Wettability, hysteresis and fracture–matrix interaction during CO2 EOR and storage in fractured carbonate reservoirs

Abstract Relative permeabilities show significant dependence on the saturation path during CO 2 enhanced oil recovery (EOR) and storage. This dependence (or hysteresis) is particularly important for water-alternating-gas (WAG) injection, a successful CO 2 EOR and storage method for clastic and carbonate reservoirs. WAG injection is characterized by an alternating sequence of drainage and imbibition cycles. Hysteresis is hence common and results in residual trapping of the CO 2 phase, which impacts the volume of CO 2 stored and the incremental oil recovery. The competition between hysteresis and geological heterogeneity during CO 2 EOR and storage, particularly in carbonate reservoirs, is not yet fully understood. In this study, we use a high-resolution simulation model of a Jurassic Carbonate ramp, which is an analogue for the highly prolific reservoirs of the Arab D formation in Qatar, to investigate the impact of hysteresis during CO 2 EOR and storage in heterogeneous carbonate formations. We then compare the impact of residual trapping (due to hysteresis) on recovery to the impact of heterogeneity in wettability and reservoir structure. End-member wettability scenarios and multiple wettability distribution approaches are tested, while, effective fracture permeabilities are computed using discrete fracture networks (DFN), ranging from sparsely distributed background fractures to fracture networks where intensity varies with proximity to faults. The results enable us to analyze the efficiency of oil recovery and CO 2 sequestration in carbonate reservoirs by comparing the impact of physical displacement processes (e.g., imbibition, drainage, residual trapping) and heterogeneous rock properties (e.g., wettability, faults, fractures, layering) that are typical in carbonate reservoirs. We show that although the fracture network properties have the greatest impact on the fluid flow, the effect of wettability and hysteresis is nontrivial. Our results emphasize the need for wettability to be accurately measured and appropriately distributed in a reservoir simulation model. Similarly, our results indicate that hysteresis effects in cyclic displacement processes must be accounted for in detail to ensure that simulation models give accurate predictions.

[1]  Anthony R. Kovscek,et al.  A pore-level scenario for the development of mixed-wettability in oil reservoirs , 1993 .

[2]  Stefan Bachu,et al.  Aquifer disposal of CO2: Hydrodynamic and mineral trapping , 1994 .

[3]  Jan M. Nordbotten,et al.  Hysteretic upscaled constitutive relationships for vertically integrated porous media flow , 2012, Comput. Vis. Sci..

[4]  Milind Deo,et al.  A methodology for quantifying risk and likelihood of failure for carbon dioxide injection into deep saline reservoirs , 2014 .

[5]  K. Sorbie,et al.  Pore-network Prediction of Residual Oil Saturation Based on Oil Layer Drainage in Mixed-wet Systems , 2010 .

[6]  Sebastian Geiger,et al.  A Novel Multi-Rate Dual-Porosity Model for Improved Simulation of Fractured and Multiporosity Reservoirs , 2013 .

[7]  H. L. Stone Estimation of Three-Phase Relative Permeability And Residual Oil Data , 1973 .

[8]  N. Morrow,et al.  Effect of Wettability on Waterflood Recovery for Crude-Oil/Brine/Rock Systems , 1995 .

[9]  Emmanuel Manceau,et al.  Integrated Study of a Fractured Middle East Reservoir With Stratiform Super-K Intervals-Part 2:Upscaling and Dual-Media Simulation , 2002 .

[10]  Erling Halfdan Stenby,et al.  REVIEW OF WAG FIELD EXPERIENCE , 1998 .

[11]  Anthony R. Kovscek,et al.  A Pore-Level Scenario for the Development of Mixed Wettability in Oil Reservoirs , 1992 .

[12]  K. S. Schmid,et al.  Universal scaling of spontaneous imbibition for water‐wet systems , 2012 .

[13]  S. Bauer,et al.  Short- and long-term regional pressure build-up during CO2 injection and its applicability for site monitoring , 2013 .

[14]  C. Mason,et al.  Co-Optimization of Enhanced Oil Recovery and Carbon Sequestration , 2009 .

[15]  M. Blunt,et al.  Prediction of Wettability Variation Within an Oil/Water Transition Zone and Its Impact on Production , 2005 .

