddon,et al.  A deuterium exchange reaction of the tris-(2,2′-bipyridine)ruthenium(II) cation: evidence for the acidity of the 3,3′-protons , 1982 .

[2]  M. Wrighton,et al.  Raman spectroscopy of electronic excited organometallic complexes: a comparison of the metal to 2,2'-bipyridine charge-transfer state of fac-(2,2'-bipyridine)tricarbonylhalorhenium and tris(2,2'-bipyridine)ruthenium(II) , 1983 .

[3]  A. Bard,et al.  Electrogenerated chemiluminescence. 35. Temperature dependence of the ECL efficiency of tris(2,2'-bipyridine)rubidium(2+) in acetonitrile and evidence for very high excited state yields from electron transfer reactions , 1979 .

[4]  R. Marcus,et al.  Electron transfers in chemistry and biology , 1985 .

[5]  B. P. Sullivan,et al.  Synthesis and properties of the chloro-bridged dimer [(bpy)2RuCl]22+ and its transient 3+ mixed-valence ion , 1978 .

[6]  P. Natarajan,et al.  Mechanism of the tris(bipyridyl)ruthenium(II) photosensitized redox decomposition of cobalt(III) complexes and the reactivity patterns of some primary radicals , 1973 .

[7]  Correlation of ligand field excited-state energies with ligand field strength in (polypyridine)ruthenium(II) complexes , 1985 .

[8]  L. Yellowlees,et al.  Ligand-ligand inter-valence charge-transfer absorption in reduced ruthenium(II) bipyridine complexes , 1982 .

[9]  A. Mau,et al.  Localization of electronic excitation energy in Ru(2,2′-bipyridine)2(2,2′-bipyridine-4,4′-dicarboxylic acid)2+ and related complexes , 1979 .

[10]  K. Honda,et al.  TEMPERATURE DEPENDENCE OF ECL EFFICIENCY OF TRIS(BIPYRIDINE)Ru(II) COMPLEX , 1979 .

[11]  T. Meyer,et al.  Synthetic control of excited-state properties. Tris-chelate complexes containing the ligands 2,2'-bipyrazine, 2,2'-bipyridine, and 2,2'-bipyrimidine , 1984 .

[12]  T. Meyer,et al.  Intervalence transfer in mixed-metal dimers of ruthenium and osmium: relationship between redox asymmetry and intervalence-transfer absorption band energy , 1984 .

[13]  R. Watts,et al.  Temperature and magnetic-field effects on the luminescence lifetimes of complexes of ruthenium(II) and iridium(III) , 1971 .

[14]  Scott R. Wilson,et al.  Cis-trans photoisomerization in Ru(bpy)2(OH2)22+. Crystal structure of trans-[Ru(bpy)2(OH2)(OH)](ClO4)2 , 1980 .

[15]  I. Rubinstein,et al.  Electrogenerated chemiluminescence. 37. Aqueous ecl systems based on tris(2,2'-bipyridine)ruthenium(2+) and oxalate or organic acids , 1981 .

[16]  A. Lever,et al.  Correlation of electronic charge transfer transitions and electrochemical potentials.: The bipyrazine(tetpacarbonyl) molybdenum(0) system in various solvents , 1984 .

[17]  H. Yersin,et al.  On the lowest excited states of [Ru(bpy)3](PF6)2 single crystals , 1984 .

[18]  C. Daul,et al.  The electronic structure and low-lying excited states of the ruthenium(II)tris(diimine) complex , 1981 .

[19]  R. C. Young,et al.  Kinetic relaxation measurement of rapid electron transfer reactions by flash photolysis. Conversion of light energy into chemical energy using the tris(2,2'-bipyridine)ruthenium(3+)-tris(2,2'-bipyridine)ruthenium(2+*) couple , 1975 .

[20]  K. A. Suresh,et al.  Langmuir monolayers of mesomorphic monomers and polymers , 1985 .

[21]  M. DeArmond,et al.  Luminescence of Transition Metal d6 Chelates , 1971 .

[22]  M. DeArmond,et al.  Multiple emission in mixed ligand metal chelates , 1972 .

[23]  M. DeArmond,et al.  Emission studies of transition-metal complexes of 2,2'-dipyridylamine. 2. Tris complexes of ruthenium(II) , 1982 .

[24]  T. Shimidzu,et al.  Photoelectrochemical properties of bis(2,2'-bipyridine)(4,4'-dicarboxy-2,2'-bipyridine)ruthenium(II) chloride , 1985 .

[25]  J. D. Luttmer,et al.  Electrogenerated Chemiluminescence XXXIII . The Production of Excited States by Direct Heterogeneous Electron Transfer from Semiconductor Electrodes , 1978 .

[26]  C. Creutz,et al.  Light induced electron transfer reactions of metal complexes , 1980 .

[27]  R. D. Wright,et al.  Photophysical properties of mixed-ligand ruthenium(II) complexes [Ru(1,10-phenanthroline)n {2-(2-pyridyl)quinoline}3-n] 2+ (n = 0, 1, 2, or 3) , 1982 .

[28]  V. Balzani,et al.  Luminescence of mixed-ligand Ru(II) chelates is there any bona fide case of dual emission? , 1984 .

[29]  J. Vos,et al.  Preparation, spectroscopic characterization, and photochemical and electrochemical properties of some bis(2,2'-bipyridyl)ruthenium(II) and tetracarbonyltungsten(0) complexes of 6-p-tolyl-2,2'-bipyridyl and of 6-p-styryl-2,2'-bipyridyl and its copolymers , 1983 .

[30]  R. Watts,et al.  Quantum efficiencies of transition metal complexes. III. Effect of ligand substituents on radiatiive and radiationless processes , 1972 .

[31]  W. E. Ford.  VISIBLE SPECTRA OF DICARBONYL SUBSTITUTED TRIS-BIPYRIDYL RUTHENIUM (II) COMPLEXES , 1980 .

[32]  Allen J. Bard,et al.  Electrogenerated chemiluminescence. IX. Electrochemistry and emission from systems containing tris(2,2'-bipyridine)ruthenium(II) dichloride , 1972 .

[33]  A. Lever,et al.  Luminescence quenching of the tris(2,2'-bipyrazine)ruthenium(II) cation and its monoprotonated complex , 1985 .

[34]  P. A. Lay,et al.  Proton transfer in the excited state of carboxylic acid derivatives of tris(2,2'-bipyridine-N,N')ruthenium(II) , 1984 .

[35]  A. D. Baker,et al.  Spectroscopic and electrochemical properties of the dimer tetrakis(2,2'-bipyridine)(.mu.-2,3-bis(2-pyridyl)pyrazine)diruthenium(II) and its monomeric analog , 1984 .

[36]  M. Myrick,et al.  Time-resolved photoselection of [Ru(bpy)3]2+−exciton hopping in the excited state , 1987 .

[37]  R. Watts,et al.  Photophysical effects of metal-carbon .sigma. bonds in ortho-metalated complexes of iridium(III) and rhodium(III) , 1984 .

[38]  B. P. Sullivan,et al.  Mixed phosphine 2,2'-bipyridine complexes of ruthenium , 1978 .

[39]  D. Kliger,et al.  Temperature dependence of the excited-state absorption of Ru(bpy)32+ , 1986 .

[40]  C. Carlin,et al.  Multiple state emission and related phenomena in transition metal complexes , 1981 .

[41]  Hiroshi Kobayashi,et al.  Energy transfer between transition‐metal complexes in double complex salts , 1973 .

[42]  V. Balzani,et al.  Bimolecular electron transfer reactions of the excited states of transition metal complexes , 1978 .

[43]  A. Bard,et al.  Electrogenerated Chemiluminescence XXXVI . The Production of Steady Direct Current ECL in Thin Layer and Flow Cells , 1980 .

[44]  T. Meyer,et al.  Photochemistry of tris(2,2'-bipyridine)ruthenium(2+) ion , 1982 .

