From the Sugar Platform to biofuels and biochemicals : Final report for the European Commission Directorate-General Energy

Numerous potential pathways to biofuels and biochemicals exist via the sugar platform1. This study uses literature surveys, market data and stakeholder input to provide a comprehensive evidence base for policymakers and industry – identifying the key benefits and development needs for the sugar platform. The study created a company database for 94 sugar-based products, with some already commercial, the majority at research/pilot stage, and only a few demonstration plants crossing the “valley of death”. Case studies describe the value proposition, market outlook and EU activity for ten value chains (acrylic, adipic & succinic acids, FDCA, BDO, farnesene, isobutene, PLA, PHAs and PE). Most can deliver significant greenhouse savings and drop-in (or improved) properties, but at an added cost to fossil alternatives. Whilst significant progress has been made, research barriers remain around lignocellulosic biomass fractionation, product separation energy, biological inhibition, chemical selectivity and monomer purity, plus improving whole chain process integration. An assessment of EU competitiveness highlights strengths in R&D, but a lack of strong commercial activity, due to the US, China and Brazil having more attractive feedstock and investment conditions. Further policy development, in particular for biochemicals, will be required to realise a competitive European sugar-based bioeconomy.

[1]  P.F.H. Harmsen,et al.  Pretreatment of lignocellulose for biotechnological production of lactic acid , 2013 .

[2]  Martin Kumar Patel,et al.  Accounting for the constrained availability of land: a comparison of bio‐based ethanol, polyethylene, and PLA with regard to non‐renewable energy use and land use , 2012 .

[3]  David Chiaramonti,et al.  Framework and perspectives of industrial lignocellulosic ethanol deployment: Introduction to the 1st International Conference on Lignocellulosic Ethanol , 2012 .

[4]  J. Sanders,et al.  A limited LCA of bio‐adipic acid: Manufacturing the nylon‐6,6 precursor adipic acid using the benzoic acid degradation pathway from different feedstocks , 2011, Biotechnology and bioengineering.

[5]  Stephanie G. Wettstein,et al.  A roadmap for conversion of lignocellulosic biomass to chemicals and fuels , 2012 .

[6]  Ning Ma,et al.  A study of the relationship between competitiveness and technological innovation capability based on DEA models , 2006, Eur. J. Oper. Res..

[7]  Dan Gavrilescu,et al.  ENERGY FROM BIOMASS IN PULP AND PAPER MILLS , 2008 .

[8]  Anuj K. Chandel,et al.  Sustainable Degradation of Lignocellulosic Biomass - Techniques, Applications and Commercialization , 2013 .

[9]  Zaki Kuruppalil Green Plastics: An Emerging Alternative for Petroleum Based Plastics? , 2011 .

[10]  Kecheng Li,et al.  Interactive forces between lignin and cellulase as determined by atomic force microscopy , 2014, Biotechnology for Biofuels.

[11]  E. Gomes,et al.  Agroindustrial Wastes as Substrates for Microbial Enzymes Production and Source of Sugar for Bioethanol Production , 2011 .

[12]  Van Den Eede Guy,et al.  The EU Legislation on GMOs - An Overview , 2010 .

[13]  Harvey W Blanch,et al.  Chemocatalytic upgrading of tailored fermentation products toward biodiesel. , 2014, ChemSusChem.

[14]  J. Frisvad,et al.  On the safety of Aspergillus niger – a review , 2002, Applied Microbiology and Biotechnology.

[15]  E. Jong,et al.  Product developments in the bio‐based chemicals arena , 2012 .

[16]  Toon Haer,et al.  Environmental, Social and Economic Sustainability of Biobased Plastics. Bio-polyethylene from Brazil and polylactic acid from the U.S. , 2012 .

[17]  Stephan Kabasci,et al.  Bio-based plastics : materials and applications , 2013 .

[18]  M. Delwiche,et al.  Methods for Pretreatment of Lignocellulosic Biomass for Efficient Hydrolysis and Biofuel Production , 2009 .

[19]  Adrie J. J. Straathof,et al.  Fermentative production of isobutene , 2012, Applied Microbiology and Biotechnology.

[20]  Jalel Labidi,et al.  Evaluation of different lignocellulosic raw materials as potential alternative feedstocks in biorefinery processes , 2014 .

[21]  Martin Schaaper,et al.  Measuring China's Innovation System: National Specificities and International Comparisons , 2009 .

[22]  Rathin Datta,et al.  Lactic acid: recent advances in products, processes and technologies — a review , 2006 .

[23]  Mark J. Burk,et al.  Sustainable production of industrial chemicals from sugars. , 2010 .

[24]  Martin Koller,et al.  Sustainable Embedding of the Bioplastic Poly-(3-Hydroxybutyrate) into the Sugarcane Industry: Principles of a Future-Oriented Technology in Brazil , 2009 .

[25]  Tapio Salmi,et al.  Intensification of hemicellulose hot-water extraction from spruce wood in a batch extractor--effects of wood particle size. , 2013, Bioresource technology.

