Biomass gasification for synthesis gas production and applications of the syngas

Synthesis gas from biomass can be produced and utilized in different ways. Conversion of biomass to synthesis gas can be done either in fluidized bed or entrained flow reactors. As gasification agent oxygen, steam, or mixtures are used. The most common use of biomass gasification in the last decades has been for heat and/or power production. Nowadays, the importance of transportation fuels from renewables is increased due to environmental aspects and growing fossil fuels prices. That is why the production of Fischer‐Tropsch (FT) liquids, methanol, mixedalcohols,substitutenaturalgas(SNG),andhydrogenfrombiomassisnowin focus of view. The most innovative and interesting ways of synthesis gas utilization andprojects,BioTfueLorGoBiGas,BioLiq,Choren,etc.arediscussedhere.Further the microchannel technology by Oxford Catalysts and distributed production of SNG in decentral small scale are presented. The synthesis platform in G¨ ussing, Austria is also presented. The FT liquids, hydrogen production, mixed alcohols, and BioSNG, these are the projects associated with the FICFB gasification plant in G¨ ussing. Also the principle and examples of sorption-enhanced reforming to adjust H2/CO ratio in product gas during the gasification is described. Finally, in the conclusion also an outlook for the thermochemical pathway to transportation fuels is given. © 2013 John Wiley & Sons, Ltd.

[1]  A. Friedl,et al.  Renewable hydrogen production: a technical evaluation based on process simulation , 2010 .

[2]  Hermann Hofbauer,et al.  BioSNG—process simulation and comparison with first results from a 1-MW demonstration plant , 2011 .

[3]  Cecília M.V.B. Almeida,et al.  The roles of cleaner production in the sustainable development of modern societies: an introduction to this special issue , 2010 .

[4]  Cole Boulevard,et al.  Preliminary Screening — Technical and Economic Assessment of Synthesis Gas to Fuels and Chemicals with Emphasis on the Potential for Biomass-Derived Syngas , 2003 .

[5]  A. Faaij,et al.  Exploration of the possibilities for production of Fischer Tropsch liquids and power via biomass gasification , 2002 .

[6]  A. Rodrigues,et al.  Adsorption of Carbon Dioxide onto Hydrotalcite-like Compounds (HTlcs) at High Temperatures , 2001 .

[7]  L. Fan,et al.  Carbonation−Calcination Cycle Using High Reactivity Calcium Oxide for Carbon Dioxide Separation from Flue Gas , 2002 .

[8]  R.W.R. Zwart,et al.  "GREEN GAS" AS SNG (SYNTHETIC NATURAL GAS) A RENEWABLE FUEL WITH CONVENTIONAL QUALITY , 2006 .

[9]  Stewart Brown,et al.  “Catalysis in the Refining of Fischer-Tropsch Syncrude” , 2011 .

[10]  Bo Feng,et al.  Screening of CO2 adsorbing materials for zero emission power generation systems , 2007 .

[11]  H. Hofbauer,et al.  Influence of operating conditions on the performance of biomass-based Fischer–Tropsch synthesis , 2012, Biomass Conversion and Biorefinery.

[12]  Zou Yong,et al.  Adsorption of carbon dioxide at high temperature—a review , 2002 .

[13]  H. Hiller In: Ullmann''''s Encyclopedia of Industrial Chemistry , 1989 .

[14]  A. M. Squires Cyclic Use of Calcined Dolomite to Desulfurize Fuels Undergoing Gasification , 1967 .

[15]  Arno de Klerk,et al.  Can Fischer−Tropsch Syncrude Be Refined to On-Specification Diesel Fuel? , 2009 .

[16]  M. Thring World Energy Outlook , 1977 .

[17]  Hermann Hofbauer,et al.  Comparison of dual fluidized bed steam gasification of biomass with and without selective transport of CO2 , 2009 .

[18]  J. Karl Distributed Generation of Substitute Natural Gas from Biomass , 2008 .

[19]  J. R. Hess,et al.  Process Design and Economics for Conversion of Lignocellulosic Biomass to Ethanol , 2011 .

[20]  Douglas P. Harrison,et al.  Sorption‐Enhanced Hydrogen Production: A Review , 2008 .

[21]  T. Schildhauer,et al.  Production of synthetic natural gas (SNG) from coal and dry biomass - A technology review from 1950 to 2009 , 2010 .

[22]  F. Lau,et al.  Techno-Economic Analysis of Hydrogen Production by Gasification of Biomass , 2002 .

[23]  A. B. Rao,et al.  A technical, economic, and environmental assessment of amine-based CO2 capture technology for power plant greenhouse gas control. , 2002 .

[24]  Jie He,et al.  Review of syngas production via biomass DFBGs , 2011 .

[25]  Hermann Hofbauer,et al.  In Situ CO2 Capture in a Dual Fluidized Bed Biomass Steam Gasifier – Bed Material and Fuel Variation , 2009 .

[26]  Dick van Dijk,et al.  Methanol from Natural Gas: Conceptual Design & Comparison of Processes , 1995 .