[45]  P. Natarajan,et al.  Direct observation of the dibromide radical anion oxidation of tris(bipyridyl)ruthenium(II). Evidence for a triplet-to-triplet energy transfer mechanism in the photosensitized redox decomposition of cobalt(III) substrates , 1973 .

[46]  V. Balzani,et al.  Free energy correlation of rate constants for electron transfer quenching of excited transition metal complexes , 1978 .

[47]  S. Goswami,et al.  Chemistry of ruthenium. 7. Aqua complexes of isomeric bis[(2-arylazo)pyridine]ruthenium(II) moieties and their reactions: solvolysis, protic equilibriums, and electrochemistry , 1983 .

[48]  A. Harriman.  Photochemistry of a surfactant derivative of tris(2,2′-bipyridyl)ruthenium(II) , 1977 .

[49]  Spatially isolated redox orbitals: evidence from low-temperature voltammetry , 1983 .

[50]  V. Balzani,et al.  Electron and energy transfer mechanisms in the quenching of the tris(2,2'-bipyridine)ruthenium(II) luminescence by cyanide complexes , 1976 .

[51]  Edward M. Kober,et al.  Application of the energy gap law to excited-state decay of osmium(II)-polypyridine complexes: calculation of relative nonradiative decay rates from emission spectral profiles , 1986 .

[52]  L. Yellowlees,et al.  Spectro-electrochemical studies on tris-bipyridyl ruthenium complexes; ultra-violet, visible, and near-infrared spectra of the series [Ru(bipyridyl)3]2+/1+/0/1– , 1981 .

[53]  Richard J. Watts,et al.  Temperature dependence of the photophysical and photochemical properties of the tris(2,2'-bipyridyl)ruthenium(II) ion in aqueous solution , 1976 .

[54]  T. Netzel,et al.  Lifetimes, spectra, and quenching of the excited states of polypyridine complexes of iron(II), ruthenium(II), and osmium(II) , 1980 .

[55]  A. Bard,et al.  Electrogenerated chemiluminescence. 41. Electrogenerated chemiluminescence and chemiluminescence of the Ru(2,21 - bpy)32+-S2O82- system in acetonitrile-water solutions , 1982 .

[56]  R. W. Callahan,et al.  A novel series of compounds containing from one to four ruthenium(II) bis(bipyridine) units bound to the same bridging ligand , 1982 .

[57]  P. S. Braterman.  Polarisation ratios in ruthenium(II) complexes containing tridentate ligands: A comment , 1984 .

[58]  J. Ferguson,et al.  The circular dichroism of the charge-transfer bands of M(bpy)2+3 (M = Re, Ru, Os) , 1982 .

[59]  S. Rice,et al.  Internal Rotation and the Breakdown of the Adiabatic Approximation: Many‐Phonon Radiationless Transitions , 1970 .

[60]  R. Marcus.  On the frequency factor in electron transfer reactions and its role in the highly exothermic regime , 1981 .

[61]  F. Fronczek,et al.  Selective perturbation of ligand field excited states in polypyridine ruthenium(II) complexes , 1984 .

[62]  D. Whitten,et al.  Electron transfer quenching of the luminescent excited state of tris(2,2'-bipyridine)ruthenium(II). Flash photolysis relaxation technique for measuring the rates of very rapid electron transfer reactions , 1974 .

[63]  B. P. Sullivan,et al.  Thioether, thiolato, and 1,1-dithioato complexes of bis(2,2'-bipyridine)ruthenium(II) and bis(2,2'-bipyridine)osmium(II) , 1985 .

[64]  H. Abruña,et al.  Electrogenerated chemiluminescence. 40. A chemiluminescent polymer based on the tris(4-vinyl-4'-methyl-2,2'-bipyridyl)ruthenium(II) system , 1982 .

[65]  A. Basu,et al.  Resonance Raman spectra of ruthenium(II) complexes of bipyridine and substituted bipyridines: ground- and excited-state properties , 1982 .

[66]  W. W. Brandt,et al.  FLUORESCIMETRIC DETERMINATION OF RUTHENIUM , 1960 .

[67]  J. Demas,et al.  LUMINESCENCE QUENCHING OF DICYANOBIS(2,2′-BIPYRIDINE)RUTHENIUM(II) AND DICYANOBIS(1,10-PHENANTHROLINE)RUTHENIUM(II) BY TRANSITION METAL COMPLEXES , 1977 .

[68]  B. P. Sullivan,et al.  Hydrido carbonyl complexes of osmium(II) and ruthenium(II) containing polypyridyl ligands , 1984 .

[69]  V. Balzani,et al.  Transition Metal Complexes as Mediators in Photochemical and Chemiluminescence Reactions , 1983 .

[70]  M. DeArmond,et al.  Nonradiative processes in transition metal complexes: Luminescence data for Rh (III) and Ir (III) complexes☆☆☆ , 1971 .

[71]  D. Klassen.  Excited states of mixed ligand complexes of ruthenium (II) with 2-(2-Pyridyl) quinoline and 2,2-biquinoline , 1982 .

[72]  V. Balzani,et al.  Temperature dependence of the bis(2,2'-bipyridine)dicyanoruthenium(II) and bis(2,2'-bipyridine)(2,2'-isobiquinoline)ruthenium(II) luminescence , 1987 .

[73]  C. Tsipis,et al.  A novel μ-terephthalato copper(II) dimer with unexpected strong antiferromagnetic exchange interaction , 1985 .

[74]  T. Meyer,et al.  Comparisons between polypyridyl nitrosyl complexes of osmium(II) and ruthenium(II) , 1984 .

[75]  A. Diamantis,et al.  Preparation and coordination geometry of quadridentate ethylenediaminetetraacetate complexes of ruthenium(II) and -(III) , 1983 .

[76]  B. Brunschwig,et al.  Thermal and light-induced reduction of Ru(bpy)/sub 3//sup 3 +/ in aqueous solution , 1984 .

[77]  W. Krug,et al.  Singlet Energy Transfer from the Charge-Transfer Excited State of Tris( 2,2'-bipyridine)ruthenium( 11) to Laser Dyes , 1983 .

[78]  M. Maestri,et al.  Luminescence quenching of tris(2,2'-bipyridine) complexes of chromium(III), ruthenium(II), and osmium(II) by cyanide complexes , 1978 .

[79]  K. W. Hipps,et al.  Charge-transfer excited states of ruthenium(II) complexes. III. Electron-ion coupling model for d.pi.* configurations , 1975 .

[80]  J. Sauvage,et al.  Synthesis and study of mononuclear ruthenium(II) complexes of sterically hindering diimine chelates. Implications for the catalytic oxidation of water to molecular oxygen , 1986 .

[81]  A. Vogler,et al.  Bipyrimidine-bridged rhenium(I)/rhenium(I) and ruthenium(II)/rhenium(I) complexes. Synthesis, electronic absorption and emission spectra , 1986 .

[82]  Kuppuswamy Kalyanasundaram,et al.  Photophysics, photochemistry and solar energy conversion with tris(bipyridyl)ruthenium(II) and its analogues , 1982 .

[83]  V. Balzani,et al.  Reduction by the triplet charge-transfer state of tris(bipyridyl)ruthenium(II). Photochemical reaction between tris(bipyridyl) ruthenium(II) and thallium(III) , 1974 .

[84]  M. Senda,et al.  Standard redox potentials of R-/R+ reference redox couples and solvent activity coefficients. , 1978 .

[85]  J. Ferguson,et al.  Electronic spectra of M(bipy) 2+ 3 complexions (M = Fe, Ru and Os) , 1979 .

[86]  M. DeArmond.  Relaxation of excited states in transition-metal complexes , 1974 .

[87]  R. Memming,et al.  Electron transfer reactions of excited ruthenium(II) complexes in monolayer assemblies at the SnO2-water interface , 1979 .

