Transition-metal catalyzed decomposition of aliphatic diazo compounds — New results and applications in organic synthesis

[1]  H. Bock,et al.  Dimethylcarbene dimerisation on a raney nickel surface , 1986 .

[2]  S. Chu,et al.  Useful chemistry of 3-(1-methylethylidene)-4-acetoxy-2-azetidinones: a formal synthesis of (.+-.)-asparenomycin C , 1985 .

[3]  M. E. Alonso,et al.  PARTICIPATION OF CHARGED SPECIES IN THE THERMOCATALYTIC ADDITION OF DIAZO CARBONYL COMPOUNDS TO ELECTRON-RICH OLEFINS. ADDITION-REARRANGEMENT OF DIMETHYL DIAZOMALONATE TO 2-METHOXY-3,4-DIHYDRO-2H-PYRANS , 1985 .

[4]  G. Maas,et al.  Carbene, 30. Metallkatalysierte Zersetzung von 4‐Diazomethyl‐4H‐pyranen – ein neuer Zugang in das Oxepin‐System , 1985 .

[5]  Y. Paik,et al.  Protected ester, nitrile, carbinol and carbinyl amine cyclopropanone hydrates , 1985 .

[6]  M. Mckervey,et al.  Alkylation of benzene with α-diazoketones via cycloheptatrienyl intermediates , 1985 .

[7]  T. Ibata,et al.  Synthesis and molecular structure of the 2:1-cycloadduct of 1-methoxy-2-benzopyrylium-4-olate with acenaphthylene. , 1985 .

[8]  B. Ganem,et al.  Total synthesis of (.+-.)-4-amino-4-deoxychorismic acid: a key intermediate in the biosynthesis of p-aminobenzoic acid and L-p-aminophenylalanine , 1985 .

[9]  Abimael D Rodríguez,et al.  Betweenanenes with vinylic heteroatoms. Route to sulfur analogues via [2,3]-sigmatropic rearrangement , 1985 .

[10]  J. Marino,et al.  NEW STRATEGY FOR (3 + 2) ANNULATION: APPLICATIONS TO THE SYNTHESIS OF FUNCTIONALIZED DI- AND TRIQUINANES , 1985 .

[11]  K. Raman,et al.  ENANTIOSELECTIVE RING CONSTRUCTION: SYNTHESIS OF (+)-α-CUPARENONE , 1985 .

[12]  H. Wolf,et al.  Gasphasen‐Reaktionen Organischer Verbindungen an Raney‐Nickel , 1985 .

[13]  M. Doyle,et al.  Synthesis and catalytic reactions of chiral N-(diazoacetyl)oxazolidones , 1985 .

[14]  A. Shusterman,et al.  Generation and spectroscopic observation of a tungsten-carbene-alkene intermediate in cyclopropane formation , 1985 .

[15]  O. Prakash,et al.  Capture of electron-deficient species with aryl halides. New syntheses of hypervalent iodonium ylides , 1985 .

[16]  A. Sekiguchi,et al.  Silabenzene and silafulvene by ring contraction and expansion of cyclic silylcarbenes , 1985 .

[17]  K. Miyashita,et al.  A Modified Procedure for the Synthesis of Spirodienones from Phenolic α-Diazoketones , 1985 .

[18]  Davidr . Evans,et al.  The asymmetric synthesis of β-lactam antibiotics -II. The first enantioselective synthesis of the carbacephalosporin nucleus. , 1985 .

[19]  M. Graziano,et al.  Reaction of ketenes. Part 18. Catalysed reactions between α-diazocarbonyl compounds and ketene acetals , 1985 .

[20]  C. Pearson,et al.  Synthesis of aza-β-lactams by rhodium carbenoid mediated cyclisation , 1985 .

[21]  T. Honda,et al.  Synthesis of an aromatic sesquiterpene, (±)-cuparene,via construction of a quaternary carbon centre by an intramolecular carbenoid displacement reaction , 1985 .

[22]  B. Christensen,et al.  Synthetic carbapenem antibiotics III. 1-Methyl thienamycin , 1985 .

[23]  J. Griffin,et al.  Procatalysts for carbenoid transformations , 1985 .

[24]  H. Fischer,et al.  Regiospecific insertion of benzylidene ligands into the α-C–H bond of ethers , 1985 .

[25]  S. Pekerar,et al.  On the question of free radical intermediacy in cycloaddition reactions of diazocarbonyl compounds to olefins under copper(II) chelate catalysis , 1985 .

[26]  T. Hudlický,et al.  Intramolecular Simmons-Smith reaction and other synthetic alternatives to cyclopropanation of dienic diazo ketones. Parallel decomposition pathways of a sterically congested diazo ketone and its vinylcyclopropane under thermal, photolytic, acid-catalyzed, and radical-release conditions , 1985 .

[27]  Raymond Schappert,et al.  Halogenation and rearrangement reactions of substituted tricyclo[2.1.0.02,5]pentan-3-ones , 1985 .

[28]  D. Taber,et al.  Diastereoselection in rhodium-mediated intramolecular C-H insertion: preparation of a trans-3,4 dialkyl cyclopentane , 1985 .

[29]  M. Hashimoto,et al.  Synthetic studies on carbapenem antibiotics from penicillins. III. Stereoselective radical reduction of a chiral 3-isocyanoazetidinone: a total synthesis of optically active carpetimycins2 , 1985 .

[30]  W. Kirmse,et al.  Oxygen ylides. II: Photochemical and rhodium-catalyzed reactions of diazomethane with (S)-2-methyloxetane , 1985 .

[31]  M. Yamashita,et al.  Total synthesis of (±)-dicranenones, novel cyclopentenonyl fatty acids , 1985 .

[32]  B. Natalini,et al.  Homolytic Substitution and Carbenoidic Reactions in the Preparation of Benzimidazole Derivatives of Pharmaceutical Interest: Synthesis and Properties of (2‐Cycloalkyl‐1‐benzimidazolyl)‐N,N‐diethylacetamides , 1985, Archiv der Pharmazie.

[33]  A. Rheingold,et al.  On the stereochemical course of cuprate-mediated homoconjugate addition to an activated cyclopropane , 1985 .

[34]  W. Nagata,et al.  An alternative synthesis of the 1-oxacephem skeleton , 1985 .

[35]  W. J. Lough,et al.  Asymmetric induction in cyclopropanation with homogeneous and immobilized chiral metal β-diketonate catalysts , 1984 .

[36]  M. Doyle,et al.  Olefin coordination with rhodium(II) trifluoroacetate , 1984 .

[37]  L. d’Haenens,et al.  An Efficient Preparation and the Intramolecular Cyclopropanation of a-Diazo-3-Ketophosphonates and a-Diazophosphonoacetates , 1984 .

[38]  H. Heydt,et al.  Untersuchungen an Diazoverbindungen und Aziden, L1). 7-Brom-5-(diazomethyl)-5H-benzocycloheptatriene – Synthese durch elektrophile Diazoalkansubstitution und Umwandlung in 8-Brombenzocyclooctatetraene , 1984 .

[39]  J. Baldwin,et al.  Absolute configurations, maximum rotations, and kinetics of thermal racemization of the 1-phenyl-2-deuteriocyclopropanes , 1984 .

[40]  H. Brunner,et al.  Enantioselektive Cyclopropanierung von 1,1-Diphenylethylen und Diazoessigester mit Kupfer-Katalysatoren , 1984 .

[41]  S. Uyeo,et al.  Total synthesis of dl-asparenomycins A, B and C, novel carbapenem antibiotics , 1984 .

[42]  E. Y. Chen Total synthesis of (.+-.)-cycloeudesmol and (.+-.)-epicycloeudesmol , 1984 .

[43]  K. H. Dötz Carbenkomplexe in der Organischen Synthese , 1984 .

