The Structural Chemistry of Quaternary Chalcogenides of the Type AMM'Q3

The rich structural chemistry of compounds of the type AMM'Q3, where A is an s-block alkali- or alkaline-earth metal, M is a d-block transition metal, M' is another d-block metal or an f-block metal, and Q is a chalcogen, is discussed. We briefly consider the syntheses and physical property measurements of these compounds, but our main emphasis is on differences and trends among the seven structure types in which the 160 known, structurally characterized compounds crystallize.

[1]  J. Ibers,et al.  Thallium(I) copper(I) thorium(IV) triselenide, TlCuThSe3 , 2012, Acta crystallographica. Section E, Structure reports online.

[2]  J. Ibers,et al.  RbAuUSe3, CsAuUSe3, RbAuUTe3, and CsAuUTe3: Syntheses and structure; magnetic properties of RbAuUSe3 , 2009 .

[3]  J. Ibers,et al.  Quaternary neptunium compounds: syntheses and characterization of KCuNpS(3), RbCuNpS(3), CsCuNpS(3), KAgNpS(3), and CsAgNpS(3). , 2009, Inorganic chemistry.

[4]  Jürgen Hafner,et al.  Ab‐initio simulations of materials using VASP: Density‐functional theory and beyond , 2008, J. Comput. Chem..

[5]  R. V. Van Duyne,et al.  Syntheses, structures, physical properties, and electronic properties of some AMUQ3 compounds (A = alkali metal, M = Cu or Ag, Q = S or Se). , 2008, Inorganic chemistry.

[6]  R. V. Duyne,et al.  Syntheses, Crystal and Band Structures, and Magnetic and Optical Properties of New CsLnCdTe(3) (Ln = La, Pr, Nd, Sm, Gd-Tm, and Lu). , 2008, Inorganic chemistry.

[7]  B. Scott,et al.  Experimental and theoretical comparison of actinide and lanthanide bonding in M[N(EPR(2))(2)](3) complexes (M = U, Pu, La, Ce; E = S, Se, Te; R = Ph, iPr, H). , 2008, Inorganic chemistry.

[8]  T. Schleid,et al.  Three structure types for strontium copper(I) lanthanide(III) selenides SrCuMSe3 (M = La, Gd, Lu) , 2006 .

[9]  D. Kaczorowski,et al.  Crystal structure and magnetic properties of YbCuPbSe3 , 2006 .

[10]  P. Dorhout,et al.  Three new phases in the K/Cu/Th/S system: KCuThS3, K2Cu2ThS4, and K3Cu3Th2S7. , 2005, Inorganic chemistry.

[11]  I. Olekseyuk,et al.  Crystal structures of the compounds YCuS2, Y3CuSnS7 and YCuPbS3 , 2005 .

[12]  I. Olekseyuk,et al.  Crystal structures of the RCuPbSe3 (R = Gd, Tb, Dy, Ho, Er, Tm, Yb and Lu) compounds , 2005 .

[13]  I. Olekseyuk,et al.  Crystal structures of the compounds YCuPbSe3, Y3CuSnSe7 and Y3Cu0.685Se6 , 2004 .

[14]  R. V. Van Duyne,et al.  Syntheses, structure, some band gaps, and electronic structures of CsLnZnTe3 (Ln=La, Pr, Nd, Sm, Gd, Tb, Dy, Ho, Er, Tm, Y). , 2004, Inorganic chemistry.

[15]  T. Schleid,et al.  Quaternäre Strontium-Kupfer(I)-Lanthanoid(III)-Selenide mit Cer und Praseodym: SrCuCeSe3 und SrCuPrSe3, ein ungleiches Geschwisterpaar / Quaternary Strontium Copper(I) Lanthanoid(III) Selenides with Cerium and Praseodymium: SrCuCeSe3 and SrCuPrSe3, Unequal Brother and Sister , 2004 .

[16]  Y. Hinatsu,et al.  Crystal structures and magnetic properties of novel rare-earth copper sulfides, EuRCuS3 (R = Y, Gd–Lu) , 2004 .

[17]  R. V. Van Duyne,et al.  Syntheses, structure, and selected physical properties of CsLnMnSe3 (Ln = Sm, Gd, Tb, Dy, Ho, Er, Tm, Yb, Y) and AYbZnQ3 (A = Rb, Cs; Q = S, Se, Te). , 2004, Inorganic chemistry.

[18]  R. V. Van Duyne,et al.  The CsLnMSe3 semiconductors (Ln = rare-earth element, Y; M = Zn, Cd, Hg). , 2003, Inorganic chemistry.