[88]  H. Dieck,et al.  Ruthenium complexes with diazabutadienes. III: Trans and cis isomers of dichlorobis(diazabutadiene)ruthenium, (RN=CR'―CR'=NR)2RuCl2 , 1984 .

[89]  Thomas J. Meyer,et al.  Hydrogen-bonding-induced solvatochromism in the charge-transfer transitions of ruthenium(II) and ruthenium(III) ammine complexes , 1983 .

[90]  H. Abruña,et al.  Oxidation of the ligand in nitro complexes of ruthenium(III) , 1980 .

[91]  J. Ibers,et al.  Effect of metal-ligand bond distances on rates of electron-transfer reactions. Crystal structures of hexaammineruthenium(II) iodide, [Ru(NH3)6]I2, and hexaammineruthenium(III) tetrafluoroborate, [Ru(NH3)6][BF4]3 , 1971 .

[92]  J. Demas,et al.  Excited-state acid-base reactions of dicyanobis(2,2'-bipyridine)ruthenium(II) and dicyanobis(1,10-phenanthroline)ruthenium(II) , 1979 .

[93]  R. Watts,et al.  Effect of ligand and solvent deuteration on the excited state properties of the tris(2,2'-bipyridyl)ruthenium(II) ion in aqueous solution. Evidence for electron transfer to solvent , 1975 .

[94]  R. A. Day,et al.  Atom-transfer redox kinetics: general-acid-assisted oxidation of iodide by chloramines and hypochlorite , 1986 .

[95]  M. Maeder,et al.  Charge localization in the luminescent states of Ru(bpy)32+ in fluid solutions , 1985 .

[96]  V. Balzani,et al.  Characterization of the Excited State Properties of Some New Photosensitizers of the Ruthenium (Polypyridine) Family , 1981 .

[97]  S. Roffia,et al.  Electrochemical behaviour of dicyanobis(2,2′-bipyridine) ruthenium(II) and dicyanobis(1,10-phenanthroline) ruthenium(II) complexes , 1977 .

[98]  H. Yersin,et al.  Effect of high pressure on the emission spectrum of tris(2,2'-bipyridine)ruthenium(II) hexafluorophosphate single crystals , 1984 .

[99]  G. Porter,et al.  Photoracemization of Ru (Bipyridine)32 , 1980 .

[100]  C. Párkányi,et al.  Spectroscopic study of the fluorescence and phosphorescence of indolecarboxylic acids in relation to pH , 1981 .

[101]  T. Meyer.  Photochemistry of metal coordination complexes: metal to ligand charge transfer excited states , 1986 .

[102]  H. Abruña,et al.  Photoinduced redox reactions of hydrophobic ruthenium(II) complexes , 1978 .

[103]  R. Marcus.  Exchange reactions and electron transfer reactions including isotopic exchange. Theory of oxidation-reduction reactions involving electron transfer. Part 4.—A statistical-mechanical basis for treating contributions from solvent, ligands, and inert salt , 1960 .

[104]  A. Launikonis,et al.  Light-induced electron-transfer reactions involving the tris(2,2'-bipyridine)ruthenium dication and related complexes. I. The bis(2,2'-bipyridine)(diethyl 2,2'-bipyridine-4,4'-dicarboxylate)ruthenium dication , 1980 .

[105]  W. Dressick,et al.  beta. -cyclodextrin inclusion complexes with. cap alpha. -diimineruthenium(II) photosensitizers , 1985 .

[106]  E. Krausz.  Excited-state Raman spectra in the luminescent states of Ru(bpy)32+ in solid phases , 1985 .

[107]  W. Cherry,et al.  Relaxation processes of electronically excited states in polypyridine ruthenium complexes , 1984 .

[108]  T. Meyer,et al.  Oxidation of primary amines bound to bis(2,2'-bipyridine)ruthenium(II) , 1976 .

[109]  V. Balzani,et al.  Oscillating chemiluminescence from the reduction of bromate by malonic acid catalyzed by tris(2,2'-bipyridine)ruthenium(II) , 1982 .

[110]  I. Hanazaki,et al.  Electronic structure of the tris(.alpha.,.alpha.'-dipyridyl)iron(II) ion , 1969 .

[111]  A. Motten,et al.  ESR of the reduction products of [Fe(bpy)3]2+ and [Ru(bpy)3]2+ , 1981 .

[112]  G. A. Crosby,et al.  Spectroscopic characterization of complexes of ruthenium(II) and iridium(III) with 4,4'-diphenyl-2,2'-bipyridine and 4,7-diphenyl-1,10-phenanthroline , 1971 .

[113]  H. Dürr,et al.  Zum Mechanismus der Photoreduktion von Wasser mit Ruthenium‐trisbipyrazil als Sensibilisator , 1983 .

[114]  B. P. Sullivan,et al.  Multiple emissions from charge transfer excited states of ruthenium(II)—polypyridine complexes , 1978 .

[115]  N. Kitamura,et al.  Time-resolved emission spectra of tris(2,2'-bipyridine)ruthenium dichloride and cis-bis(2,2'-bipyridine)dicyanoruthenium at low temperature , 1986 .

[116]  A. Adamson,et al.  CHEMILUMINESCENCE FROM THE REACTION OF THE HYDRATED ELECTRON WITH TRIS(BIPYRIDYL)RUTHENIUM(III). , 1972 .

[117]  J. Vos,et al.  Polymer-modified electrodes , 1984 .

[118]  V. Balzani,et al.  Excited-state properties of ruthenium(II) tris chelate complexes containing the ligands 2,2'-bipyridine (bpy) and dipyrido(3,2-c:2',3'-e)pyridazine (taphen) , 1986 .

[119]  V. Balzani,et al.  Polypyridine transition metal complexes as light emission sensitizers in the electrochemical reduction of the persulfate ion , 1982 .

[120]  A. Lever,et al.  Ruthenium(II) tris(bipyrazyl) dication: a new photocatalyst , 1980 .

[121]  V. Balzani,et al.  Vertical and "nonvertical" energy transfer processes. A general classical treatment , 1980 .

[122]  G. Crosby.  Optical excitation of transition-metal ions via intramolecular energy transfer , 1967 .

[123]  R. Watts.  Ruthenium polypyridyls: A case study , 1983 .

[124]  R. Watts,et al.  Inversion of Excited States of Transition-Metal Complexes , 1970, Science.

[125]  G. Crosby,et al.  Charge-transfer exited states of ruthenium(II) complexes. I. Quantum yield and decay measurements , 1975 .

[126]  M. Myrick,et al.  Interligand and charge-transfer emission from [Ru(bpy)(HDPA)2]2+: a dual emitting ruthenium(II) complex. , 1986, Journal of the American Chemical Society.

[127]  T. K. Foreman,et al.  Effects of ligand substituents on excited-state reactivity and overall photoredox behavior for (polypyridyl)ruthenium(II) complexes. Laser flash study with potential reductive quenchers , 1981 .

[128]  G. Lawrance.  Redox properties of bis(1,10-phenanthroline)-(pyridine)ruthenium(II) complexes , 1985 .

[129]  G. Crosby,et al.  Charge-transfer excited states of osmium(II) complexes. 1. Assignment of the visible absorption bands , 1980 .

[130]  B. Brunschwig,et al.  Formation of electronically excited products in electron-transfer reactions: reaction of polypyridine complexes of cobalt(I) and ruthenium(III) in acetonitrile , 1986 .

[131]  M. Maeder,et al.  Electronic spectroscopy of M(bpy)2+3 (M = Fe, Ru, Os), Cr(bpy)3+3 and related compounds , 1985 .

[132]  A. Adamson.  Properties of excited states , 1983 .

[133]  N. Sutin,et al.  Kinetics and mechanism of the quenching of the emission of substituted polypyridineruthenium(II) complexes. Reactions of RuL3+, *RuL32+, and RuL33+ with the copper(I)-copper(II) couple , 1978 .