[44]  D. A. Laidler,et al.  Asymmetric synthesis of cyclopropane carboxylates, catalysis of diazoacetate reactions by copper(II) Schiff base complexes derived from α-amino acids , 1984 .

[45]  Peter Murray-Rust,et al.  An expeditious synthesis of 4-alkoxycarbonyl-5-hydroxy-1,2,3-triazoles: the crystal and molecular structure of the 2-thienylammonium salt of 5-hydroxy-4-methoxycarbonyl-1-(2-thienyl)-1,2,3-triazole , 1984 .

[46]  H. Kurihara,et al.  Conversion of 1,3-Dicarbonyls to 1,4-Dicarbonyls , 1984 .

[47]  S. Branca,et al.  Vinylogous Wolff rearrangement. 5. Mechanistic studies , 1984 .

[48]  S. Branca,et al.  Vinylogous Wolff rearrangement. 4. General reaction of .beta.,.gamma.-unsaturated .alpha.'-diazo ketones , 1984 .

[49]  M. Regitz,et al.  Untersuchungen an Diazoverbindungen und Aziden. XLIV: 4-Diazomethyl-4H-pyrane durch elektrophile Diazoalkansubstitution , 1984 .

[50]  G. S. Singh,et al.  Reactions of 2-Diazo-1,2-Diphenylethanone and Diphenyldiazomethane with Ketohydrazones , 1984 .

[51]  A. Padwa 1,3-Dipolar Cycloaddition Chemistry , 1984 .

[52]  B. Ganem,et al.  Epoxides as alkene protecting groups. A mild and efficient deoxygenation , 1984 .

[53]  P. March,et al.  Functicnalization of 4-Hydroxy-6-Methyl-2-Pyrone at C-5 Through [2,3] Sigmatropic Rearrangements of Allylic Sulphonium Ylides , 1984 .

[54]  M. Doyle,et al.  Catalytic role of copper triflate in Lewis acid promoted reactions of diazo compounds , 1984 .

[55]  T. Hudlický,et al.  TWO TOPOLOGICALLY DISTINCT TOTAL SYNTHESES OF (.+-.)-SARKOMYCIN , 1984 .

[56]  D. Cane,et al.  Synthesis of (dl)-pentalenolactones E and F , 1984 .

[57]  H. Reissig,et al.  Synthese von 2-siloxysubstituierten Cyclopropancarbonsäure-methylestern , 1984 .

[58]  T. Patapoff,et al.  Stereochemical kinetics of the thermal stereomutations interconverting achiral isomers of 1-phenyl-1,2,3-trideuteriocyclopropane , 1984 .

[59]  D. J. Milner Reaction or ethyl diazoacetate with halogenoethylenes in the presence of rhodium(II) pivalate , 1984 .

[60]  A. Saba A New Synthesis of 3-Oxo-3,4-dihydro-2H-1-benzopyrans, 3-Oxo-3,4-dihydro-2H-naphtho[1,2-b]pyran, and 2-Oxo-2,3-dihydro-1H-naphtho[2,1-b]pyran: The Use of Bis[hexafluoroaceto-aceton , 1984 .

[61]  M. Mckervey,et al.  Efficient synthesis of bicyclo[5.3.0]decatrienones and of 2-tetralones via rhodium(II) acetate-catalysed cyclisation of α-diazoketones derived from 3-arylpropionic acids , 1984 .

[62]  J. Griffin,et al.  Stereoselectivity of catalytic cyclopropanation reactions. Catalyst dependence in reactions of ethyl diazoacetate with alkenes , 1984 .

[63]  M. Curini,et al.  Preparation of 1‐(Aroylalkyl)‐1H‐imidazole and ‐Benzimidazole Derivatives of Pharmaceutical Interest. A New Synthetic Procedure , 1984 .

[64]  Y. Leblanc,et al.  Synthesis of 5S,12S - diHETE (LTBx) , 1984 .

[65]  H. Davies,et al.  Approaches to the synthesis of aza analogs of the .beta.-lactam antibiotics: some anomalous rhodium(II)-catalyzed carbene insertion reactions , 1984 .

[66]  M. Doyle,et al.  Influence of olefin coordination on cyclopropanation selectivity , 1984 .

[67]  M. Hashimoto,et al.  Synthetic studies on carbapenem antibiotics from penicillins. II: Regio- and stereoselective aldol reaction of a chiral azetidinone: a synthesis of optically active 6-epicarpetimycins , 1984 .

[68]  N. Moss,et al.  Thermal rearrangement of divinylcyclopropane systems. Preparation of functionalized, stereochemically defined bicyclic and tricyclic products containing the bicyclo[3.2.1]octane skeleton , 1984 .

[69]  H. Pajouhesh,et al.  The addition of chlorosulphonyl isocyanate to an allenyl acetate. The preparation of a versatile intermediate for antibiotic synthesis , 1984 .

[70]  J. Griffin,et al.  Rearrangements of Ylides Generated from Reactions of Diazo Compounds with Allyl Acetals and Thioketals by Catalytic Methods. Heteroatom Acceleration of the [2,3]-Sigmatropic Rearrangement , 1984 .

[71]  A. Chakraborti,et al.  Regioselectivity in the intramolecular carbon–hydrogen insertion in metal-catalysed decomposition of some cis-1-methyl-3-arylcyclohexyl diazomethyl ketones. A highly efficient homogeneous nickel catalyst for carbenoid insertion , 1984 .

[72]  W. Hartwig,et al.  A convergent scheme for the stereoselective synthesis of 3'-nor-1-oxacephems , 1984 .

[73]  W. Peters,et al.  Neue Synthese von 6-Formyl-trans- 5.6-methanohexansäuremethylester / Novel Synthesis of Methyl 6 -Formyl-trans- 5.6-methanohexanoate , 1984 .

[74]  G. Maas,et al.  Untersuchungen an diazoverbindungen und aziden—Li Thermolyse von 7-chlor-5-(diazomethyl)benzocyclo)-heptatrienen zu 8-chlor-benzocyclooctatetraenen , 1984 .

[75]  J. Rokach,et al.  Synthesis of ±8- and 9-HETES , 1984 .

[76]  C. Sha,et al.  Novel 1,2-dihydroisoquinoline synthesis via intramolecular 1,3-dipolar alkylazide-olefin cycloaddition , 1984 .

[77]  E. V. D. Eycken,et al.  Photoinduced Wolff Rearrangement of α-Diazo-β-Ketophosphonates : A Novel Entry into Substituted Phosphonoacetates , 1984 .

[78]  S. Nordenson,et al.  Stevens rearrangement of a potentially aromatic thiophenium ylide: formation of 10-methoxycarbonyl-10H-benzo[3,4]cyclopenta[1,2-b]thiopyran-9-one , 1984 .

[79]  J. Griffin,et al.  Correlations between catalytic reactions of diazo compounds and stoichiometric reactions of transition-metal carbenes with alkenes. Mechanism of the cyclopropanation reaction , 1984 .

[80]  H. V. Bekkum,et al.  The decomposition of ethyl diazoacetate over zeolite NaCuX , 1984 .

[81]  W. Johncock,et al.  Intramolecular Carbenoid Reactions of Pyrrole Derivatives Efficient Syntheses of Pyrrolizinone and Dihydroindolizinone , 1983 .

[82]  H. Reisenauer,et al.  Tricyclo[2.1.0.02,5]pentan‐3‐one , 1983 .

[83]  H. Reißig,et al.  Deprotonierung und diastereoselektive Alkylierung von Cyclopropancarbonsäure‐methylestern , 1983 .

[84]  T. Hudlický,et al.  General method of synthesis of cyclopentanoid terpenic acids. Stereocontrolled total syntheses of (.+-.)-isocomenic acid and (.+-.)-epiisocomenic acid , 1983 .