[26]  Heather L. MacLean,et al.  Impact of cellulase production on environmental and financial metrics for lignocellulosic ethanol , 2013 .

[27]  Seungdo Kim,et al.  Energy and greenhouse gas profiles of polyhydroxybutyrates derived from corn grain: a life cycle perspective. , 2008, Environmental science & technology.

[28]  Akihiko Kondo,et al.  Biotechnological production of enantiomeric pure lactic acid from renewable resources: recent achievements, perspectives, and limits , 2009, Applied Microbiology and Biotechnology.

[29]  Yan Lin,et al.  Ethanol fermentation from biomass resources: current state and prospects , 2006, Applied Microbiology and Biotechnology.

[30]  J. A. Posada Duque,et al.  A biorefinery in Rotterdam with isobutanol as platform molecule , 2014 .

[31]  F. Zimbardi,et al.  2nd generation lignocellulosic bioethanol: is torrefaction a possible approach to biomass pretreatment? , 2011 .

[32]  Kes McCormick,et al.  The Bioeconomy in Europe: An Overview , 2013 .

[33]  R. Vos A review of biomass utilization in a Northern European context , 2013 .

[34]  R. P. Beaven,et al.  Assessing MSW degradation by BMP and fibre analysis , 2007 .

[35]  Guo-Qiang Chen,et al.  Plastics from bacteria : natural functions and applications , 2010 .

[36]  Saon Ray,et al.  Feedstock for the petrochemical industry , 2014 .

[37]  Martin Kumar Patel,et al.  Succinic acid production derived from carbohydrates: An energy and greenhouse gas assessment of a platform chemical toward a bio‐based economy , 2014 .

[38]  C. Cardona,et al.  Trends in biotechnological production of fuel ethanol from different feedstocks. , 2008, Bioresource technology.

[39]  David Chiaramonti,et al.  Review of pretreatment processes for lignocellulosic ethanol production, and development of an innovative method , 2012 .

[40]  H. L. Bos,et al.  Green building blocks for bio‐based plastics , 2014 .

[41]  P.F.H. Harmsen,et al.  Green building blocks for biobased plastics: biobased processes and market development , 2013 .

[42]  Steve Davies,et al.  ORIGINAL RESEARCH: The eco-profile for current Ingeo® polylactide production , 2010 .

[43]  Geert Potters,et al.  Promising biofuel resources: lignocellulose and algae , 2010 .

[44]  D. T. Jones,et al.  Acetone-butanol fermentation revisited. , 1986, Microbiological reviews.

[45]  K. Blok,et al.  Producing bio-based bulk chemicals using industrial biotechnology saves energy and combats climate change. , 2007, Environmental science & technology.

[46]  David Chiaramonti,et al.  Review of US and EU initiatives toward development, demonstration, and commercialization of lignocellulosic biofuels , 2013 .

[47]  W. Huijgen,et al.  Literature review of physical and chemical pretreatment processes for lignocellulosic biomass , 2010 .

[48]  Sabine Ziem,et al.  Environmental assessment of Braskem ’ s biobased PE resin Summary , 2013 .

[49]  G. Zeeman,et al.  Pretreatments to enhance the digestibility of lignocellulosic biomass. , 2009, Bioresource technology.

[50]  M. Taherzadeh,et al.  Pretreatment of Lignocellulosic Wastes to Improve Ethanol and Biogas Production: A Review , 2008, International journal of molecular sciences.

[51]  E. Green Fermentative production of butanol--the industrial perspective. , 2011, Current opinion in biotechnology.

[52]  Xavier Colom,et al.  Effect of alkali pretreatment on cellulase hydrolysis of wheat straw: Kinetic study , 2005 .

[53]  T. Viraraghavan,et al.  Treatment of pulp and paper mill wastewater--a review. , 2004, The Science of the total environment.

[54]  J. van Groenestijn,et al.  Pretreatment of lignocellulose with biological acid recycling (biosulfurol process) : Vorbehandlung von Lignozellulose mit biologischem Säure-Recycling (Biosulfurol-Prozess) , 2006 .

[55]  S. Mekhilef,et al.  A review on biomass as a fuel for boilers , 2011 .

[56]  Rajeev Mehta,et al.  Synthesis of Poly(Lactic Acid): A Review , 2005 .

[57]  Carles M. Gasol,et al.  Environmental profile of ethanol from poplar biomass as transport fuel in Southern Europe , 2010 .

[58]  K. O’Connor,et al.  Current progress on bio-based polymers and their future trends , 2013, Progress in Biomaterials.

[59]  Temitope Falano,et al.  Sustainability assessment of integrated bio-refineries , 2012 .

[60]  C. Wyman,et al.  Features of promising technologies for pretreatment of lignocellulosic biomass. , 2005, Bioresource technology.

[61]  S. Desobry,et al.  Poly-Lactic Acid: Production, Applications, Nanocomposites, and Release Studies. , 2010, Comprehensive reviews in food science and food safety.

[62]  M. Ballesteros,et al.  Pretreatment technologies for an efficient bioethanol production process based on enzymatic hydrolysis: A review. , 2010, Bioresource technology.