[134]  L. Interrante,et al.  Ruthenium(II) complexes of modified 1,10-phenanthrolines. 1. Synthesis and properties of complexes containing dipyridophenazines and a dicyanomethylene-substituted 1,10-phenanthroline , 1984 .

[135]  C. Creutz,et al.  Electron-transfer reactions of excited states , 1983 .

[136]  F. H. Burstall.  34. Optical activity dependent on co-ordinated bivalent ruthenium , 1936 .

[137]  R. Fabian,et al.  Synthesis and spectroscopic characterization of ruthenium and osmium complexes with sterically hindering ligands. 3. Tris complexes with methyl- and dimethyl-substituted 2,2'-bipyridine and 1,10-phenanthroline , 1980 .

[138]  G. L. Jun. Gaines,et al.  Surfactant tris(2,2'-bipyridine)ruthenium(II) derivatives in aqueous micellar solutions. Absorption and emission spectroscopy and luminescence quenching , 1980 .

[139]  R. Murray,et al.  Transient storage of photochemically produced oxidative and reductive equivalents in soluble redox polymers , 1986 .

[140]  P. D. Fleischauer,et al.  Photoluminescence of transition metal coordination compounds , 1970 .

[141]  W. M. Wallace,et al.  Ion-multiplet formation and the photoanation of tris(2,2'-bipyridine)ruthenium(II) , 1980 .

[142]  N. Kitamura,et al.  Spectroscopic and electrochemical studies on ruthenium(II) complexes containing diazadiimine ligands , 1983 .

[143]  E. Kober,et al.  An electronic structural model for the emitting MLCT excited states of Ru(bpy)32+ and Os(bpy)32+ , 1984 .

[144]  Héctor D. Abruña,et al.  Electropolymerization of vinylpyridine and vinylbipyridine complexes of iron and ruthenium: homopolymers, copolymers, reactive polymers , 1982 .

[145]  V. Balzani,et al.  Quenching and sensitization processes of coordination compounds , 1975 .

[146]  Thomas J. Meyer,et al.  Photochemistry of tris(2,2'-bipyridine)ruthenium(2+) ion (Ru(bpy)32+). Solvent effects , 1983 .

[147]  G. Crosby.  Spectroscopic investigations of excited states of transition-metal complexes , 1975 .

[148]  C. Creutz.  Mechanism of the quenching of the emission of substituted poly(pyridine)ruthenium(II) complexes by europium(II). [Or 1,10-phenanthroline derivative] , 1978 .

[149]  A. Bard,et al.  Electrogenerated Chemiluminescence XXIII. On the Operation and Lifetime of ECL Devices , 1975 .

[150]  G. Crosby,et al.  Spectroscopic studies of ruthenium /II/ complexes - Assignment of the luminescence. , 1968 .

[151]  D. W. Wertz,et al.  Spatially ioslated redox orbitals - an update , 1985 .

[152]  T. Saji,et al.  Polarographic studies on bipyridine complexes , 1975 .

[153]  Katsumi Nakamaru.  Synthesis, Luminescence Quantum Yields, and Lifetimes of Trischelated Ruthenium(II) Mixed-ligand Complexes Including 3,3′-Dimethyl-2,2′-bipyridyl , 1982 .

[154]  G. Crosby,et al.  Emission spectra, decay times, and polarization ratios of ruthenium(II) complexes containing tridentate ligands , 1982 .

[155]  D. Klassen.  Synthesis and spectroscopic characterization of ruthenium and osmium complexes with sterically hindering ligands. 2. Tris complexes with 2-(2'-pyridyl)quinoline and 2,2'-biquinoline , 1976 .

[156]  H. Yersin,et al.  Effect of high pressure on the emission spectrum of [Ru(bpy)₃](PF₆)₂ single crystals , 1984 .

[157]  A. Vlc̆ek.  Ligand based redox series , 1982 .

[158]  D. G. Whitten.  Photochemische Reaktionen oberflächenaktiver Moleküle in Systemen monomolekularer Schichten— Steuerung der Reaktivität durch die Umgebung , 1979 .

[159]  F. Lytle,et al.  CHEMILUMINESCENCE FROM THE REDUCTION OF AROMATIC AMINE CATIONS AND RUTHENIUM(III) CHELATES *, ‡ , 1971 .

[160]  M. Ridd,et al.  Mechanism of oxidation of an amine coordinated to ruthenium , 1981 .

[161]  R. W. Callahan,et al.  Thermal and Light-Induced Decomposition of Azido(bis-2,2′-bipyridine) Complexes of Ruthenium(III) , 1975 .

[162]  Hiroshi Kobayashi,et al.  Electronic Excitation Energy Transfer between Complex Ions , 1970 .

[163]  L. Interrante,et al.  Excited state proton transfer of a metal complex: determination of the acid dissociation constant for a metal-to-ligand charge transfer state of a ruthenium(II) complex , 1977 .

[164]  D. Whitten.  Photoinduced electron transfer reactions of metal complexes in solution , 1980 .

[165]  V. Balzani,et al.  Luminescence of ruthenium(II) tris chelate complexes containing the ligands 2,2'-bipyridine and 2,2'-biisoquinoline. Behavior of the Ru(bpy)2+ and Ru(bpy)22+ emitting units , 1985 .

[166]  J. Calvert,et al.  Metallopolymer photochemistry. Photophysical, photochemical, and photoelectrochemical properties of (bpy)âRu/sup II/ < sites bound to poly(4-vinylpyridine). [Visible radiation] , 1982 .

[167]  J. Demas.  Photophysical pathways in metal complexes , 1983 .

[168]  H. Goodwin,et al.  Light-induced electron-transfer reactions involving the Tris(2,2'-bipyridine)ruthenium dication and related complexes. II. Effect of the 2-(Thiazol-2'-yl)pyridine ligand , 1983 .

[169]  K. Brewer,et al.  The next generation of (polyazine)ruthenium(II) complexes , 1986 .

[170]  A. V. Zelewsky,et al.  On the assignment of the MLCT transition in the Ru(bpy) 2+ 3 complex ion , 1981 .

[171]  H. Abruña,et al.  Spectral, electrochemical and electrocatalytic properties of 1,10-phenanthroline-5,6-dione complexes of transition metals , 1985 .

[172]  L. Wilson,et al.  Synthesis and electrochemical and photoemission properties of mononuclear and binuclear ruthenium(II) complexes containing 2,2'-bipyridine, 2,9-dimethyl-1,10-phenanthroline, 2,2'-bipyrimidine, 2,2'-biimidazole, and 2-pyridinecarboxaldimine ligands , 1978 .

[173]  Katsumi Nakamaru.  Solvent Effect on the Nonradiative Deactivation of the Excited State of Tris(2,2′-bipyridyl)ruthenium(II) Ion , 1982 .

[174]  C. Bignozzi,et al.  Cyano-bridged ruthenium(II)/platinum(II) complexes: synthesis, photophysical properties, and excited-state redox behavior , 1984 .

[175]  D. Rillema,et al.  The low-lying excited state in ligand .pi.-donor complexes of ruthenium(II): mononuclear and binuclear species , 1982 .

[176]  J. G. Haasnoot,et al.  Ruthenium(II)bis(2,2-bipyridyl) complexes of some 1,2,4-triazoles , 1983 .

[177]  F. Lytle,et al.  Luminescence of tris(2,2'-bipyridine)ruthenium(II) dichloride , 1969 .

[178]  K. Kalyanasundaram.  Direct observation of substitutional photochemistry in tris(bipyrazyl)ruthenium(II) , 1986 .

[179]  F. Bolletta,et al.  Chemiluminescence and electrochemiluminescence of coordination compounds , 1986 .

[180]  G. Navon,et al.  Mechanism of the quenching of the phosphorescence of tris(2,2'-bipyridine)ruthenium(II) by some cobalt(III) and ruthenium(III) complexes , 1974 .