[16]  O. Gosselin,et al.  Matrix-fracture transfer function in dual-medium flow simulation - Improved model of capillary imbibition , 2008 .

[17]  Ye Zhang,et al.  Model complexity in carbon sequestration: A design of experiment and response surface uncertainty analysis , 2014 .

[18]  Erdal Ozkan,et al.  A Critical Review for Proper Use of Water/Oil/Gas Transfer Functions in Dual-Porosity Naturally Fractured Reservoirs: Part II , 2009 .

[19]  John Killough,et al.  Reservoir Simulation With History-Dependent Saturation Functions , 1976 .

[20]  Mohammad Piri,et al.  Three-dimensional mixed-wet random pore-scale network modeling of two- and three-phase flow in porous media. II. Results. , 2005, Physical review. E, Statistical, nonlinear, and soft matter physics.

[21]  K. S. Schmid,et al.  Universal scaling of spontaneous imbibition for arbitrary petrophysical properties: Water-wet and mixed-wet states and Handy's conjecture , 2013 .

[22]  G. H. Mäkel,et al.  The modelling of fractured reservoirs: constraints and potential for fracture network geometry and hydraulics analysis , 2007 .

[23]  Norman R. Morrow,et al.  Recovery of oil by spontaneous imbibition , 2001 .

[24]  Patrice de Caritat,et al.  Safe storage and effective monitoring of CO2 in depleted gas fields , 2011, Proceedings of the National Academy of Sciences.

[25]  Martin J. Blunt,et al.  Design of Carbon Dioxide Storage in Oil Fields , 2008 .

[26]  K. Aziz,et al.  Petroleum Reservoir Simulation , 1979 .

[27]  Martin J. Blunt,et al.  Multirate-Transfer Dual-Porosity Modeling of Gravity Drainage and Imbibition , 2007 .

[28]  S. M. Hassanizadeh,et al.  Insights into the Relationships Among Capillary Pressure, Saturation, Interfacial Area and Relative Permeability Using Pore-Network Modeling , 2008 .

[29]  Olivier Gosselin,et al.  Matrix-Fracture Transfer Function in Dual-Media Flow Simulation: Review, Comparison and Validation , 2008 .

[30]  Ruben Juanes,et al.  Impact of relative permeability hysteresis on geological CO2 storage , 2006 .

[31]  M. Z. Kalam,et al.  Variations in Bounding and Scanning Relative Permeability Curves with Different Carbonate Rock Types , 2012 .

[32]  Philip Ringrose,et al.  Evaluating the impact of fractures on the performance of the In Salah CO2 storage site , 2010 .

[33]  F. Friedmann,et al.  Assessing Uncertainty in Channelized Reservoirs Using Experimental Designs , 2003 .

[34]  Ruben Juanes,et al.  CO2 migration in saline aquifers. Part 2. Capillary and solubility trapping , 2011, Journal of Fluid Mechanics.

[35]  Jean-Marc Daniel,et al.  An Integrated Workflow to Account for Multi-Scale Fractures in Reservoir Simulation Models: Implementation and Benefits , 2002 .

[36]  Ruben Juanes,et al.  A New Model of Trapping and Relative Permeability Hysteresis for All Wettability Characteristics , 2008 .

[37]  Martin J. Blunt,et al.  Multi-Rate Transfer Dual Porosity Modeling of Gravity Drainage Imbibition , 2005 .

[38]  Anthony R. Kovscek,et al.  Geologic storage of carbon dioxide and enhanced oil recovery. II. Cooptimization of storage and recovery , 2005 .

[39]  J. E. Warren,et al.  The Behavior of Naturally Fractured Reservoirs , 1963 .

[40]  Charles D. Gorecki,et al.  CO 2 storage associated with CO 2 enhanced oil recovery: A statistical analysis of historical operations , 2015 .

[41]  Martin J. Blunt,et al.  Effects of wettability on three-phase flow in porous media , 2000 .

[42]  Eduardo Manrique,et al.  EOR Field Experiences in Carbonate Reservoirs in the United States , 2007 .

[43]  Front dynamics of supercritical non‐Boussinesq gravity currents , 2006 .

[44]  G. Jerauld,et al.  Wettability and Relative Permeability of Prudhoe Bay: A Case Study in Mixed-Wet Reservoirs , 1997 .

