Lactic acid recovery from fermentation broth using one‐stage electrodialysis

One-stage electrodialysis (ED) for lactic acid recovery with two- and three-compartment water-splitting ED (WSED) was investigated using various ion-exchange membranes in order to overcome the inefficiency of two-stage ED, which consists of desalting ED for recovery and partial purification and subsequent WSED for acidification. The two-compartment WSED had a low current efficiency and high energy consumption in spite of a simple stack configuration. A three-compartment WSED successfully converted sodium lactate in the fermentation broth into lactic acid and sodium hydroxide with average yields of 96% and 93%, respectively. In relation to lactic acid purification, of the membranes tested in this study, the highest glucose rejection, 98.3%, was achieved using a PC 100D membrane. The CMS membrane rejected magnesium and calcium at levels as high as 81.7% and 78.5%, respectively. We concluded that the three-compartment WSED with properly chosen membranes, enabled lactic acid to be recovered directly from the fermentation broth. © 2001 Society of Chemical Industry

[1]  Romain Jeantet,et al.  Semicontinuous production of lactic acid in a bioreactor coupled with nanofiltration membranes , 1996 .

[2]  Masayoshi Iwahara,et al.  Novel Method of Lactic Acid Production by Electrodialysis Fermentation , 1986, Applied and environmental microbiology.

[3]  S. Tsai,et al.  An integrated bioconversion process for production of L-lactic acid from starchy potato feedstocks. , 1998 .

[4]  Kazuyuki Shimizu,et al.  Cell recycle and broth reuse fermentation with cross‐flow filtration and ion‐exchange resin , 1996 .

[5]  R. Audinos,et al.  Ion-exchange membrane processes for clean industrial chemistry , 1997 .

[6]  E. S. Lipinsky,et al.  Is lactic acid a commodity chemical , 1986 .

[7]  T. Jeffries,et al.  Effect of Corn Steep Liquor on Fermentation of Mixed Sugars by Candida shehatae FPL-702 , 1996 .

[8]  J. Lunt Large-scale production, properties and commercial applications of polylactic acid polymers , 1998 .

[9]  J. R. Frank,et al.  Technological and economic potential of poly(lactic acid) and lactic acid derivatives , 1995 .

[10]  Seung-Hyeon Moon,et al.  Lactic acid recovery using two-stage electrodialysis and its modelling , 1998 .

[11]  V. A. Shaposhnik,et al.  An early history of electrodialysis with permselective membranes , 1997 .

[12]  G. Pourcelly,et al.  Influence of cations on the proton leakage through anion-exchange membranes , 1996 .

[13]  K. Shimizu,et al.  Performance improvement of lactic acid fermentation by multistage extractive fermentation , 1996 .

[14]  P. Pfromm,et al.  Electrodialysis for chloride removal from the chemical recovery cycle of a Kraft pulp mill , 1998 .

[15]  A. Elmidaoui,et al.  Nitric acid and sodium hydroxide generation by electrodialysis using bipolar membranes , 1997 .

[16]  M. Goto,et al.  Extraction of lactic acid from fermented broth with microporous hollow fiber membranes , 1998 .

[17]  H. Bruschke Industrial application of membrane separation processes , 1995 .