[181]  B. P. Sullivan,et al.  Mixed amminc-olefin complexes of ruthenium(II) [15] , 1977 .

[182]  J. Demas,et al.  On the "intersystem crossing" yields in ruthenium(II) and osmium(II) photosensitizers , 1979 .

[183]  A. Saaman,et al.  Synthesis, electrochemical properties, and charge-transfer band of binuclear 1,10-phenanthroline/bis(2,2'-bipyridine) complexes of ruthenium , 1981 .

[184]  C. Carlin,et al.  Evidence for symmetry reduction in excited states of [Ru(bpy)3]+ and related compounds , 1982 .

[185]  Richard J. Watts,et al.  Excited-state properties of a triply ortho-metalated iridium(III) complex , 1985 .

[186]  G. L. Gaines.  Coulombic effects in the quenching of photoexcited tris(2,2'-bipyridine)ruthenium(II) and related complexes by methyl viologen , 1979 .

[187]  D. Meisel,et al.  Reaction of eaq- into excited states of tris(2,2'-bipyridine)ruthenium(2+) , 1978 .

[188]  N. Sutin.  Theory of electron transfer reactions: insights and hindsights , 2007 .

[189]  M. Grätzel,et al.  Towards the Construction of a Complete Cyclic Water Decomposition System, Design and Operation of an Oxygen Producing Half Cell , 1979 .

[190]  G. Crosby,et al.  Luminescence from Transition‐Metal Complexes: Tris(2,2′‐bipyridine)‐ and Tris(1,10‐phenanthroline)Ruthenium(II) , 1965 .

[191]  E. Kober,et al.  Concerning the absorption spectra of the ions M(bpy)32+ (M = Fe, Ru, Os; bpy = 2,2'-bipyridine) , 1982 .

[192]  Jean-Marie Lehn,et al.  Photoactive cryptands. Synthesis of the sodium cryptates of macrobicyclic ligands containing bipyridine and phenoanthroline groups , 1984 .

[193]  D. E. Morris,et al.  Electrochemical and ESR studies of [Fe(terpy)2]2+ and [Ru(terpy)2]2+ and their reduction products , 1983 .

[194]  V. Balzani,et al.  Photosensitized aquation of the hexacyanochromate(III) ion. Evidence against the doublet mechaism , 1972 .

[195]  C. Creutz,et al.  Electron-transfer reactions of excited states: direct evidence for reduction of the charge-transfer excited state of tris(2,2'-bipyridine)ruthenium(II) , 1976 .

[196]  M. Wrighton,et al.  Resonance Raman spectroscopy of the lowest excited state of derivatives of tris(2,2'-bipyridine)ruthenium(II): substituent effects on electron localization in mixed-ligand complexes , 1986 .

[197]  D. Ege,et al.  Electrogenerated chemiluminescent determination of Ru(bpy)3(2+) at low levels. , 1984, Analytical chemistry.

[198]  M. Newton,et al.  Electron Transfer Reactions in Condensed Phases , 1984 .

[199]  M. Graetzel,et al.  Light-induced charge injection in functional crown ether vesicles , 1980 .

[200]  C. Creutz,et al.  Mechanism of the quenching of the emission of substituted polypyridineruthenium(II) complexes by iron(III), chromium(III), and europium(III) ions , 1976 .

[201]  Gilbert M. Brown,et al.  Oxidation of coordinated diamines in bis(2,2'-bipyridine) complexes of ruthenium , 1976 .

[202]  M. R. Snow,et al.  Oxidation of isopropylamine and related amines coordinated to ruthenium. Formation of monodentate imine and alkylideneamido complexes of ruthenium , 1984 .

[203]  D. Behnken,et al.  Preparation and monolayer properties of surfactant tris(2,2'-bipyridine)ruthenium(II) derivatives , 1979 .

[204]  V. Balzani,et al.  Energy-transfer processes of excited states of coordination compounds , 1983 .

[205]  R. C. Young,et al.  Photochemical Generation of Ru(bpy)3+ and 02 - , 1977 .

[206]  V. Balzani,et al.  EXCITED-STATE PROPERTIES OF COMPLEXES OF THE TRIS(DIIMINE)RUTHENIUM(2+) ION FAMILY , 1983 .

[207]  R. C. Young,et al.  Electron transfer quenching of nonemitting excited states of Ru(TPP)(py)2 and Ru(trpy)22 , 1978 .

[208]  T. Meyer,et al.  Alkyl nitrite complexes of ruthenium prepared by acid-base chemistry at the bound nitrosyl group , 1980 .

[209]  H. Offen,et al.  Luminescence lifetimes of ruthenium(II) polypyridyls in water and water-d2 at high pressures , 1986 .

[210]  D. McMillin,et al.  Photochemistry and photophysics of bis(terpyridyl) complexes of ruthenium(II) in fluid solution. Evidence for the formation of an .eta.2-diphenylterpyridine complex , 1985 .

[211]  D. E. Morris,et al.  ESR studies of the redox orbitals in diimine complexes of iron(II) and ruthenium(II) , 1983 .

[212]  H. Offen,et al.  Luminescence of ruthenium(II) and osmium(II) polypyridyls in acetonitrile at high pressures , 1985 .

[213]  R. Schmehl,et al.  Independent control of charge-transfer and metal-centered excited states in mixed-ligand polypyridine ruthenium(II) complexes via specific ligand design , 1986 .

[214]  P. Fuochi,et al.  On the nature of tris(2,2'-bipyridine)ruthenium(1+) ion in aqueous solution , 1978 .

[215]  Y. Ohsawa,et al.  A proton NMR study of reduced paramagnetic tris(2,2'-bipyridine) complexes of iron(II), ruthenium(II) and osmium(II) , 1985 .

[216]  W. E. Ohnesorge,et al.  Effect of ligand field strength on charge transfer luminescence of several bis-(1,10-phenanthroline) ruthenium(II) chelates , 1972 .

[217]  V. Balzani,et al.  Electron-transfer quenching of the luminescence of ruthenium and osmium polypyridine complexes by cobalt(III) complexes , 1984 .

[218]  V. Balzani,et al.  Intersystem crossing efficiency in the hexacyanochromate(III) ion , 1974 .

[219]  C. M. Elliott.  Electrochemistry and near infrared spectroscopy of tris(4,4′-dicarboxyethyl-2,2′-bipyridine)ruthenium(II) , 1980 .

[220]  V. Balzani,et al.  Absorption spectra, electrochemical behavior, luminescence spectra, and excited-state lifetimes of mixed-ligand ortho-metalated rhodium(III) complexes , 1987 .

[221]  J. Ferguson,et al.  The electronic structure of the metal-to-ligand charge-transfer states of M(bpy)2+3 (M = Fe, Ru, Os) , 1982 .

[222]  J. Ferguson,et al.  Magnetically circular-polarized luminescence (MCPL) evidence for the transition from delocalized to localized luminescent states of tris(2,2'-bipyridine)ruthenium(2+) in glass-fluid media , 1986 .

[223]  V. Balzani,et al.  Electron transfer reactions involving light , 1983 .

[224]  V. Balzani,et al.  Laser flash spectroscopy of tris(2,2'-bipyridine)ruthenium(II) in solution , 1976 .

[225]  D. Whitten,et al.  Photoreactions of transition metal complexes. Ligand reactivity as a probe for excited-state characterization , 1973 .

[226]  N. Sutin.  Nuclear, electronic, and frequency factors in electron transfer reactions , 1982 .

[227]  P. Bugnon,et al.  Spectro-electrochemical studies of some nitrogen-donor bidentate complexes of ruthenium(II) , 1983 .

[228]  B. Brunschwig,et al.  Reactions of the excited states of substituted polypyridinechromium(III) complexes with oxygen, iron(II) ions, ruthenium(II) and -(III), and osmium(II) and -(III) complexes , 1978 .