[85]  M. Ohno,et al.  Stereocontrolled synthesis of an ene-carbapenem antibiotic (-)-asparenomycin C , 1983 .

[86]  W. Herrmann,et al.  Übergangsmetall-Methylen-Komplexe, LI [1]. Carbocyclische Carbene, Carben-Brücken, kleine Kohlenwasserstoff-Liganden und Metallacyclen: Beispiele einer umfassenden Synthesekonzeption / Transition Metal Methylene Complexes, LI [1]. Carbocyclic Carbenes, Carbene Bridges, Small Hydrocarbon Ligands, and , 1983 .

[87]  J. B. Lambert,et al.  Palladium(II) Acetate, an Efficient Catalyst for Cyclopropanation Reactions with Ethyl Diazoacetate , 1983 .

[88]  T. Kulp,et al.  Intramolecular cyclopentene annulation. III: Synthesis and carbon-13 nuclear magnetic resonance spectroscopy of bicyclic cyclopentene lactones as potential perhydroazulene and/or monoterpene synthons , 1983 .

[89]  T. Ibata,et al.  Formation and reaction of carbonyl ylides. 1,3-Dipolar cycloaddition of 1-methoxy-2-benzopyrylium-4-olate to carbonyl compounds. , 1983 .

[90]  K. Raman,et al.  Enantioselective carbocyclization: a facile route to chiral cyclopentanes , 1983 .

[91]  E. Wenkert,et al.  A dihydro-.alpha.-furoic ester synthesis by the catalyzed reactions of ethyl diazopyruvate with enol ethers , 1983 .

[92]  C. Damas,et al.  Nuclear analogs of β-lactam antibiotics. XVIII: A short synthesis of 2-alkylthiocarbapen-2-em-3-carboxylate , 1983 .

[93]  P. Policastro,et al.  Improved synthesis of racemic chorismic acid. Claisen rearrangement of 4-epi-chorismic acid and dimethyl 4-epi-chorismate , 1983 .

[94]  J. Nokami,et al.  A new total synthesis of dl-sirenin , 1983 .

[95]  M. Chiba,et al.  A New Efficient Homologation Reaction of Ketones via their Lithiodiazoacetate Adducts , 1983 .

[96]  W. Herrmann Wege und irrwege zu metallorganischen methylen-brücken , 1983 .

[97]  D. Mckinnon The reaction of 1,6,6aλ4-trithiapentalenes with carbene and nitrene reagents , 1983 .

[98]  H. Fliri,et al.  Synthesis of carbapenem-3-phosphonic acid derivatives , 1983 .

[99]  R. Neidlein,et al.  Versuche zur Herstellung eines «Bis(triasterans)» und Synthese des heterocyclischen (Tricyclo[4.4.1.01,6]undeca‐3,8‐dien‐11,11‐dimethyl)sulfits , 1983 .

[100]  E. Wenkert,et al.  Short syntheses of furan and catechol derivatives. A synthesis of hydrourushiol , 1983 .

[101]  E. Galeazzi,et al.  Synthesis of ethyl 1,2-dihydro-3H-pyrrolo[1,2-a]pyrrole-1-carboxylate by an intramolecular carbenoid reaction , 1983 .

[102]  T. Honda,et al.  STUDIES ON THE SYNTHESIS OF CARBAPENEM ANTIBIOTICS. STEREOSELECTIVE SYNTHESIS OF A POTENTIAL INTERMEDIATE FOR 6-AMIDOCARBAPENEM ANTIBIOTICS , 1983 .

[103]  H. Kunz,et al.  Isomerisierung von 2‐Alkoxycyclopropancarbonsäuren – Eine effektive Synthese von 4‐Oxocarbonsäuren , 1983 .

[104]  J. Brennan,et al.  An efficient synthesis of (±) 7-oxo-3-thia-1-azabicyclo[3.2.0]heptane-2-carboxylate-3,3-dioxide , 1983 .

[105]  H. Davies,et al.  Rhodium(II) acetate-catalyzed reaction of ethyl 2-diazo-3-oxopent-4-enoates: Simple routes to 4-aryl-2-hydroxy-1-naphthoates and β,β-unsaturated esters. The dianion of ethyl 4-(diethylphosphono)acetoacetate as a propionate homoenolate equivalent , 1983 .

[106]  G. Mlostoń,et al.  Aziridines; III1. 1,2,3-Trisubstituted Aziridines by the Reaction of Phenyldiazomethane with Imines in the Presence of Zinc Iodide , 1983 .

[107]  T. Honda,et al.  Ring expansion reactions of penicillin derivatives by rhodium-catalyzed decomposition of diazoketones ??? stereoselective syntheses of eight-membered oxa-β-lactams , 1983 .

[108]  M. Regitz,et al.  Metallkatalysierte zersetzung von 4-diazomethyl-4H-pyranen - ein neuer zugang in das oxepinsystem , 1983 .

[109]  I. Gosney,et al.  Ring transformation of 2-substituted isothiazol-3(2H)-ones to 3,4-dihydro-1,3-thiazin-4(2H)-ones by a novel carbene addition–ring expansion sequence , 1983 .

[110]  A. Demonceau,et al.  Transition metal catalyzed reactions of diazoesters , 1983 .

[111]  J. Rokach,et al.  A new general method for the synthesis of lipoxygenase products: preparation of ±5-HETE , 1983 .

[112]  M. Doyle,et al.  Rearrangements of oxocyclopropanecarboxylate esters to vinyl ethers. Disparate behavior of transition-metal catalysts , 1983 .

[113]  B. Ganem,et al.  Shikimate-derived metabolites. 11. A total synthesis of (.+-.)-chorismic acid , 1982 .

[114]  Kagetoshi Yamamoto,et al.  SYNTHESIS AND PROPERTIES OF 4- AND 4,5-SUBSTITUTED 2,7-DI-tert-BUTYLTHIEPINS , 1982 .

[115]  A. Daniewski,et al.  New total synthesis of equilenin and estrone , 1982 .

[116]  D. Taber,et al.  General route to highly functionalized cyclopentane derivatives by intramolecular C-H insertion , 1982 .

[117]  M. Doyle,et al.  Regioselectivity in catalytic cyclopropanation reactions , 1982 .

[118]  B. Shankar,et al.  Rhodium ion catalyzed decomposition of aryldiazoalkanes , 1982 .

[119]  B. Shankar,et al.  Chemistry of diazoacenaphthenones and diazoacenaphthenes , 1982 .

[120]  Raymond Schappert,et al.  Synthesis of 1,5-disubstituted tricyclo[2.1.0.02,5]pentanes. The crystal and molecular structures of 1,5-bis(acetoxymethyl)tricyclo[2.1.0.02,5]pentan-3-one , 1982 .

[121]  M. Doyle,et al.  Cyclopropanation of .alpha.,.beta.-unsaturated carbonyl compounds and nitriles with diazo compounds. The nature of the involvement of transition-metal promoters , 1982 .

[122]  M. E. Alonso,et al.  Studies on the origin of dihydrofurans from .alpha.-diazocarbonyl compounds. Concerted 1,3-dipolar cycloaddition vs. nonsynchronous coupling in the copper chelate catalyzed reactions of .alpha.-diazodicarbonyl compounds with electron-rich olefins , 1982 .

[123]  W. A. Donaldson,et al.  Mechanism of formation of (.eta.3-oxocyclobutenyl)cobalt compounds from [Co(CO)4]- and cyclopropenium cations , 1982 .

[124]  R. Huisgen,et al.  Carbonyl ylides from aldehydes and carbenes , 1982 .

[125]  R. Huisgen,et al.  Three-component reactions of diazomalonic ester, benzaldehyde, and electrophilic olefins , 1982 .

