Self-assembled molecular devices: a minireview

Abstract Self-assembled molecular devices are expected to be the leaders in the next generation of electronic devices due to their good performance and strong scalability. Types of self-assembled molecular devices include self-assembled molecular wires, self-assembled molecular field effect transistors, self-assembled molecular memory, self-assembled molecular switches, and self-assembled molecular rectifiers. In this review, the recent progress on self-assembled molecular devices is described. The achievements on fabrication of high-quality molecular devices by various methods and techniques are firstly introduced, which confirm that the molecular device performance depends largely on the self-assembly systems and materials. Next, important recent achievements on the practicability and scalability of self-assembled molecular devices are presented that form the basis for the commercialization of self-assembled molecular devices. Lastly, critical future challenges are outlined and the prospect of commercialization of self-assembled molecular devices is presented.

[1]  R. Wiesendanger,et al.  Toward Tailored All-Spin Molecular Devices. , 2016, Nano letters.

[2]  Zhen Zhang,et al.  Dynamically Regulated Ag Nanowire Arrays for Detecting Molecular Information of Substrate‐Induced Stretched Cell Growth , 2016, Advanced materials.

[3]  Y. H. Jang,et al.  Shuttlecock-Shaped Molecular Rectifier: Asymmetric Electron Transport Coupled with Controlled Molecular Motion. , 2017, Nano letters.

[4]  P. Chiu,et al.  High-performance and high-sensitivity applications of graphene transistors with self-assembled monolayers. , 2016, Biosensors & bioelectronics.

[5]  M. Ree,et al.  Finely tuned digital memory modes and performances in diblock copolymer devices by well-defined lamellar structure formation and orientation control , 2016 .

[6]  Xuewen Geng,et al.  Self-catalyzed molecular beam epitaxy growth and their optoelectronic properties of vertical GaAs nanowires on Si(111) , 2016 .

[7]  C. Lambert,et al.  Electrical characterization of 7 nm long conjugated molecular wires: experimental and theoretical studies , 2007 .

[8]  R. McCreery,et al.  Control of Rectification in Molecular Junctions: Contact Effects and Molecular Signature. , 2017, Journal of the American Chemical Society.

[9]  Vivian Wing-Wah Yam,et al.  Supramolecular Self-Assembly and Dual-Switch Vapochromic, Vapoluminescent, and Resistive Memory Behaviors of Amphiphilic Platinum(II) Complexes. , 2017, Journal of the American Chemical Society.

[10]  J. Samitier,et al.  Molecular architecture for DNA wiring. , 2018, Biosensors & bioelectronics.

[11]  J. Lacroix,et al.  Supramolecular Networks and Wires Dominated by Intermolecular BiEDOT Interactions , 2018, The Journal of Physical Chemistry C.

[12]  Jeffrey Kelling,et al.  DNA-Mold Templated Assembly of Conductive Gold Nanowires. , 2018, Nano letters.

[13]  Roey J. Amir,et al.  Reversible Dimerization of Polymeric Amphiphiles Acts as a Molecular Switch of Enzymatic Degradability. , 2017, Biomacromolecules.

[14]  J. Veciana,et al.  An Electrically Driven and Readable Molecular Monolayer Switch Based on a Solid Electrolyte. , 2016, Angewandte Chemie.

[15]  M. Halik,et al.  A facile approach to synthesize an oxo-functionalized graphene/polymer composite for low-voltage operating memory devices , 2015 .

[16]  L. Jones,et al.  Nanostructured Fused Pyrrole Thin Films: Encoding Nano “Bits” with Temporary Remanence , 2018, Advanced Electronic Materials.

[17]  K. Jeong,et al.  Solid‐State Light Emission Controlled by Tuning the Hierarchical Superstructure of Self‐Assembled Luminogens , 2018 .

[18]  A. Jen,et al.  Enhanced Performance of Self‐Assembled Monolayer Field‐Effect Transistors with Top‐Contact Geometry through Molecular Tailoring, Heated Assembly, and Thermal Annealing , 2015 .

[19]  Ken Sakai,et al.  Inside Cover: Near-Infrared Light-Driven Hydrogen Evolution from Water Using a Polypyridyl Triruthenium Photosensitizer (Angew. Chem. Int. Ed. 1/2018) , 2018 .

[20]  V. Yam,et al.  Triindole-Tris-Alkynyl-Bridged Trinuclear Gold(I) Complexes for Cooperative Supramolecular Self-Assembly and Small-Molecule Solution-Processable Resistive Memories. , 2017, ACS applied materials & interfaces.

[21]  Igor L. Medintz,et al.  Extending DNA‐Based Molecular Photonic Wires with Homogeneous Förster Resonance Energy Transfer , 2016 .

