Formation of Palladium Silicide on Heavily Doped Si(001) Substrates Using Ti Intermediate Layer

The formation of palladium silicide on Pd/Ti/Si systems with and without heavy B-doping has been investigated. For comparison, Pd2Si was also formed on Pd/Si systems. The agglomeration of Pd2Si could be retarded in Pd/Ti/Si systems with and without B-doping after annealing at 600 °C. The existence of the Ti layer could improve the thermal stability of Pd2Si. In addition, epitaxial or highly oriented Pd2Si formed in Pd/Ti/Si systems. The two orientation relationships of Pd2Si layers were identified to be Pd2Si[110]∥Si[110] and Pd2Si[110]∥Si[001], and Pd2Si[100]∥Si[110] and Pd2Si[001]∥Si[001]. The formation of strained epitaxial Pd2Si layers was found in Pd/Ti/Si systems. The improvement in the thermal stability of Pd2Si and the formation of epitaxial or highly oriented Pd2Si in Pd/Ti/Si systems were observed with and without B-doping.