[126]  P. Stütz,et al.  A new method of carbon extension at C-4 of azetidinones , 1982 .

[127]  M. Curini,et al.  Cyclopentanone synthesis by intramolecular carbon-hydrogen insertion of diazo ketones. A diterpene-to-steroid skeleton conversion , 1982 .

[128]  W. Kirmse,et al.  Desaminierungsreaktionen, 37. Zerfall von Bicyclo[6.1.0]nonan‐ und Bicyclo[6.1.0]non‐2‐en‐9‐diazonium‐Ionen , 1982 .

[129]  B. Maryanoff Reaction of dimethyl diazomalonate and ethyl 2-diazoacetoacetate with N-methylpyrrole , 1982 .

[130]  T. Aratani,et al.  Asymmetric synthesis of permethric acid. stereochemistry of chiral copper carbenoid reaction , 1982 .

[131]  F. Bohlmann,et al.  Natürlich vorkommende Terpen‐Derivate, 446. Synthese von Precarabron , 1982 .

[132]  V. Roberts,et al.  Synthesis of 3- and 4-(carbethoxy)-2,4,6-cycloheptatrien-1-one , 1982 .

[133]  T. Hudlický,et al.  Terpenic acids by cyclopentene annulation of exocyclic dienes. Synthesis of the triquinane portion of retigeranic acid , 1982 .

[134]  B. Haymore,et al.  Diazoalkane complexes of molybdenum and tungsten , 1982 .

[135]  J. Baldwin,et al.  COMPLETE KINETIC ANALYSIS OF THE THERMAL STEREOMUTATIONS OF (+)-(1S,2S,3R)-R-1-CYANO-T-2-METHYL-1,2,T-3-TRIDEUTERIOCYCLOPROPANE , 1982 .

[136]  M. Curtis,et al.  Reactivity of .mu.-alkylidene complexes: bridge-to-terminal alkylidene ligand conversion in a dimolybdenum complex , 1982 .

[137]  W. Herrmann The methylene bridge: a challenge to synthetic, mechanistic and structural organometallic chemistry , 1982 .

[138]  Heiner Jendralla,et al.  Carbenoide Additionen an 3,6‐Dihydro‐4‐methyl‐2H‐pyran Bildung gespannter Oxatricycloheptane bei der Lithiierung des Dibromcarben‐Addukts , 1982 .

[139]  K. G. Taylor Carbenes and carbenoids with neighboring heteroatoms , 1982 .

[140]  J. Heck,et al.  Nuclear analogs of β-lactam antibiotics II. The synthesis of 6α-(1-hydroxylethyl)-cyclonocardicins , 1982 .

[141]  P. Montevecchi,et al.  Ylide formation and rearrangement in the thermal reaction of 6H-dibenzo[b,d]thiopyran and its 6-phenyl derivative with diazoalkanes , 1982 .

[142]  D. Lloyd,et al.  The effects of different copper (and some other) catalysts on the conversion of triphenyl- and tetraphenyl- diazocyclopentadienes and of some phenyliodonium αα′-dicarbonylylides into arsonium and other ylides , 1982 .

[143]  N. J. Morrison Synthesis of 4- and 5-(1,3-dimethylbut-2-enylthio)-2,6-dimethylocta-2,6-diene, models for sulphur crosslinks in natural rubber , 1982 .

[144]  H. Callot,et al.  Sterically crowded cyclopropanation catalysts. Syn-selectivity using rhodium(III)porphyrins , 1982 .

[145]  R. Carrié,et al.  Syntheses asymetriques a l'aide d'oxazolidines chirales derivees de l'ephedrine. Preparation de formyl cyclopropanes chiraux. , 1982 .

[146]  H. Callot,et al.  Homologation of n-alkanes using diazoesters and rhodium(III)porphyrins. Enhanced attack on primary CH bonds. , 1982 .

[147]  A. Demonceau,et al.  Transition-metal-catalyzed reaction of diazocompounds, efficient synthesis of functionalized ethers by carbene insertion into the hydroxylic bond of alcohols , 1982 .

[148]  M. Mckervey,et al.  Regiospecific synthesis of α-(phenylthio)ketones via rhodium(II) acetate catalysed addition of thiophenol to α-diazoketones , 1982 .

[149]  David J. Williams,et al.  Tricyclic products from the reaction between penicillin derived thiazoloazetidinones and ethyl diazoacetate. X-Ray structure of methyl 2-[(1R, 3S, 4R, 5S, 6S, 8R)-3-benzyl-4,5-bismethoxycarbonyl-6-ethoxycarbonyl-9-oxo-7,10-diaza-2-thiatricyclo[6.2.0.03,7]decan-10-yl]-3-methylbut-2-enoate , 1982 .

[150]  David J. Williams,et al.  Preparation of 6α-monosubstituted and 6,6-disubstituted penicillanates from 6-diazopenicillanates: reactions of 6-diazopenicillanates with alcohols, thiols, phenylseleninyl compounds, and allylic sulphides, and their analogues , 1982 .

[151]  R. Kerr,et al.  Homologation of selenoesters to (phenylseleno)- or (methylseleno)methyl ketones with diazomethane , 1982 .

[152]  M. Kapon,et al.  Intramolecular cycloaddition of carbonyl ylides generated from α-diazo ketones , 1982 .

[153]  W. Herrmann The Methylene Bridge , 1982 .

[154]  V. Bagheri,et al.  Highly effective catalytic methods for ylide generation from diazo compounds. Mechanism of the rhodium- and copper-catalyzed reactions with allylic compounds , 1982 .

[155]  S. Matlin,et al.  New spiro derivatives of penicillin , 1982 .

[156]  M. Curini,et al.  An improved two-step route for the preparation of β-diketones from aldehydes and its application to the synthesis of β-damascone , 1982 .

[157]  M. Suda Cyclopropanation of Terminal Olefins Using Diazomethane/Palladium(II) Acetate , 1981 .

[158]  S. Danishefsky,et al.  Approaches to the synthesis of the mitomycins. A route to the mitosanes involving activated cyclopropanes , 1981 .

[159]  T. Honda,et al.  A short and stereoselective synthesis of the carbapenem antibiotic PS-5 , 1981 .

[160]  M. Curini,et al.  Reactions of Alkoxycarbonylcarbenoids with Imidazole; An Improved Preparation of Ethyl Imidazole-1-ylacetate and the First Synthesis of Diethyl Imidazole-1-ylmalonate , 1981 .

[161]  K. Saigo,et al.  A Convenient Synthesis of 3-(Diethoxymethyl)alkanals , 1981 .

[162]  M. Jautelat,et al.  Synthesen von Pyrethroidsäuren , 1981 .

[163]  M. Doyle,et al.  Transition-metal-catalyzed rearrangements of oxocyclopropanes to vinyl ethers. Activation by vicinal carboalkoxy substituents , 1981 .

[164]  M. Doyle,et al.  Correlation between catalytic cyclopropanation and ylide generation , 1981 .

[165]  S. B. Singh,et al.  Effect of bis(acetylacetonato) copper(II) catalyst on the reaction of benzoylphenyldiazomethane with primary amines. A novel example of insertion of benzoylphenylcarbene into N—H bonds of amines , 1981 .

[166]  M. Doyle,et al.  Exceptionally effective catalysis of cyclopropanation reactions by the hexarhodium carbonyl cluster , 1981 .

[167]  H. Reißig,et al.  Alkylierung von Donor‐Acceptor‐substituierten Cyclopropanen: ein flexibler Weg zu 4‐Oxo‐carbonsäureestern , 1981 .

[168]  T. Suzuki,et al.  Nickel-catalyzed reactions involving strained bonds. 17. Nickel(0)-catalyzed reactions of bicyclo[1.1.0]butanes. Geminal two-bond cleavage reaction and the stereospecific olefin trapping of the carbenoid intermediate , 1981 .