[229]  A. Ludi,et al.  Ruthenium(II)-bipyrimidine complexes. Spectroscopic and electrochemical properties of a novel series of compounds , 1977 .

[230]  Redox asymmetry and metal-metal coupling in pyrazine-bridged ruthenium dimers , 1985 .

[231]  J. Demas,et al.  Excited state acid-base reactions of transition metal complexes: dicyanobis(2,2'-bipyridine) ruthenium(III) in aqueous acid , 1976 .

[232]  Y. Kaizu,et al.  Lifetimes of the lowest excited state of tris(2,2′-bipyridine)ruthenium(II) and its amphipathic derivative in micellar systems , 1985 .

[233]  C. Creutz,et al.  Reaction of tris(bipyridine)ruthenium(III) with hydroxide and its application in a solar energy storage system. , 1975, Proceedings of the National Academy of Sciences of the United States of America.

[234]  W. O. Siegl,et al.  Synthesis and characterization of mononuclear and binuclear ruthenium complexes of 1,3-bis(2-pyridylimino)isoindolines , 1982 .

[235]  R. Marcus,et al.  Theory of highly exothermic electron transfer reactions , 1982 .

[236]  G. Newkome,et al.  Effect of chelate ring size on the photoanation reaction of polypyridine ruthenium complexes , 1985 .

[237]  T. Meyer,et al.  Redox Properties of Ruthenium(II) Tris Chelate Complexes Containing the Ligands 2,2′-Bipyrazine, 2,2′-Bipyridine, and 2,2/-Bipyrimidine , 1983 .

[238]  J. Ferguson,et al.  The electronic spectrum of tris(2,2'-bipyridine)ruthenium(2+) , 1980 .

[239]  M. Haga,et al.  Synthesis and protonation-deprotonation reactions of ruthenium(II) complexes containing 2, 2′-bibenzimidazole and related ligands , 1983 .

[240]  A. Lever,et al.  Comparative chemistry of bipyrazyl and bipyridyl metal complexes: spectroscopy, electrochemistry and photoanation , 1982 .

[241]  C. W. Hudson,et al.  Synthesis and spectroscopic characterization of bis[2,6-di(2'-quinolyl)pyridine] complexes of ruthenium(II) and osmium(II) , 1975 .

[242]  J. Calvert,et al.  Poly(pyridyl)ruthenium(II) Complexes of Poly(4-vinylpyridine). Synthesis, Characterization, and Investigation of Optical and Electrochemical Properties, , 1981 .

[243]  E. Kober,et al.  Concerning the electronic structure of the ions M(bpy)33+ (M = Fe, Ru, Os; bpy = 2,2'-bipyridine) , 1983 .

[244]  G. Crosby,et al.  Excited states of mixed ligand chelates of ruthenium(II) and rhodium(III) , 1976 .

[245]  S. Mandal,et al.  Resonance Raman spectra of iron(II) and ruthenium(II) complexes with perdeuteriated 2,2′-bipyridine , 1984 .

[246]  J. Calvert,et al.  Polypyridine complexes of ruthenium(II) bound to poly(4-vinylpyridine). Synthesis, characterization, and thin-film electrochemistry of a series of bis(bipyridine) metallopolymers , 1982 .

[247]  W. Krug,et al.  Charge-transfer luminescence from a nonaromatic .alpha.-diimine complex of ruthenium(II) , 1979 .

[248]  A. Adamson,et al.  Chemiluminescence: An Illuminating Experiment. , 1975 .

[249]  J. Demas,et al.  On the multiplicity of the emitting state of ruthenium(II) complexes , 1968 .

[250]  A. W. Cordes,et al.  Six-coordinate complexes with 1,10-phenanthroline ligands in the trans configuration. Preparation of trans-bis(1,10-phenanthroline)ruthenium(II) complexes and crystal structure of trans-bis(1,10-phenanthroline)bis(pyridine)ruthenium(II) hexafluorophosphate , 1983 .

[251]  A. Cox,et al.  Demonstration of two non-radiative pathways in the decay of luminescent complexes of ruthenium(II) in a variety of solvents , 1976 .

[252]  T. Meyer,et al.  Directed, intramolecular electron transfer in mixed-valence dimers , 1985 .

[253]  B. P. Sullivan,et al.  Solvent dependence of metal-to-ligand charge-transfer transitions. Evidence for initial electron localization in MLCT excited states of 2,2'-bipyridine complexes of ruthenium(II) and osmium(II) , 1984 .

[254]  W. Cherry,et al.  Dynamics of ligand field excited states in polypyridine ruthenium(II) complexes , 1985 .

[255]  V. Balzani,et al.  Temperature dependence of the luminescence emission of ruthenium(II) complexes containing the ligands 2,2'-bipyridine and dipyrido[3,2-c:2',3'-e]pyridazine , 1986 .

[256]  E. Kober,et al.  Application of the energy gap law to the decay of charge transfer excited states, solvent effects , 1982 .

[257]  F. Keene,et al.  Oxidation of isopropylamine coordinated to ruthenium , 1981 .

[258]  R. C. Young,et al.  Electron transfer quenching of excited states of metal complexes , 1976 .

[259]  R. W. Callahan,et al.  Intervalence transfer and electron transfer in themixed-valence ion [(bpy)₂ClRu(pyz)RuCl(bpy)₂]³⁺ , 1977 .

[260]  R. Murray,et al.  Synthetic and mechanistic investigations of the reductive electrochemical polymerization of vinyl-containing complexes of iron(II), ruthenium(II), and osmium(II) , 1983 .

[261]  A. Bard,et al.  Electrogenerated chemiluminescence. XIII. Electrochemical and electrogenerated chemiluminescence studies of ruthenium chelates , 1973 .

[262]  T. Meyer.  Electron Transfer Reactions Induced by Excited State Quenching , 1976 .

[263]  W. W. Brandt,et al.  Polysubstituted 1,10-Phenanthrolines and Bipyridines as Multiple Range Redox Indicators , 1949 .

[264]  R. Watts,et al.  Photochemistry of tris(2,2'-bipyridyl)ruthenium(II) in aqueous solutions , 1978 .

[265]  R. D. Wright,et al.  Electronic absorption and emission spectra of mixed-ligand ruthenium(II) complexes [Ru(2,2'-bipyridine)n {2-(2-pyridyl)quinoline}3−n]2+(n = 0,1,2 or 3) , 1980 .

[266]  D. Whitten,et al.  Photochemistry of ruthenium complexes. Ligand isomerization via orbitally different excited states , 1971 .

[267]  B. Divisia-Blohorn.  Solvent effects on the electrochemical properties of IrCl2(bpy)2 , 1986 .

[268]  B. Moyer,et al.  Properties of the oxo/aqua system (bpy)2(py)RuO2+/(bpy)2(py)Ru(OH2)2+ , 1981 .

[269]  T. Meyer,et al.  Photochemistry of MLCT excited states. Effect of nonchromophoric ligand variations on photophysical properties in the series cis-Ru(bpy)2L22+ , 2002 .

[270]  R. Ballardini,et al.  Experimental investigation of highly exergonic outer-sphere electron-transfer reactions , 1984 .

[271]  A. Adamson,et al.  Excited state Ru(bipyr)32+ as an electron-transfer reductant , 1972 .

[272]  V. Balzani,et al.  Electrogenerated chemiluminescence of an ortho-metalated platinum(II) complex , 1986 .

[273]  G. Crosby,et al.  Charge-transfer luminescence from ruthenium(II) complexes containing tridentate ligands , 1981 .

[274]  R. A. Krause,et al.  Chemistry of bipyridyl-like ligands. III: Complexes of ruthenium(II) with 2-((4-nitrophenyl)azo)pyridine , 1984 .

[275]  J. Beattie,et al.  Oxidative dehydrogenation of ethylenediamine complexes of ruthenium(II) , 1973 .

[276]  D. Rillema,et al.  Structure of tris(2,2′-bipyridyl)ruthenium(II) hexafluorophosphate, [Ru(bipy)3][PF6]2; X-ray crystallographic determination , 1979 .