[22]  D. Zahn,et al.  Helical Ordering of α-l-Polyalanine Molecular Layers by Interdigitation , 2019, The Journal of Physical Chemistry C.

[23]  M. Halik,et al.  Self-assembled monolayer field-effect transistors based on oligo-9,9'-dioctylfluorene phosphonic acids. , 2017, Nanoscale.

[24]  Xiaodong Xu,et al.  Systematic Doping Control of CVD Graphene Transistors with Functionalized Aromatic Self‐Assembled Monolayers , 2014 .

[25]  Y. Tao,et al.  Organic transistor memory with a charge storage molecular double-floating-gate monolayer. , 2015, ACS applied materials & interfaces.

[26]  M. Lin,et al.  Novel supramolecular conjugated polyrotaxane as an acid-base controllable optical molecular switch , 2017 .

[27]  B. Heinrich,et al.  Electron-Deficient Dihydroindaceno-Dithiophene Regioisomers for n-Type Organic Field-Effect Transistors. , 2017, ACS applied materials & interfaces.

[28]  Jinlan Wang,et al.  How to Fabricate a Surface-Grafted Polythiophene on H-Si(100)2×1 Surface via Self-Assembling and in Situ Surface Polymerization: A Theoretical Guide , 2016 .

[29]  S. Hecht,et al.  Reversible and Efficient Light-Induced Molecular Switching on an Insulator Surface. , 2018, ACS nano.

[30]  Daniel J. Tate,et al.  Trichlorosilanes as Anchoring Groups for Phenylene‐Thiophene Molecular Monolayer Field Effect Transistors , 2014 .

[31]  R. Tokas,et al.  Probing molecular packing at engineered interfaces in organic field effect transistor and its correlation with charge carrier mobility. , 2015, ACS applied materials & interfaces.

[32]  M. Halik,et al.  Effect of Structure and Disorder on the Charge Transport in Defined Self-Assembled Monolayers of Organic Semiconductors. , 2017, ACS nano.

[33]  J. Veciana,et al.  Tuning the Rectification Ratio by Changing the Electronic Nature (Open-Shell and Closed-Shell) in Donor-Acceptor Self-Assembled Monolayers. , 2017, Journal of the American Chemical Society.

[34]  B. Liu,et al.  The photochromism, light harvesting and self-assembly activity of a multi-function Schiff-base compound based on the AIE effect , 2018 .

[35]  Synthesis, Surface Grafting, and Fabrication of Ultrathin Polymeric SAMFETs with High Field-Effect Mobility. , 2018, ACS applied materials & interfaces.

[36]  P. Geerlings,et al.  Conductance Switching in Expanded Porphyrins through Aromaticity and Topology Changes. , 2018, Journal of the American Chemical Society.

[37]  Chunhui Xu,et al.  Tuning the Crystal Polymorphs of Alkyl Thienoacene via Solution Self‐Assembly Toward Air‐Stable and High‐Performance Organic Field‐Effect Transistors , 2015, Advanced materials.

[38]  Miso Kim,et al.  Gradients of Rectification: Tuning Molecular Electronic Devices by the Controlled Use of Different-Sized Diluents in Heterogeneous Self-Assembled Monolayers. , 2016, Angewandte Chemie.

[39]  Xiaoyan He,et al.  Dual-Responsive Molecular Switches Based on Dithienylethene-RuII Organometallics in Self-Assembled Monolayers Operating at Low Voltage. , 2017, Chemistry.

[40]  R. H. Kim,et al.  Non-Volatile ReRAM Devices Based on Self-Assembled Multilayers of Modified Graphene Oxide 2D Nanosheets. , 2016, Small.

[41]  N. Glezos,et al.  Low-Dimensional Polyoxometalate Molecules/Tantalum Oxide Hybrids for Non-Volatile Capacitive Memories. , 2016, ACS applied materials & interfaces.

[42]  P. Saalfrank,et al.  Two-Dimensional Nonlinear Optical Switching Materials: Molecular Engineering toward High Nonlinear Optical Contrasts , 2018, The Journal of Physical Chemistry C.

[43]  D. Wei,et al.  Photo-switchable field-effect transistors based on two-dimensional stilbene oligomer crystals , 2017 .

[44]  M. Liu,et al.  Reversible Quadruple Switching with Optical, Chiroptical, Helicity, and Macropattern in Self‐Assembled Spiropyran Gels , 2017 .

[45]  Igor L. Medintz,et al.  Increased Transfer Efficiency from Molecular Photonic Wires on Solid Substrates and Cryogenic Conditions. , 2018, The journal of physical chemistry letters.