[169]  C. Mukai,et al.  Synthesis, stereochemistry, and rearrangement of thioxanthen-10-io-(bismethoxycarbonyl)methanides and their 9-alkyl derivatives , 1981 .

[170]  P. G. Mattingly,et al.  Synthesis of 2-azetidinones from serinehydroxamates: approaches to the synthesis of 3-aminonocardicinic acid , 1981 .

[171]  D. Holland,et al.  Catalytic asymmetric synthesis of cyclopropane carboxylates: ligand—reagent interactions in diazoacetate reactions catalysed by copper (II) species bearing sugar—Schiff base ligands , 1981 .

[172]  H. Hogeveen,et al.  SYNTHESIS AND CHEMISTRY OF A BICYCLOBUTANE-BRIDGED α-DIAZOKETONE , 1981 .

[173]  M. E. Alonso,et al.  ALUMINUM OXIDE ASSISTED STEREOSELECTIVE REARRANGEMENT OF A CYCLOPROPYL KETONE TO 4,5‐DIHYDROFURAN , 1981 .

[174]  Robert C. Brady,et al.  Mechanism of the Fischer-Tropsch reaction. The chain propagation step , 1981 .

[175]  Alfred F. Noels,et al.  Transition-metal-catalyzed reactions of diazo compounds. 2. Addition to aromatic molecules: catalysis of Buchner's synthesis of cycloheptatrienes , 1981 .

[176]  E. Wenkert,et al.  Methyl β-(2-Methyl-5-Oxocyclopentenyl-) Propionate and Ethyl 3-Methyl-6-Oxohepta-2, 4-Dienoate , 1981 .

[177]  K. Nakasuji,et al.  Recent advances in thiepin chemistry , 1981 .

[178]  J. Heck,et al.  Nuclear analogs of β-lactam antibiotics I. The synthesis of 6β-amidocyclonocardicins , 1981 .

[179]  B. Ganem,et al.  Catalyzed insertion reactions of substituted α-diazoesters. A new synthesis of cis-enoates , 1981 .

[180]  M. E. Alonso,et al.  A new convenient synthesis of trisubstituted 1,3-dioxole-4-carboxylates from methyl 2-diazo-3-oxobutyrate and aldehydes , 1981 .

[181]  E. Hunt,et al.  Synthesis of ethyl 3-methyl-7-oxo-4-oxo-4-oxa-1-azabicyclo[3.2.0]hept-2-ene-2-carboxylate and the reaction of 4-acetoxyazetidin-2-one with ethyl α-diazoacetoacetate , 1981 .

[182]  Jimmie L. Williams,et al.  Dichlorobis(organonitrile)palladium(II) catalysis of cis- to trans- isomerization of ethylchrysanthemate and chrysanthemic acid , 1981 .

[183]  W. Herrmann,et al.  Komplexchemie reaktiver organischer Verbindungen, XXXV1) Metallkoordinierte Diazoalkane: Synthese und Molekülstruktur von Dicarbonyl(η5‐cyclopentadienyl)(diazomalonsäure‐dimethylester‐N)mangan , 1981 .

[184]  T. Honda,et al.  A carbon–carbon bond formation reaction at the C-4 position of a β-lactam , 1981 .

[185]  M. Mckervey,et al.  Synthesis of macrocyclic oxo-crown ethers from αω-bis-diazo-ketones and polyethylene glycols , 1981 .

[186]  A. Demonceau,et al.  Transition-metal-catalysed reactions of diazoesters. Insertion into C–H bonds of paraffins by carbenoids , 1981 .

[187]  D. Holland,et al.  SYNTHESIS OF NOVEL COPPER(II) COMPLEXES OF OPTICALLY ACTIVE SCHIFF BASES , 1981 .

[188]  M. Doyle,et al.  Efficient Alternative Catalysts and Methods for the Synthesis of Cyclopropanes from Olefins and Diazo Compounds , 1981 .

[189]  H. D. Showalter,et al.  Total syntheses of eburnamonine, quebrachamine, vincadine and epivincadine , 1981 .

[190]  W. Kingsbury,et al.  A facile synthesis of benzyl 3,7-dioxo-1-azabicyclo[3.2.0]Heptane-2-carboxylate. A potential precursor of thienamycin and clavulanic acid analogs , 1981 .

[191]  R. K. Boeckman,et al.  Cyclic vinyl ether carbanions—II : Preparation and applications to the synthesis of carbonyl compounds , 1981 .

[192]  T. Hudlický,et al.  Cyclopentene annulation via intramolecular addition of diazoketones to 1,3-dienes. Applications to the synthesis of cyclopentanoid terpenes , 1980 .

[193]  M. E. Alonso,et al.  Catalytic decomposition of ethyl diazopyruvate in the presence of electron-deficient and hydrocarbon alkenes. Cyclopropanation vs. carbon-hydrogen insertion , 1980 .

[194]  L. T. Scott,et al.  A short new azulene synthesis , 1980 .

[195]  R. Brady,et al.  Reactions of diazomethane on transition-metal surfaces and their relationship to the mechanism of the Fischer-Tropsch reaction , 1980 .

[196]  B. Christensen,et al.  A stereocontrolled synthesis of (+)-thienamycin , 1980 .

[197]  T. Hudlický,et al.  Total synthesis of (.+-.)-hirsutene , 1980 .

[198]  R. Knorr Empirical Substituent Parameters for E/Z Equilibrium Constants , 1980 .

[199]  M. E. Alonso,et al.  THE SYNTHESES OF ETHOXYCARBONYL‐1,3‐DIOXOLES AND OXAZOLES FROM THE COPPER‐CATALYZED THERMOLYSIS OF ETHYL DIAZOPYRUVATE IN THE PRESENCE OF KETONES, ALDEHYDES AND NITRILES , 1980 .

[200]  N. S. Vyazankin,et al.  Organometallic Derivatives of Diazoalkanes , 1980 .

[201]  M. Doyle,et al.  Molybdenum hexacarbonyl catalyzed cyclopropanation of .alpha.,.beta.-unsaturated esters and nitriles and diazocarbonyl compounds , 1980 .

[202]  B. Christensen,et al.  A novel synthesis of the carbapen-2-em ring system , 1980 .

[203]  C. Foote,et al.  Olefin epoxidation by an intermediate formed in the metal ion catalyzed oxygenation of azibenzil , 1980 .

[204]  A. Anciaux,et al.  Transition-Metal-Catalyzed Reactions of Diazo Compounds. 1. Cyclopropanation of Double Bonds , 1980 .

[205]  Ralf‐Peter Hinze,et al.  Beiträge zur Kenntnis des chromophoren Systems der Corrine, VII. Notiz über die Reaktion von Diazoessigsäure‐methylester mit Lactamen; eine Modellreaktion zur Cyclisierung von 5,6‐Dioxo‐monosecocorrinen , 1980 .

[206]  E. Abel,et al.  The preparation of perhalogenopentafulvalenes utilising a palladium catalyst , 1980 .

[207]  J. Anselme,et al.  Remarkably stereoselective formation of cis-stilbenes from the lithium bromide-catalysed decomposition of aryldiazomethanes , 1980 .

[208]  E. Wenkert Oxycyclopropanes in organochemical synthesis , 1980 .

[209]  H. Callot,et al.  Cyclopropanation using rhodium (III) porphyrins : Large cis vs trans selectivity , 1980 .

[210]  T. Oshima,et al.  Stereochemistry of the copper perchlorate or copper bromide-catalyzed decomposition of aryldiazomethanes to stilbenes , 1980 .

[211]  A. Porter,et al.  Facile entry into the 7-oxo-4-oxo-1-azabicyclo[3.2.0]hept-2-ene ring system , 1980 .