[45]  Sebastian Geiger,et al.  Accurate Modelling of Pore-Scale Films and Layers for Three-Phase Flow Processes in Clastic and Carbonate Rocks with Arbitrary Wettability , 2013, Transport in Porous Media.

[46]  Martin J. Blunt,et al.  Effects of Heterogeneity and Wetting on Relative Permeability Using Pore Level Modeling , 1997 .

[47]  Trevor P. Burchette,et al.  Carbonate rocks and petroleum reservoirs: a geological perspective from the industry , 2012 .

[48]  Amin Ettehadtavakkol,et al.  CO2-EOR and storage design optimization , 2014 .

[49]  Martin J. Blunt,et al.  Predictive pore‐scale modeling of two‐phase flow in mixed wet media , 2004 .

[50]  M. Blunt,et al.  Prediction Of Wettability Variation And Its Impact On Waterflooding Using Pore- To Reservoir-Scale Simulation , 2002 .

[51]  H. Herzog,et al.  Lifetime of carbon capture and storage as a climate-change mitigation technology , 2012, Proceedings of the National Academy of Sciences.

[52]  Roddy V. Amenta,et al.  Simulating fabric development in igneous rocks: a solution for modeling space competition among growing crystals , 1992 .

[53]  Jack C. Parker,et al.  A model for hysteretic constitutive relations governing multiphase flow: 2. Permeability‐saturation relations , 1987 .

[54]  Celso Cesar M. Branco,et al.  Challenges in Implementing an EOR Project in the Pre-Salt Province in Deep Offshore Brasil , 2012 .

[55]  Francis M. Carlson,et al.  Simulation of Relative Permeability Hysteresis to the Nonwetting Phase , 1981 .

[56]  Rainer Helmig,et al.  A concept for data-driven uncertainty quantification and its application to carbon dioxide storage in geological formations , 2011 .

[57]  Louis J. Durlofsky,et al.  A New Well-Pattern-Optimization Procedure for Large-Scale Field Development , 2011 .

[58]  R. Haszeldine,et al.  CO2–Mineral Reaction in a Natural Analogue for CO2 Storage—Implications for Modeling , 2009 .

[59]  L. Baker Three-Phase Relative Permeability Correlations , 1988 .

[60]  J. C. Sabathier,et al.  Typical Features of a Multipurpose Reservoir Simulator , 1989 .

[61]  B. Todd Hoffman,et al.  Using production logs (PLT) to estimate the size of fracture networks , 2012 .

[62]  Martin J. Blunt An Empirical Model for Three-Phase Relative Permeability , 2000 .

[63]  F. Sonier,et al.  Hysteresis in Three-Phase Flow: Experiments, Modeling and Reservoir Simulations , 2000 .

[64]  Robert J. Lenhard,et al.  A Parametric Model for Predicting Relative Permeability-Saturation-Capillary Pressure Relationships of Oil–Water Systems in Porous Media with Mixed Wettability , 1998 .

[65]  Taha M. Okasha,et al.  Fifty Years of Wettability Measurements in the Arab-D Carbonate Reservoir , 2007 .

[66]  Mohammad Piri,et al.  Three-dimensional mixed-wet random pore-scale network modeling of two- and three-phase flow in porous media. I. Model description. , 2005, Physical review. E, Statistical, nonlinear, and soft matter physics.

[67]  Slawomir Koziel,et al.  Computational Optimization, Methods and Algorithms , 2016, Computational Optimization, Methods and Algorithms.

[68]  Mrinal K. Sen,et al.  On optimization algorithms for the reservoir oil well placement problem , 2006 .

[69]  Stephen E. Laubach,et al.  Predicting and characterizing fractures in dolostone reservoirs: using the link between diagenesis and fracturing , 2004, Geological Society, London, Special Publications.

[70]  Hossein Kazemi,et al.  Improvements in Simulation of Naturally Fractured Reservoirs , 1983 .

[71]  Lingli Wei,et al.  Integration of Discrete Feature Network Methods With Conventional Simulator Approaches , 2000 .

[72]  L. Dake Fundamentals of Reservoir Engineering , 1983 .

[73]  Sebastian Geiger,et al.  The third porosity system , 2012 .