[46]  G. Yu,et al.  Isoindigo dye incorporated copolymers with diselenophenylethene: Synthesis, characterization, and enhanced mobilities in field-effect transistors with electrodes modified by thiol-based self-assembled monolayers , 2017 .

[47]  Eunji Lee,et al.  Simple Solvent Engineering for High-Mobility and Thermally Robust Conjugated Polymer Nanowire Field-Effect Transistors. , 2018, ACS applied materials & interfaces.

[48]  W. Xu,et al.  Photocontrol of charge injection/extraction at electrode/semiconductor interfaces for high-photoresponsivity organic transistors , 2016 .

[49]  Stable doping of carbon nanotubes via molecular self assembly , 2014 .

[50]  Lin Gu,et al.  Design of a Photoactive Hybrid Bilayer Dielectric for Flexible Nonvolatile Organic Memory Transistors. , 2016, ACS nano.

[51]  C. Rovira,et al.  A four-state capacitance molecular switch based on a redox active tetrathiafulvalene self-assembled monolayer , 2017 .

[52]  John S. Suehle,et al.  Redox-Active Molecular Nanowire Flash Memory for High-Endurance and High-Density Nonvolatile Memory Applications. , 2015, ACS applied materials & interfaces.

[53]  R. Eelkema,et al.  Single-Molecule Resonant Tunneling Diode , 2015 .

[54]  A. Kaifer,et al.  Cucurbit[8]uril (CB[8])-Based Supramolecular Switches. , 2018, Angewandte Chemie.

[55]  Shermin S. Goh,et al.  Theoretical study on the self-assembly of 1,3,5-triethynylbenzene on Si(100)2 × 1 and in situ polymerization via reaction with CO to fabricate a single surface-grafted polymer , 2017 .

[56]  A. Riemann,et al.  Molecular wires self-assembled on a graphite surface. , 2009, Langmuir : the ACS journal of surfaces and colloids.

[57]  Yu Zhu,et al.  Hydrogen-Bonding-Mediated Solid-State Self-Assembled Isoepindolidiones (isoEpi) Crystal for Organic Field-Effect Transistor , 2018 .

[58]  B. Ong,et al.  Engineering gate dielectric surface properties for enhanced polymer field-effect transistor performance , 2015 .

[59]  J. Ulański,et al.  Balanced Ambipolar Organic Field-Effect Transistors by Polymer Preaggregation. , 2017, ACS applied materials & interfaces.

[60]  J. Ortega,et al.  Tunable Band Alignment with Unperturbed Carrier Mobility of On-Surface Synthesized Organic Semiconducting Wires , 2016, ACS nano.

[61]  M. Fujita,et al.  Rectifying Electron-Transport Properties through Stacks of Aromatic Molecules Inserted into a Self-Assembled Cage. , 2015, Journal of the American Chemical Society.

[62]  M. Halik,et al.  Tuning the molecular order of C60-based self-assembled monolayers in field-effect transistors. , 2014, Nanoscale.

[63]  R. Ma,et al.  Superlattice assembly of graphene oxide (GO) and titania nanosheets: fabrication, in situ photocatalytic reduction of GO and highly improved carrier transport. , 2014, Nanoscale.

[64]  C. Rovira,et al.  Self-Assembly of an Organic Radical Thin Film and Its Memory Function Investigated Using a Liquid-Metal Electrode , 2018, The Journal of Physical Chemistry C.

[65]  Li Yuan,et al.  Arrays of high quality SAM-based junctions and their application in molecular diode based logic. , 2015, Nanoscale.

[66]  Hua-Zhong Yu,et al.  Metastable Molecular Metal–Semiconductor Junctions , 2015 .

[67]  D. Porath,et al.  Magnetic Nanoplatelet‐Based Spin Memory Device Operating at Ambient Temperatures , 2017, Advanced materials.

[68]  M. Aono,et al.  Self-assembled diacetylene molecular wire polymerization on an insulating hexagonal boron nitride (0001) surface , 2016, Nanotechnology.

[69]  D. Porath,et al.  Highly Conductive Thin Uniform Gold‐Coated DNA Nanowires , 2018, Advanced materials.

[70]  K. Loh,et al.  Synthesis and electrical characterization of oligo(phenylene ethynylene) molecular wires coordinated to transition metal complexes. , 2009, ACS nano.

[71]  M. Thuo,et al.  Elucidating the Role of Molecule-Electrode Interfacial Defects in Charge Tunneling Characteristics of Large-Area Junctions. , 2018, Journal of the American Chemical Society.

[72]  T. Satoh,et al.  Donor–Acceptor Poly(3‐hexylthiophene)‐block‐Pendent Poly(isoindigo) with Dual Roles of Charge Transporting and Storage Layer for High‐Performance Transistor‐Type Memory Applications , 2016 .