[212]  B. Christensen,et al.  Total synthesis of (−) homothienamycin , 1980 .

[213]  R. Ponsford Copper (II) catalysed decomposition of penicillin - derived diazoketones: formation of a novel fused β-lactam , 1980 .

[214]  B. Zwanenburg,et al.  Cyclopropanation reactions with α, β-epoxy diazomethyl ketones and rearrangement of α, β-epoxy cyclopropyl ketones , 1980 .

[215]  K. Rehse,et al.  Neuropsychotrope Aktivität dopaminanaloger Phenylpropyl‐ und Phenylcyclopropylpiperidine , 1980 .

[216]  J. Ibers,et al.  Synthesis and characterization of some .pi.-bonded diazo complexes of nickel(0), platinum(0), and ruthenium(0): molecular structure of Ru(CO)2(N2C5Cl4)(P(C6H5)3)2.CH2Cl2 , 1980 .

[217]  S. Matlin,et al.  Metal-catalysed reactions of benzhydryl 6-diazopenicillanate with alcohols , 1980 .

[218]  B. Zwanenburg,et al.  Oxygen transfer during the copper induced reaction of α,β-epoxy diazomethyl ketones , 1980 .

[219]  H. Tomioka,et al.  The reactivity of carbenes from photolysis of diazo-compounds towards carbon–hydrogen bonds. Effects of structure, temperature, and matrix on the insertion selectivity , 1980 .

[220]  E. J. Thomas,et al.  Reactions of 6-diazopenicillanates with allylic sulphides, selenides, and bromides , 1980 .

[221]  J. Ibers,et al.  Structure of bis(triphenylphosphine)(tetrachlorodiazocyclopentadiene)chloroiridium(I) toluene solvate, IrCl(N2C5Cl4)(P(C6H5)3)2•C7H8 , 1980 .

[222]  U. Ghatak,et al.  Synthetic studies toward complex diterpenoids. Stereocontrolled total synthesis of some gibbane synthons and degradation products of gibberellins , 1979 .

[223]  R. Lawton,et al.  Ring expansion synthesis of fused trans-.alpha.methylene-.gamma.-lactones , 1979 .

[224]  B. Maryanoff Carbenoid chemistry. Reaction of pyrrole derivatives with ethyl diazoacetate , 1979 .

[225]  D. Bethell,et al.  Intermediates in the decomposition of aliphatic diazo-compounds. Part 16. Catalysis of the decomposition of diazodiphenylmethane by copper(I) bromide, iodide, and perchlorate in acetonitrile , 1979 .

[226]  S. Fairhurst,et al.  Intermediates in the decomposition of aliphatic diazo-compounds. Part 15. Radical cations in the decomposition of diazodiphenylmethane by copper(II) perchlorate and by tris(p-bromophenyl)ammoniumyl perchlorate , 1979 .

[227]  M. M. Campbell,et al.  Reactions of 6-diazopenams and 7-diazocephems: spirocyclopropyl and spiropyrazolinyl β-lactams , 1979 .

[228]  Kagetoshi Yamamoto,et al.  Synthesis of 2,7-di-tert-butyl-4-ethoxycarbonyl-5-methylthiepin. A remarkably stable and simple monocyclic thiepin , 1979 .

[229]  B. Weber,et al.  Untersuchungen an Diazoverbindungen und Aziden, XXXII. Substitutionsreaktionen am Diazokohlenstoff von Diazomethylphosphorylverbindungen , 1979 .

[230]  P. Yates,et al.  Aliphatic diazo compounds. XIII. The copper-catalyzed decomposition of 5-endo-hetero-atom-substituted 3-diazo-2-norbornanones , 1979 .

[231]  R. Gillespie,et al.  Reaction of activated arenes with 2,5-dichlorothiophenium bismethoxycarbonylmethylide , 1979 .

[232]  A. Hubert,et al.  Novel iminooxazolines from reactions of diazoacetates with carbodiimides (a revision) , 1979 .

[233]  W. Andō Photochemistry of the diazonium and diazo groups , 1979 .

[234]  S. Danishefsky Electrophilic cyclopropanes in organic synthesis , 1979 .

[235]  M. E. Alonso,et al.  Studies on the origin of allylic CH “insertion” products in additions of dimethyl diazomalonate to olefins. Thermocatalytic reaction of diazomalonate with dicyclopropyl ethylene , 1979 .

[236]  M. Curini,et al.  Catalysed insertion reactions of diphenyl diselenide with ethyl diazoacetate and dimethyl diazomalonate , 1979 .

[237]  R. Southgate,et al.  Preparation of 8-oxo-7-(1-hydroxyethyl)-3-oxa-1-azabicyclo[4.2.0]octane derivatives: intermediates for thienamycin synthesis , 1979 .

[238]  T. Hudlický,et al.  Intramolecular carbenoid addition to 1,3-dienes. Synthesis of cyclopentene annulated ring systems. , 1979 .

[239]  K. Akiyama,et al.  Syntheses and rearrangements of C11H10O ketones derived from homooctavalene - I1 copper-catalyzed decomposition of homooctavalenyldiazomethylketone☆ , 1979 .

[240]  R. Pellicciari,et al.  β-Keto esters from the rhodium(II) acetate catalysed conversion of α-diazo-β-hydroxy esters , 1979 .

[241]  R. Gillespie,et al.  The reaction of diazoalkanes with thiophen , 1979 .

[242]  M. Mckervey,et al.  Synthesis of some medium- and large-ring cycloalk-2-ene-1,4-diones by intramolecular coupling of αω-bis-diazoketones , 1979 .

[243]  K. Kondo,et al.  A new stereoselective synthesis of dl-prostaglandin F2α , 1978 .

[244]  J. Landgrebe,et al.  Asymmetric induction in the addition of chiral carbalkoxycarbenoids to styrene , 1978 .

[245]  W. Herrmann Organometall‐Synthesen mit Diazoalkanen , 1978 .

[246]  K. Nakasuji,et al.  A ROLE OF 2,7-DIISOPROPYL GROUPS IN THE STABILITY OF THIEPIN , 1978 .

[247]  A. Nakamura,et al.  Enantioselective carbenoid cyclopropanation catalyzed by chiral vic-dioximatocobalt(II) complexes prepared from natural camphor and .beta.-pinene. Mechanism and stereochemistry , 1978 .

[248]  A. Nakamura,et al.  Additions and Corrections - A Highly Enantioselective Synthesis of Cyclopropane Derivatives through Chiral Cobalt(II) Complex Catalyzed Carbenoid Reaction. General Scope and Factors Determining the Enantioselectivity. , 1978 .

[249]  A. Craveiro,et al.  Oxy cyclo propanes in organochemical synthesis total syntheses of racemic alpha cuparenone and racemic beta vetivone , 1978 .

[250]  H. Iranmanesh,et al.  Regiospecificity of enol ether formation in the catalyzed decomposition of ethyl diazoacetate in the presence of unsymmetrical ketones , 1978 .

[251]  E. Vedejs,et al.  Ring expansion by [2,3]sigmatropic shift: conversion of five-membered into eight-membered heterocycles , 1978 .

[252]  TunemotoDaiei,et al.  STEREOSELECTIVE SYNTHESIS OF 10-OXA-11-DEOXY-PROSTAGLANDIN E1 , 1978 .

[253]  A. Craveiro,et al.  Oxycyclopropanes in organochemical synthesis. Total syntheses of (.+-.)-.alpha.-cuparenone and (.+-.)-.beta.-vetivone , 1978 .

[254]  A. Nakamura,et al.  Some Aspects on the Mechanism of Palladium-complex-catalyzed Decomposition of and Cyclopropanation with Ethyl Diazoacetate , 1978 .