[277]  Rudolph A. Marcus,et al.  Theoretical relations among rate constants, barriers, and Broensted slopes of chemical reactions , 1968 .

[278]  Roald Hoffmann,et al.  Interaction of orbitals through space and through bonds , 1971 .

[279]  V. Balzani,et al.  Ligand-centered luminescence from a ruthenium(II) complex , 1982 .

[280]  A. Lever,et al.  Relationships between electronic spectroscopy and electrochemistry. A probe of reorganisation energies , 1985 .

[281]  J. Selbin,et al.  Cyclometalated complexes of ruthenium. 2. Spectral and electrochemical properties and x-ray structure of bis(2,2'-bipyridine)(4-nitro-2-(2-pyridyl)phenyl)ruthenium(II) , 1985 .

[282]  R. Hester,et al.  Resonance raman investigation of electronically excited ru(bipyridine)2+3 using a cw laser , 1981 .

[283]  K. W. Hanck,et al.  Electrochemistry of iridium-bipyridine complexes , 1978 .

[284]  G. Crosby.  Luminescence as a Probe of Excited State Properties , 1976 .

[285]  M. Maestri,et al.  Quantum yield of formation of the lowest excited state of Ru(bpy)2+3 and Ru(phen)2+3 , 1980 .

[286]  V. Balzani,et al.  Concerning the nonadiabaticity problem in outer-sphere electron- and energy-transfer reactions , 1986 .

[287]  L. Orgel.  715. Double bonding in chelated metal complexes , 1961 .

[288]  D. Kliger,et al.  Transient circular dichroism of the luminescent state of Ru(bpy)32 , 1985 .

[289]  B. Sullivan,et al.  Chemistry of highly reduced polypyridyl-metal complexes. Anion substitution induced by ligand-based reduction , 1985 .

[290]  R. Mukherjee,et al.  Chemistry of ruthenium. 12. Reactions of bidentate ligands with diaquabis[2-(arylazo)pyridine]ruthenium(II) cation. Stereoretentive synthesis of tris chelates and their characterization: metal oxidation, ligand reduction, and spectroelectrochemical correlation , 1983 .

[291]  C. Tait,et al.  Ligand charge localization in tris(2-(2'-pyridyl)quinoline)ruthenium(II), tris(2,2'-biquinoline)ruthenium(II), and their first three reduction products , 1986 .

[292]  G. Porter,et al.  The photochemistry of Ru(bpy)32+ in basic medium , 1982 .

[293]  W. Cherry,et al.  Selective perturbation of ligand field excited states , 1985 .

[294]  Rudolph A. Marcus,et al.  Chemical and Electrochemical Electron-Transfer Theory , 1964 .

[295]  M. Wrighton,et al.  Excited state proton transfer of ruthenium(II) complexes of 4,7-dihydroxy-1,10-phenanthroline. Increased acidity in the excited state , 1978 .

[296]  K. A. Norton,et al.  Electrochemistry in Liquid Sulfur Dioxide. 5. Oxidation of Bipyridine and Phenanthroline Complexes of Osmium, Ruthenium, and Iron , 1984 .

[297]  I. Rubinstein,et al.  Electrogenerated chemiluminescence. 42. Electrochemistry and electrogenerated chemiluminescence of the tris(2,2'-bipyrazine)ruthenium(II) system , 1983 .

[298]  J. Demas,et al.  Luminescence quenching of the tris(2,2'-bipyridine)ruthenium(II) and tris(1,10-phenanthroline)ruthenium(II) cations , 1976 .

[299]  M. Root,et al.  Quencher ligand binding to luminescent complexes. Luminescent phenothiazine polypyridine Ru(II) complexes , 1983 .

[300]  G. Crosby,et al.  Excited states of mixed-ligand chelates of ruthenium. II. Quantum yield and decay time measurements , 1981 .

[301]  J. Ferguson,et al.  A model for the interpretation of the electronic spectra of the complex ions M(bpy)32+ (M = Fe, Ru, Os) in D3 and C2 sites , 1983 .

[302]  Photosubstitution reactions of Ru(bpy)2XYn+ complexes , 1984 .

[303]  V. Balzani,et al.  The nonadiabaticity problem of outer-sphere electron-transfer reactions. Reduction and oxidation of europium ions , 1981 .

[304]  J. Ferguson,et al.  The assignment of the luminescent states of Ru(bpy)2+3. MCPL and time-resolved luminescence at 2.0 K , 1982 .

[305]  V. Balzani,et al.  Photochemical preparation of luminescent platinum(IV) complexes via oxidative addition on luminescent platinum(II) complexes. , 1986, Journal of the American Chemical Society.

[306]  Mauro Maestri Michael-Grätzel.  530 nm-Laser Photolysis Studies of the Photo Reduction of Tris (2,2-bipyridine)-ruthenium(II) by Organic Donors , 1977 .

[307]  A. Lever,et al.  Correlations between Electrochemical Potentials and Optical Charge Transfer Energies in Ruthenium Bipyridine Derivatives. , 1985 .

[308]  V. Balzani,et al.  "Second-sphere" photochemistry and photophysics of coordination compounds , 1986 .

[309]  N. Kress,et al.  Vibrational spectroscopy of the electronically excited state. 5. Time-resolved resonance Raman study of tris(bipyridine)ruthenium(II) and related complexes. Definitive evidence for the "localized" MLCT state , 1981 .

[310]  Richard S. Lumpkin,et al.  Time-resolved emission at the glass-to-fluid transition. Localization or delocalization in polypyridyl-based metal-to-ligand charge-transfer excited states of ruthenium and osmium? , 1987 .

[311]  C. M. Elliott,et al.  Electrochemical and spectral investigations of ring-substituted bipyridine complexes of ruthenium , 1982 .

[312]  C. Bignozzi,et al.  Simple poly(pyridine)ruthenium(II) photosensitizer: (2,2'-bipyridine)tetracyanoruthenate(II). , 1986, Journal of the American Chemical Society.

[313]  R. A. Krause,et al.  Chemistry of bipyridyllike ligands. 2. Mixed complexes of ruthenium(II) with 2-(phenylazo)pyridine: a new .pi.-bonding probe , 1982 .

[314]  V. Balzani,et al.  Bimolecular electron transfer processes of electronically excited tris(2,2'-bipyridine)chromium(III) , 1976 .

[315]  J. Demas,et al.  Tris (2,2'-bipyridine)ruthenium(II) sensitized reactions of some oxalato complexes , 1973 .

[316]  B. P. Sullivan,et al.  Isocyanide-bis(2,2'-bipyridine) complexes of ruthenium(II). A new synthetic route to complexes of ruthenium via the ion [(bpy)2Ru(DME)]2+ , 1979 .

[317]  J. N. Demas,et al.  Energy transfer from luminescent transition metal complexes to oxygen , 1977 .

[318]  Joshua Jortner,et al.  The energy gap law for radiationless transitions in large molecules , 1970 .

[319]  Y. Ohsawa,et al.  Electrochemistry and spectroscopy of ortho-metalated complexes of iridium(III) and rhodium(III) , 1987 .

[320]  M. Grätzel,et al.  Optical absorption spectrum of excited ruthenium tris-bipyridyl (Ru(bpy)2+3) , 1979 .

[321]  D. Lerner,et al.  New ruthenium(II) complexes with pyridylpyrazole ligands. Photosubstitution and /sup 1/H, /sup 13/C, and /sup 99/Ru NMR structural studies , 1983 .

[322]  W. Dressick,et al.  New probe of solvent accessibility of bound photosensitizers. 2. Ruthenium(II) and Osmium(II) photosensitizers in Triton X-100 micelles , 1984 .

[323]  K. W. Hanck,et al.  Electron transfer sequence and mechanism for bis bipyridine complexes of Ru(II) , 1984 .

