Influence of metakaolin as supplementary cementing material on strength and durability of concretes

Abstract Durability of concrete is an important issue for predicting the service life of concrete structures. Recently, the properties of metakaolin as high-quality pozzolanic materials are investigated by several researchers. It is not widely produced and used due to the lack of adequate experiments on this material in the Middle East. Local kaolin with high kaolinite content was thermally treated by a special furnace at 800 °C and 60 min burning time to produce metakaolin. This study investigates the performance of concrete mixtures containing local metakaolin in terms of compressive strength, water penetration, sorptivity, salt ponding, Rapid Chloride Permeability Test (RCPT) and electrical resistivity at 7, 28, 90 and 180 days. In addition, microstructure of the cement pastes incorporating metakaolin was studied by XRD and SEM tests. The percentages of metakaolin that replace PC in this research are 0%, 10%, 12.5% and 15% by mass. The water/binder ( w / b ) ratios are 0.35, 0.4 and 0.5 having a constant total binder content of 400 kg/m 3 . Results show that concrete incorporating metakaolin had higher compressive strength and metakaolin enhanced the durability of concretes and reduced the chloride diffusion. An exponential relationship between chloride permeability and compressive strength of concrete is exhibited. A significant linear relationship was found between Rapid Chloride Permeability Test and salt ponding test results.

[1]  A. Kaur,et al.  Effect of metakaolin on the near surface characteristics of concrete , 2011 .

[2]  Ali Akbar Ramezanianpour,et al.  Practical evaluation of relationship between concrete resistivity, water penetration, rapid chloride penetration and compressive strength , 2011 .

[3]  C. L. Page,et al.  Aspects of the pore solution chemistry of hydrated cement pastes containing metakaolin , 1997 .

[4]  Mohammad Shekarchi,et al.  Transport properties in metakaolin blended concrete , 2010 .

[5]  J. G. Cabrera,et al.  Pore size distribution and degree of hydration of metakaolin–cement pastes , 2000 .

[6]  H. A. Razak,et al.  Near surface characteristics of concrete containing supplementary cementing materials , 2004 .

[7]  Michael D. A. Thomas,et al.  INCREASING CONCRETE DURABILITY WITH HIGH-REACTIVITY METAKAOLIN , 2001 .

[8]  Luc Courard,et al.  Durability of mortars modified with metakaolin , 2003 .

[9]  S. Cho,et al.  The relationship between pore structure and chloride diffusivity from ponding test in cement-based materials , 2006 .

[10]  D. S. Klimesch,et al.  Use of the second-derivative differential thermal curve in the evaluation of cement-quartz pastes with metakaolin addition autoclaved at 180°C , 1997 .

[11]  Kiyofumi Kurumisawa,et al.  Development of technique for observing pores in hardened cement paste , 2002 .

[12]  J. Bai,et al.  Metakaolin and calcined clays as pozzolans for concrete: a review , 2001 .

[13]  Willfried Krieg Rapid chloride permeability testing : a critical review , 2007 .

[14]  C. Page,et al.  Effects of metakaolin, water/binder ratio and interfacial transition zones on the microhardness of cement mortars , 2002 .

[15]  Mehmet Gesoǧlu,et al.  Improving strength, drying shrinkage, and pore structure of concrete using metakaolin , 2008 .

[16]  Emil Makovicky,et al.  Pozzolanic reactions of six principal clay minerals: Activation, reactivity assessments and technological effects , 1995 .

[17]  Jamal M. Khatib,et al.  ABSORPTION CHARACTERISTICS OF METAKAOLIN CONCRETE , 2004 .

[18]  J. Brooks,et al.  Effect of metakaolin on creep and shrinkage of concrete , 2001 .

[19]  E. Badogiannis,et al.  Exploitation of poor Greek kaolins: Durability of metakaolin concrete , 2009 .

[20]  R. D. Hooton,et al.  STUDY OF THE JOULE EFFECT ON RAPID CHLORIDE PERMEABILITY VALUES AND EVALUATION OF RELATED ELECTRICAL PROPERTIES OF CONCRETES , 2004 .

[21]  Jamal M. Khatib,et al.  Pore size distribution of metakaolin paste , 1996 .

[22]  Obada Kayali,et al.  Chloride penetration in binary and ternary blended cement concretes as measured by two different rapid methods , 2008 .

[23]  Han-Young Moon,et al.  Strength properties and durability aspects of high strength concrete using Korean metakaolin , 2007 .

[24]  N Gowripalan,et al.  Chloride-ion induced corrosion of galvanized and ordinary steel reinforcement in high-performance concrete , 1998 .

[25]  F. Curcio,et al.  Dilatant Behavior of Superplasticized Cement Pastes Containing Metakaolin , 1998 .

[26]  Min-Hong Zhang,et al.  Characteristics of a thermally activated alumino-silicate pozzolanic material and its use in concrete , 1995 .

[27]  S. Wild,et al.  Relative strength, pozzolanic activity and cement hydration in superplasticised metakaolin concrete , 1996 .

[28]  B. Ramesh Babu,et al.  Study on strength and corrosion performance for steel embedded in metakaolin blended concrete/mortar , 2008 .

[29]  D. S. Klimesch,et al.  Autoclaved Cement-Quartz Pastes with Metakaolin Additions , 1998 .

[30]  Z. Ding,et al.  PROPERTY IMPROVEMENT OF PORTLAND CEMENT BY INCORPORATING WITH METAKAOLIN AND SLAG , 2003 .

[31]  Alaa M. Rashad,et al.  Durability and strength evaluation of high-performance concrete in marine structures , 2010 .