[255]  H. Callot,et al.  Reactions diazoalcanes et metalloporphyrines. Nouvelle synthese d'alkylcobalt(III) porphyrines☆ , 1978 .

[256]  K. N. Mehrotra,et al.  The insertion of diaryl carbenes into an imine NH bond , 1978 .

[257]  M. Elliott,et al.  Synthetic pyrethroids-a new class of insecticide. , 1978 .

[258]  A. Anciaux,et al.  Rhodium catalysed cyclopropenation of acetylenes , 1978 .

[259]  A. Nakamura Enantioselective reactions through chiral metal-carbene intermediates , 1978 .

[260]  B. Christensen,et al.  Total synthesis of β-lactam antibiotics IX (±)-1-oxabisnorpenicillin G , 1978 .

[261]  R. Gillespie,et al.  2,5-Dichlorothiophenium bismethoxycarbonylmethylide: a bismethoxycarbonylcarbene equivalent , 1978 .

[262]  R. Gillespie,et al.  Thermal rearrangement of thiophenium bismethoxycarbonylmethylides: a novel synthesis of thiophene-2-malonic esters , 1978 .

[263]  O. M. Nefedov,et al.  Reaktionen von Alkenylfuranen mit Ethyldiazoacetat , 1977 .

[264]  R. Neidlein,et al.  Untersuchungen mit 1,4-Dioxen, I. Reaktion von 1,4-Dioxen mit (Ethoxycarbonyl)carben , 1977 .

[265]  B. Ranu,et al.  .gamma.-Alkylation of .alpha.,.beta.-unsaturated carbonyl compounds , 1977 .

[266]  E. Wenkert,et al.  A method of synthesis of .beta.-methylfurans and .alpha.-methylene and .beta.-methylene .gamma.-lactones. Two menthofuran syntheses , 1977 .

[267]  S. Bien,et al.  Catalyst-product dependency in the transition metal catalyzed decomposition of ethyl 3-diazo-2-oxopropionate. An unusual Wolff rearrangement , 1977 .

[268]  W. Andō Ylide formation and rearrangement in the reaction of carbene with divalent sulfur compounds , 1977 .

[269]  R. M. Richman,et al.  Electron paramagnetic resonance study of the adduct of a nitroxide and rhodium trifluoroacetate dimer , 1977 .

[270]  R. G. Salomon,et al.  Rhodium(I) catalysis of vinylcyclopropane epimerization and ring cleavage rearrangements , 1977 .

[271]  A. Tai,et al.  Stereo-differentiating reactions , 1977 .

[272]  J. Ibers,et al.  Cyclopropanation reactions of diazoalkanes with substituted olefins in the presence and absence of nickel(0) and palladium(0) catalysts. The structure of (diazofluorene)bis(tert-butyl isocyanide)nickel(0); a complex containing a .pi.-bonded diazofluorene molecule , 1977 .

[273]  M. Curini,et al.  The rearrangement of isothiochroman sulphonium ylides via a thermal ylide exchange reaction , 1977 .

[274]  I. Ernest Penicillin-derived diazoketones: Copper(II) catalyzed decomposition in aprotic media , 1977 .

[275]  G. Koomen,et al.  Unconventional nucleotide analogues: Reaction of carbenes with uracil and uridine derivatives , 1977 .

[276]  T. King,et al.  Reaction of ethyl diazoacetate with cobalt porphyrins. Part 3. structure and reactions of the 2:1 adducts. , 1977, Journal of the Chemical Society. Perkin transactions 1.

[277]  A. W. Johnson,et al.  Reaction of ethyl diazoacetate with cobalt porphyrins. Part 2. , 1977, Journal of the Chemical Society. Perkin transactions 1.

[278]  A. Anciaux,et al.  Rhodium(II) carboxylates: Novel highly efficient catalysts for the cyclopropanation of alkenes with alkyl diazoacetates , 1976 .

[279]  Maitland Jones,et al.  The stereochemistry of the intramolecular reactions of cyclopropylcarbenes , 1976 .

[280]  A. Hubert,et al.  Synthesis of iminoaziridines from carbodiimides and diazoesters : A new example of transition metal salt catalysed reactions of carbenes , 1976 .

[281]  P. G. Sammes,et al.  Recent chemistry of the β-lactam antibiotics , 1976 .

[282]  B. Poling,et al.  Metal salt catalyzed carbenoids , 1976 .

[283]  S. Bien,et al.  Dependence of product on catalyst in the transition-metal-catalysed decomposition of ethyl 2-allyl-4-diazoacetoacetate , 1976 .

[284]  D. Crumrine,et al.  Cyclopropanation transition states. The electronic effect , 1976 .

[285]  B. W. Peace,et al.  Metal salt catalyzed carbenoid—XIII: On the mechanisms of cyclopropanation and allylic CH insertions by diazo esters in the presence of olefins and homogeneous copper catalysts , 1976 .

[286]  N. Thinh,et al.  Metal salt catalyzed carbenoids—XV: The synthetic and structural aspects of copper salt catalyzed additions of bis-methoxycarbonyl carbene to olefins☆ , 1976 .

[287]  B. W. Peace,et al.  Metal salt catalyzed carbenoides—XIV: The mechanisms of carbene dimer formation from diazoacetic ester and dimethyl diazomalonate in the presence of some soluble copper catalysts , 1976 .

[288]  H. Kisch,et al.  Complexation and activation of diazenes and diazo compounds by transition metals , 1976 .

[289]  E. Vedejs,et al.  Macrocycle synthesis by repeatable 2,3-sigmatropic shifts. Ring-growing reactions , 1975 .

[290]  H. Callot,et al.  Rearrangement of N-substituted porphyrins. Preparation and structure of homoporphyrins , 1975 .

[291]  T. Aratani,et al.  Asymmetric synthesis of chrysanthemic acid. An application of copper carbenoid reaction , 1975 .

[292]  W. Agosta,et al.  PREPARATION OF BICYCLO(3,2,1)OCTAN-6-ONES FROM SUBSTITUTED CYCLOHEXYL DIAZO KETONES , 1975 .

[293]  D. Crumrine,et al.  Catalytic decomposition of diphenyldiazomethane by Lewis acids, cyclopropanation reactions of a diphenylcarbenoid species , 1975 .

[294]  A. Nakamura,et al.  Diazoalkankomplexe mit Nickel(0) und Palladium(0) und ihre Bedeutung für Carbenoidreaktionen , 1975 .

[295]  D. Tavernier,et al.  Some Carbene Reactions on Myrcene , 1975 .

[296]  Ph. Moniotte,et al.  The role of copper(I) complexes in the selective formation of oxazoles from unsaturated nitriles and diazoesters , 1975 .

[297]  R. Coates,et al.  Regiospecific synthesis of trimethylsilyl enol ethers via silatropic rearrangements , 1975 .

[298]  R. G. Salomon,et al.  Vinylcyclopropanation of olefins with vinyldiazomethane , 1975 .

[299]  H. Meier,et al.  Die Wolff‐Umlagerung von α‐Diazocarbonyl‐Verbindungen , 1975 .

[300]  J. Kottwitz,et al.  The Formation of Cyclopropanes from Strained Alkenes with Diazomethane/Palladium(II) Acetate , 1975 .

[301]  H. Vorbrüggen,et al.  A new simple conversion of α,β-unsaturated carbonyl compounds into their corresponding cyclopropyl ketones and esters , 1975 .

[302]  C. Elson,et al.  Condensation of ethyl diazoacetate with cobalt porphyrins. , 1975, Journal of the Chemical Society. Perkin transactions 1.

[303]  W. Herrmann Ein neues Verfahren zur Darstellung von Übergangsmetall-Carben-Komplexen , 1974 .