[19]  R. V. Van Duyne,et al.  Tuning of optical band gaps: syntheses, structures, magnetic properties, and optical properties of CsLnZnSe(3) (Ln = Sm, Tb, Dy, Ho, Er, Tm, Yb, and Y). , 2002, Inorganic chemistry.

[20]  J. Ibers,et al.  New layered materials: syntheses, structures, and optical and magnetic properties of CsGdZnSe3, CsZrCuSe3, CsUCuSe3, and BaGdCuSe3. , 2001, Inorganic chemistry.

[21]  J. Ibers,et al.  New layered materials: syntheses, structures, and optical properties of K(2)TiCu(2)S(4), Rb(2)TiCu(2)S(4), Rb(2)TiaAg(2)S(4), Cs(2)TiAg(2)sS(4), and Cs(2)TiCu(2)Se(4). , 2001, Inorganic chemistry.

[22]  J. Ibers,et al.  The related compounds MThTe3 (M = Mn, Mg) and ACuThSe3 (A = K, Cs): syntheses and characterization. , 2000, Inorganic chemistry.

[23]  J. Ibers,et al.  Synthesis and Characterization of a Series of Quaternary Chalcogenides BaLnMQ3 (Ln=Rare Earth, M=Coinage Metal, Q=Se or Te) , 1999 .

[24]  Stephen J. Lee,et al.  Syntheses and Crystal Structures of Three Copper Tellurides: BaDyCuTe3, K1.5Dy2Cu2.5Te5, and Acentric K0.5Ba0.5DyCu1.5Te3 , 1998 .

[25]  K. Peters,et al.  Crystal structure of 2,3-diisocyano-2,3-diphenylbutane, [H3CC(NC)(C6H5)]2 , 1997 .

[26]  K. Klepp,et al.  Quaternary chalcogenides of the IVa metals with layered structures: preparation and crystal structures of TlCuTIVQ3 (T=Zr, Hf; Q=S, Se) and their relation to the Re3B structure type , 1996 .

[27]  J. Ibers,et al.  Synthesis and structure of TlCuTiTe3 , 1996 .

[28]  M. Kanatzidis,et al.  New quaternary compounds resulting from the reaction of copper and f-block metals in molten polychalcogenide salts at intermediate temperatures. Valence fluctuations in the layered CsCuCeS3 , 1996 .

[29]  J. Ibers,et al.  Uranium Tellurides: New One- and Two-Dimensional Compounds CsUTe6, CsTiUTe5, Cs8Hf5UTe30.6, and CsCuUTe3 , 1995 .

[30]  J. Ibers,et al.  New Quaternary Chalcogenides BaLnMQ3 (Ln = Rare Earth or Sc; M = Cu, Ag; Q= S, Se): II. Structure and Property Variation vs Rare-Earth Element , 1994 .

[31]  J. Ibers,et al.  New Quaternary Chalcogenides BaLnMQ3 (Ln - Rare Earth; M = Cu, Ag; Q = S, Se): I. Structures and Grinding-Induced Phase Transition in BaLaCuQ3 , 1994 .

[32]  J. Ibers,et al.  Synthesis of the New Quaternary Sulfides K2Y4Sn2S11 and BaLnAgS3 (Ln = Er, Y, Gd) and the Structures of K2Y4Sn2S11 and BaErAgS3 , 1994 .

[33]  J. Ibers,et al.  Synthesis and Structures of the New Group IV Chalcogenides NaCuTiS3 and NaCuZrQ3 (Q = S, Se, Te) , 1993 .

[34]  J. Ibers,et al.  Synthesis, structure, and conductivity of the new group IV chalcogenides, KCuZrQ3 (Q = S, Se, Te) , 1992 .

[35]  J. Ibers,et al.  LaPbCuS3: Cu(I) insertion into the α-La2S3 framework , 1992 .

[36]  J. Ibers,et al.  A new low-temperature route to metal polychalcogenides: solid-state synthesis of potassium titanium sulfide (K4Ti3S14), a novel one-dimensional compound , 1987 .

[37]  W. Bronger,et al.  Darstellung und Kristallstruktur von Na3AuS2—ein thioaurat mit isolierten anionen , 1987 .

[38]  M. Guittard,et al.  Structure du sulfure d'europium et de cuivre Eu2CuS3 , 1986 .

[39]  W. Bronger,et al.  Na3AgS2 — ein thioargentat mit isolierten anionen , 1985 .

[40]  R. D. Shannon.  Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides , 1976 .

[41]  I. Grey,et al.  Crystal structure of Ba2MnSe3. Linear antiferromagnetism in Ba2MnX3 (X = S,Se) , 1971 .