[74]  Emmanuel Manceau,et al.  Integrated Study of a Fractured Middle East Reservoir with Stratiform Super-K Intervals - Part 2: Upscaling and Dual Media Simulation , 2001 .

[75]  Raphael T. Haftka,et al.  Surrogate-based Analysis and Optimization , 2005 .

[76]  S. Geiger,et al.  Black-Oil Simulations for Three-Component, Three-Phase Flow in Fractured Porous Media , 2009 .

[77]  Z. Beydoun,et al.  Arabian plate oil and gas: Why so rich and so prolific? , 1998 .

[78]  Mahmoud Jamiolahmady,et al.  Safe storage of Co2 together with improved oil recovery by Co2-enriched water injection , 2011 .

[79]  Arne Graue,et al.  Wettability effects on the matrix–fracture fluid transfer in fractured carbonate rocks , 2011 .

[80]  M. Oda,et al.  Permeability tensor for discontinuous rock masses , 1985 .

[81]  Kenneth Stuart Sorbie,et al.  Two-Phase Pore-Network Modelling: Existence of Oil Layers During Water Invasion , 2009 .

[82]  Sebastian Geiger,et al.  Numerical simulation of fluid-flow processes in a 3D high-resolution carbonate reservoir analogue , 2014 .

[83]  Edward Alan Clerke,et al.  Permeability, Relative Permeability, Microscopic Displacement Efficiency and Pore Geometry of M_1 Bimodal Pore Systems in Arab-D Limestone , 2009 .

[84]  Hengwei Liu,et al.  The Role of CO2 Capture and Storage in Saudi Arabia's Energy Future , 2012 .

[85]  Matthew D. Jackson,et al.  Prediction of wettability variation and its impact on flow using pore- to reservoir-scale simulations , 2003 .

[86]  Béatrice Rivière,et al.  Computational methods for multiphase flows in porous media , 2007, Math. Comput..

[87]  Jack C. Parker,et al.  A model for hysteretic constitutive relations governing multiphase flow: 1. Saturation-pressure relations , 1987 .

[88]  D. Denney Fifty Years of Wettability Measurements in the Arab-D Carbonate Reservoir , 2008 .

[89]  M. Blunt,et al.  General Transfer Functions for Multiphase Flow in Fractured Reservoirs , 2008 .

[90]  H. L. Stone Probability Model for Estimating Three-Phase Relative Permeability , 1970 .

[91]  F. Friedmann,et al.  Assessing Uncertainty in Channelized Reservoirs Using Experimental Designs , 2001 .

[92]  Anthony R. Kovscek,et al.  SCREENING CRITERIA FOR CO2 STORAGE IN OIL RESERVOIRS , 2002 .

[93]  K. S. Schmid,et al.  Multi-Rate Mass-Transfer Dual-Porosity Modelling Using the Exact Analytical Solution for Spontaneous Imbibition , 2013 .

[94]  M. Z. Kalam,et al.  Variations in Bounding and Scanning Relative Permeability Curves With Different Carbonate Rock Type , 2013 .

[95]  Jon Kleppe,et al.  A Survey of North Sea Enhanced-Oil-Recovery Projects Initiated During the Years 1975 to 2005 , 2008 .

[96]  Rainer Helmig,et al.  Comparison of cell- and vertex-centered discretization methods for flow in a two-dimensional discrete-fracture–matrix system , 2009 .

[97]  Steven Robert McDougall,et al.  Saturation-dependencies of three-phase relative permeabilities in mixed-wet and fractionally wet systems , 2001 .

[98]  Ryan T. Armstrong,et al.  Exploring capillary trapping efficiency as a function of interfacial tension, viscosity, and flow rate , 2011 .

[99]  H. Kazemi,et al.  A Critical Review For Proper Use Of Water-Oil-Gas Transfer Functions In Dual-Porosity Naturally Fractured Reservoirs-Part II , 2007 .

[100]  Erdal Ozkan,et al.  A Critical Review for Proper Use of Water-Oil-Gas Transfer Functions in Dual-Porosity Naturally Fractured Reservoirs - Part I , 2007 .

[101]  Ali Rawahi,et al.  Maximize the Ultimate Recovery by Designing & Optimizing a CO2 Miscible Gas Injection Pilot in Giant Carbonate Oil Reservoir, Abu Dhabi , 2012 .