[304]  L. Paquette,et al.  Solvolytic studies of unsaturated 11-hydroxymethylbicyclo[4.4.1]undecane 3,5-dinitrobenzoates. Valence isomerization leading to conformationally distinguishable annulated norcaradienylcarbinyl cations and the question of remote p.pi. stabilization of such .sigma.-delocalized systems , 1974 .

[305]  J. Ibers,et al.  STRUCTURE AND MECHANISM OF FORMATION OF A NOVEL PI‐BONDED KETENIMINE COMPLEX, BIS(TERT.‐BUTYLISOCYANID) (N‐TERT.‐BUTYLDICYANOKETENIMINE)NICKEL(0), EVIDENCE FOR A METAL‐ASSISTED CARBENE ADDITION , 1974 .

[306]  S. Bien,et al.  Reactions with α-diazo-ketones. Part II. Intramolecular cyclisation of bisdiazo-ketones , 1974 .

[307]  Ph. Moniotte,et al.  Transition metal catalyzed 1-3-dipolar cycloaddition of carbethoxycarbene to acrylonitrile , 1974 .

[308]  L. T. Scott,et al.  Intermolecular carbon-hydrogen insertion of copper carbenoids , 1974 .

[309]  D. Bethell,et al.  Intermediates in the decomposition of aliphatic diazo-compounds. Part X. Kinetic and mechanistic studies of the decomposition of diphenyldiazomethane catalysed by copper(II) bromide , 1974 .

[310]  R. G. Salomon,et al.  Copper(I) catalysis in cyclopropanations with diazo compounds. Role of olefin coordination , 1973 .

[311]  M. Lappert,et al.  The chemistry of transition-metal carbene complexes and their role as reaction intermediates , 1973 .

[312]  S. Bertz,et al.  Reaction of metal-carbene complexes with diazoalkanes. A versatile vinyl ether synthesis. , 1973 .

[313]  H. Ledon,et al.  Insertion intramoleculaire selective de carbenoide malonique sur la liaison C - H tertiaire d'un carbone asymetrique avec retention de configuration. , 1973 .

[314]  B. W. Peace,et al.  Preparation and Reactions of Diazomalonic Esters , 1973 .

[315]  E. Wenkert,et al.  γ-Ketoacid Derivatives , 1973 .

[316]  K. Nakayama,et al.  Decomposition of dimethyl diazomalonate in allyl compounds containing heteroatoms , 1972 .

[317]  K. Sonogashira,et al.  Novel carbene complexes of rhodium , 1972 .

[318]  J. Kochi,et al.  Cationic benzene and olefin complexes of copper(I) trifluoromethanesulphonate , 1972 .

[319]  A. Hubert,et al.  Transition metal catalysed cyclopropanation of olefin , 1972 .

[320]  H. Callot Stereochimie de l'addition de carbenes sur la meso-tetraphenylporphine. , 1972 .

[321]  J. Rooney,et al.  Reaction of diazomethane on a cobalt molybdate catalyst. The mechanism of olefin disproportionation , 1972 .

[322]  K. C. Brown,et al.  Intermediates in the decomposition of aliphatic diazo-compounds. Part IX. Kinetics and mechanism of the decomposition of diaryldiazomethanes catalysed by zinc halides , 1972 .

[323]  N. Peet,et al.  Chemistry of carbanions. XX. Comparison of .alpha.-chloro enolate anions and .alpha.-diazo ketones , 1971 .

[324]  K. Nakayama,et al.  Reaction of carbethoxycarbene with aliphatic sulfides and allyl compounds , 1971 .

[325]  W. S. Trahanovsky,et al.  Oxidation of organic compounds with cerium(IV). XIII. Cerium(IV)-catalyzed decomposition of aryldiazomethanes to cis- and trans-stilbenes , 1971 .

[326]  W. Kirmse CHAPTER 3 – Organometallic Methylene Transfer Agents , 1971 .

[327]  R. J. Stoodley,et al.  Epimerisation of penicillanic acid derivatives and their rearrangement to 1,4-thiazepines: evidence for an E1cB mechanism , 1971 .

[328]  E. Steffen,et al.  Homogeneous copper(I) catalysed decomposition of dimethyl diazomalonate. The role of the counter ion in determining the effective spin multiplicity , 1971 .

[329]  Yoshinori Yamamoto,et al.  Catalytic decomposition of diazo compounds by metal salts , 1971 .

[330]  J. Poland,et al.  α-Heterodiazoalkanes and the Reactions of Diazoalkanes with Derivatives of Metals and Metalloids , 1971 .

[331]  R. Mueller,et al.  Cyclopropanol derivatives as intermediates for organochemical synthesis , 1970 .

[332]  A. Ledwith,et al.  Developments in the chemistry of diazo-alkanes , 1970 .

[333]  J. C. Shepard,et al.  Synthesis, spectral properties, and chemical ring opening of tricyclo[3,3.0.02,8]octan-3-one, a rigid model for unsymmetrical cyclopropyl ketone participation , 1969 .

[334]  W. R. Moser Mechanism of the copper-catalyzed addition of diazoalkanes to olefins. I. Steric effects , 1969 .

[335]  W. Andō Thermal rearrangement of cyclopropyl and alkenyl malonic esters , 1969 .

[336]  S. Goh,et al.  Carbenoid decomposition of aryldiazomethanes with lithium and zinc halides. Synthesis of arylcyclopropanes , 1969 .

[337]  J. Richards,et al.  Reaction of nickelocene with diazoalkanes , 1968 .

[338]  W. Kirmse,et al.  Reaktionen des Diazomethans mit Diallylsulfid und Allyläthern unter Kupfersalz‐Katalyse , 1968 .

[339]  C. J. Blankley,et al.  Perhydroindan derivatives. VIII. Bridgehead alkylation via cyclopropane intermediates , 1968 .

[340]  C. J. Blankley,et al.  Preparation and decomposition of unsaturated esters of diazoacetic acid , 1968 .

[341]  H. Takaya,et al.  Homogeneous catalysis in the decomposition of diazo compounds by copper chelates , 1968 .

[342]  B. Bogdanović,et al.  Übergangsmetallkomplexe, I. Olefin‐Komplexe des Nickels(0) , 1966 .

[343]  R. K. Armstrong Decomposition of Ethyl Diazoacetate by a π-Allylic Palladium Chloride Complex , 1966 .

[344]  H. Takaya,et al.  Reaction of carbethoxycarbene with 2-phenyloxirane and 2-phenyloxetane , 1966 .

[345]  H. Kessler,et al.  Katalysierte Diazoalkan-Reaktionen , 1966 .

[346]  D. Cowan,et al.  Mechanisms of Photochemical Reactions in Solution. XXIV.1 Photochemical and Catalytic Decomposition of Diazoacetophenone , 1964 .

[347]  H. M. Neumann,et al.  Preparation and Properties of Anhydrous Rhodium-(II) Acetate and Some Adducts Thereof , 1963 .

[348]  G. Schrauzer,et al.  Über die Carbonylierung von Carbenen und die katalytische Zersetzung von Diazoalkanen mit Nickelcarbonyl , 1960 .

[349]  W. Doering,et al.  Stereo-selectivity in the reaction of carbomethoxycarbene with cis-butene , 1960 .

[350]  M. F. Dull,et al.  The Reaction of Some Methylene Derivatives with Ketene Diethylacetal1 , 1959 .

[351]  M. Kharasch,et al.  Reactions of diazoacetates and diazoketones. I. Reaction of ethyl diazoacetate with cyclohexanone and with acetone , 1953 .

[352]  L. Wolff,et al.  Über Diazoanhydride (1,2,3-Oxydiazole oder Diazoxyde) und Diazoketone , 1912 .

[353]  A. Loose Reaktionen des Diazoessigesters , 1909 .