[324]  T. Meyer,et al.  Directed, intramolecular electron and energy transfer in mixed-valence dimers , 1981 .

[325]  J. Ferguson,et al.  Time-resolved luminescence and MCPL of Ru(bpy)2+3 in glassy solvents at the fluid-glass transition , 1986 .

[326]  S. Roffia,et al.  Electrochemical and spectroscopic behaviour of cyanobridged bi- and trinuclear complexes of ruthenium containing 2,2'-bipyridine and ammonia as ligands. Convolutive potential sweep voltammetric study of two nernstian waves , 1986 .

[327]  J. S. Harrington,et al.  Photochemical and Photophysical Processes in 2,2'-Bipyridine Complexes of Iridium(III) and Ruthenium(II) , 1978 .

[328]  T. G. Hayes,et al.  Resonance Raman spectra of the ground and excited states of specifically deuterated tris(2,2'-bipyridine)ruthenium(II) , 1983 .

[329]  E. Tsuchida,et al.  The Synthesis and Luminescence Quenching of the Water-soluble Polymer-supported Tris(2,2′-bipyridine)ruthenium(II) Analogue , 1982 .

[330]  N. Turro,et al.  Photosensitization by reversible electron transfer: theories, experimental evidence, and examples , 1986 .

[331]  A. K. Mesmaeker,et al.  Photoelectrochemistry of a new ruthenium complex, the Ru(II)-tris-(1,4,5,8-tetraazaphenanthrene) dication , 1985 .

[332]  A. Bard,et al.  Electrochemistry in Liquid Sulfur Dioxide. 3. Electrochemical Production of New Highly Oxidized 2,2′-Bipyridine Complexes of Ruthenium and Iron , 1982 .

[333]  F. J. Holler,et al.  Mixed-ligand poly(pyridine) complexes of ruthenium(II). Resonance Raman spectroscopic evidence for selective population of ligand-localized 3MLCT excited states , 1985 .

[334]  S. Angel,et al.  Resonance Raman spectra of the first three reduction products of tris(bipyridyl)ruthenium(II) , 1984 .

[335]  M. Grätzel,et al.  Tris (2,2? bipyridine 4,4? dicarboxylic acid) Ruthenium (II), a redox sensitizer affording water oxidation to oxygen in the absence of a heterogeneous catalyst , 1985 .

[336]  C. Carlin,et al.  Temperature-dependent photoselection-intramolecular exciton motion in tris(2,2'-bipyridine)ruthenium [Ru(bpy)3]2+ , 1985 .

[337]  Peter Belser,et al.  Synthese, spektroskopische Eigenschaften und elektrochemisches Verhalten von Ruthenium(II)-Komplexen mit zweizähnigen Stickstoffliganden , 1980 .

[338]  D. Rehm,et al.  Kinetics of Fluorescence Quenching by Electron and H‐Atom Transfer , 1970 .

[339]  R. Levine,et al.  Energy, entropy and the reaction coordinate: thermodynamic-like relations in chemical kinetics☆ , 1977 .

[340]  V. Balzani,et al.  New Photosensitizers of the Ruthenium‐Polypyridine Family for the Water Splitting Reaction , 1982 .

[341]  V. Balzani,et al.  Luminescence of mixed-ligand polypyridine−ruthenium(II) complexes in the temperature range 84−250 K. Interligand interactions and viscosity effects on radiationless processes , 1985 .

[342]  E. Kober,et al.  Critical Deactivating Modes for the Metal-2,2'-Bipyridine or -1,10-Phenanthroline MLCT Excited States , 1985 .

[343]  J. CrutchleyR,et al.  ビピラジルおよびビピリジル金属錯体の化学の比較: スペクトル,電気化学および光アネーション , 1982 .

[344]  T. Meyer,et al.  Photochemistry of Ru( bpy)32+. Solvent Effects , 1983 .

[345]  Y. Ohsawa,et al.  A systematic electrochemical and spectroscopic study of mixed-ligand ruthenium(II) 2,2′-bipyridine complexes [Ru(bpy)3-nLn]2+ (n=0,1,2 and 3) , 1984 .

[346]  G. Hensler,et al.  Fine structure in the emission spectrum of [Ru(bpy)3] (PF6)2 single crystals , 1986 .

[347]  A. Chakravorty,et al.  Chemistry of ruthenium. 3. Synthesis, structure, and electron-transfer behavior of trans-dihalobis[(arylazo)oximato]ruthenium(III) , 1981 .

[348]  W. W. Brandt,et al.  Chelate Complexes of 1,10-Phenanthroline and Related Compounds. , 1954 .

[349]  G. Crosby,et al.  Symmetry assignments of the lowest CT excited states of ruthenium (II) complexes via a proposed electronic coupling model , 1973 .

[350]  T. Saji,et al.  A Voltammetric Study of the Reduction of Ruthenium(II) Complexes with Mixed Ligands , 1982 .

[351]  T. Meyer,et al.  Synthetic applications of photosubstitution reactions of poly(pyridyl) complexes of ruthenium (II) , 1980 .

[352]  M. Scandola,et al.  Role of the excited states in the photoreaction of the hexacyanochromate(III) ion. Sensitization study , 1973 .

[353]  G. Mclendon,et al.  Collisionless photoinduced electron transfer from ruthenium tris(bipyridine)2+* homologs to methyl viologen (MV2+) in rigid glycerol solution , 1983 .

[354]  S. Goswami,et al.  Chemistry of ruthenium. 2. Synthesis, structure, and redox properties of 2-(arylazo)pyridine complexes , 1981 .

[355]  A. Ceulemans,et al.  Charge-transfer spectra of iron(II)- and ruthenium(II)-tris(2,2'-bipyridyl) complexes , 1981 .

[356]  A. Lever,et al.  Resonance raman spectra of Ru(bipyridine)3(ClO4)2 and Ru(bipyrazine)3(PF6)2 in relation to the phosphorescence lifetimes , 1982 .

[357]  D. Robbins,et al.  Radiationless processes in transition-metal complexes , 1973 .

[358]  N. Sutin,et al.  Quenching of the luminescence of the tris(2,2'-bipyridine) complexes of ruthenium(II) and osmium(II). Kinetic considerations and photogalvanic effects , 1976 .

[359]  S. Licoccia,et al.  Charge-transfer spectra of metallophthalocyanines: correlation with electrode potentials , 1981 .

[360]  O. Haas,et al.  Preparation, characterisation and electrochemistry of electrodes coated with poly (4-vinylpyridine) bound ruthenium complexes , 1980 .

[361]  Y. Ohsawa,et al.  An electrochemical study of quenching reactions of polypyridine complexes of Ru(II) and Os(II) in excited states , 1980 .

[362]  T. Meyer,et al.  MOLECULAR AND ELECTRONIC STRUCTURE IN THE METAL‐TO‐LIGAND CHARGE‐TRANSFER EXCITED STATES OF D6 TRANSITION‐METAL COMPLEXES IN SOLUTION , 1984 .

[363]  B. P. Sullivan,et al.  Monomeric and dimeric pyrazole and pyrazolyl complexes of ruthenium , 1979 .

[364]  A. Juris,et al.  Catalytic Efficiency of Hydrated RuO2for the Photooxidation of Water in a Sacrificial System , 1982 .

[365]  G. Hensler,et al.  Low-temperature emission spectra of crystalline [Ru(bpy)3](ClO4)2 , 1985 .

[366]  W. Woodruff,et al.  Time-resolved resonance Raman study of the lowest (d.pi.*,3CT) excited state of tris(2,2'-bipyridine)ruthenium(II) , 1979 .

[367]  G. A. Crosby,et al.  Quantum efficiencies on transition metal complexes. II. Charge-transfer luminescence , 1971 .

[368]  T. Matsumura-Inoue,et al.  Relation between electrode potentials and electronic spectra of Ru(III)-α,α′-bipyridine complexes , 1979 .