[102]  Jan M. Nordbotten,et al.  Impact of capillary hysteresis and trapping on vertically integrated models for CO2 storage , 2013 .

[103]  Sebastian Geiger,et al.  A Novel Multi-rate Dual-porosity Model for Improved Simulation of Fractured and Multi-porosity Reservoirs , 2011 .

[104]  M. Z. Kalam,et al.  Carbonate Reservoir Rock Typing - The Link between Geology and SCAL , 2008 .

[105]  R. Juanes,et al.  CO[subscript 2] migration in saline aquifers: Regimes in migration with dissolution , 2011 .

[106]  Tadeusz W Patzek,et al.  Impact of wettability alteration on two‐phase flow characteristics of sandstones: A quasi‐static description , 2003 .

[107]  Arne Skauge,et al.  Methodology for Numerical Simulation With Cycle-Dependent Relative Permeabilities , 1998 .

[108]  Martin J. Blunt,et al.  Design of carbon dioxide storage in aquifers , 2009 .

[109]  C. Durlet,et al.  Spatial and temporal distribution of ooids along a Jurassic carbonate ramp: Amellago outcrop transect, High-Atlas, Morocco , 2010 .

[110]  M. Sohrabi,et al.  An Improved Three-Phase Relative Permeability and Hysteresis Model for the Simulation of a Water-Alternating-Gas Injection , 2013 .

[111]  Ruben Juanes,et al.  Impact of relative permeability hysteresis on the numerical simulation of WAG injection , 2006 .

[112]  Venkateswaran Sriram Pudugramam,et al.  Novel Three-Phase Compositional Relative Permeability and Three-Phase Hysteresis Models , 2015 .

[113]  S. Geiger,et al.  Impact of pore-scale three-phase flow for arbitrary wettability on reservoir-scale oil recovery , 2014 .

[114]  Peter R. King,et al.  Robust optimisation of CO2 sequestration strategies under geological uncertainty using adaptive sparse grid surrogates , 2014, Computational Geosciences.

[115]  Lingli Wei,et al.  Integration of Discrete Feature Network Methods with Conventional Simulator Approaches , 2000 .

[116]  Michael A. Celia,et al.  Trapping and hysteresis in two‐phase flow in porous media: A pore‐network study , 2013 .

[117]  Carlon S. Land,et al.  Calculation of Imbibition Relative Permeability for Two- and Three-Phase Flow From Rock Properties , 1968 .

[118]  S. Geiger,et al.  Effective integration of reservoir rock-typing and simulation using near-wellbore upscaling , 2015 .

[119]  Amilcar Soares,et al.  Integrated Reservoir Characterisation of a Fractured Carbonate Reservoir , 2000 .

[120]  Sara Tomás,et al.  Outcrop analog for an oolitic carbonate ramp reservoir: A scale-dependent geologic modeling approach based on stratigraphic hierarchy , 2013 .

[121]  Karsten Pruess,et al.  Numerical Modeling of Aquifer Disposal of CO2 , 2001 .

[122]  Matthew D. Jackson,et al.  Detailed physics, predictive capabilities and macroscopic consequences for pore-network models of multiphase flow. , 2002 .

[123]  John W. Cosgrove,et al.  Hybrid veins from the southern margin of the Bristol Channel Basin, UK , 2010 .

[124]  Hossein Kazemi,et al.  Analytical and numerical solution of oil recovery from fractured reservoirs with empirical transfer functions , 1992 .

[125]  Anthony R. Kovscek,et al.  Increasing CO2 storage in oil recovery , 2005 .

[126]  Cathy Hollis,et al.  Pore system characterisation in heterogeneous carbonates: An alternative approach to widely-used rock-typing methodologies , 2010 .

[127]  M. Z. Kalam,et al.  Miscible Gas Injection Tests in Carbonates and its impact on Field Development , 2011 .

[128]  J. E. Sylte,et al.  Ekofisk Field: fracture permeability evaluation and implementation in the flow model , 2005, Petroleum Geoscience.

[129]  Mark Naylor,et al.  Review and implications of relative permeability of CO2/brine systems and residual trapping of CO2 , 2014 .

[130]  R. Pollard,et al.  The Machar Oil Field: waterflooding a fractured chalk reservoir , 2007, Geological Society, London, Special Publications.