Urban energy simulation can provide valuable information to urban planning, urban energy management, and urban emission reduction. Therefore, urban energy simulation has become an active research discipline. Various urban energy simulation methods and techniques have been developed and applied to cities on different scales. A review is conducted to categorize these methods and techniques and to analyze their pros and cons. Several representative methods and techniques are compared for their data inputs, suitable scales, accuracy, and computing speeds. Hangzhou South Railway Station area, which contains 522 buildings, is used as the case to evaluate the effectiveness and challenges of different urban energy simulation methods.