Superior radical polymer cathode material with a two-electron process redox reaction promoted by graphene

Poly(2,2,6,6-tetramethyl-1-piperidinyloxy-4-yl methacrylate) (PTMA) displays a two–electron process redox reaction, high capacity of up to 222 mA h g−1, good rate performance and long cycle life, which is promoted by graphene as cathode material for lithium rechargeable batteries.

[1]  Doron Aurbach,et al.  Challenges in the development of advanced Li-ion batteries: a review , 2011 .

[2]  Hong Li,et al.  Thermodynamic analysis on energy densities of batteries , 2011 .

[3]  Philippe Poizot,et al.  Clean energy new deal for a sustainable world: from non-CO2 generating energy sources to greener electrochemical storage devices , 2011 .

[4]  Li-Jun Wan,et al.  Better lithium-ion batteries with nanocable-like electrode materials , 2011 .

[5]  Jaephil Cho,et al.  Who will drive electric vehicles, olivine or spinel? , 2011 .

[6]  Hua Zhang,et al.  Cobalt Oxide Nanowall Arrays on Reduced Graphene Oxide Sheets with Controlled Phase, Grain Size, and Porosity for Li-Ion Battery Electrodes , 2011 .

[7]  G. Shi,et al.  Graphene based new energy materials , 2011 .

[8]  Ping He,et al.  Olivine LiFePO4: development and future , 2011 .

[9]  Tetsuo Sakai,et al.  High-capacity organic positive-electrode material based on a benzoquinone derivative for use in rechargeable lithium batteries , 2010 .

[10]  Yu‐Guo Guo,et al.  Synthesis of CuO/graphene nanocomposite as a high-performance anode material for lithium-ion batteries , 2010 .

[11]  Ling Huang,et al.  Crystal Habit‐Tuned Nanoplate Material of Li[Li1/3–2x/3NixMn2/3–x/3]O2 for High‐Rate Performance Lithium‐Ion Batteries , 2010, Advanced materials.

[12]  H. Dai,et al.  Mn3O4-graphene hybrid as a high-capacity anode material for lithium ion batteries. , 2010, Journal of the American Chemical Society.

[13]  Shinichi Komaba,et al.  Fast redox of composite electrode of nitroxide radical polymer and carbon with polyacrylate binder , 2010 .

[14]  Dongsheng Lu,et al.  Synthesis and properties of a lithium-organic coordination compound as lithium-inserted material for lithium ion batteries , 2010 .

[15]  Y. Mei,et al.  Stretchable graphene: a close look at fundamental parameters through biaxial straining. , 2010, Nano letters.

[16]  J-M Tarascon,et al.  Key challenges in future Li-battery research , 2010, Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences.

[17]  Klaus Müllen,et al.  Graphene-based nanosheets with a sandwich structure. , 2010, Angewandte Chemie.

[18]  Yu‐Guo Guo,et al.  Mono dispersed SnO2 nanoparticles on both sides of single layer graphene sheets as anode materials in Li-ion batteries , 2010 .

[19]  Yunhong Zhou,et al.  Polyimides: promising energy-storage materials. , 2010, Angewandte Chemie.

[20]  G. Cui,et al.  Fabrication of cobalt and cobalt oxide/graphene composites: towards high-performance anode materials for lithium ion batteries. , 2010, ChemSusChem.

[21]  Jeffrey W. Fergus,et al.  Recent developments in cathode materials for lithium ion batteries , 2010 .

[22]  Xueping Gao,et al.  Multi-electron reaction materials for high energy density batteries , 2010 .

[23]  Xuejie Huang,et al.  Research on Advanced Materials for Li‐ion Batteries , 2009 .

[24]  A. Manthiram,et al.  Rapid, Facile Microwave-Solvothermal Synthesis of Graphene Nanosheets and Their Polyaniline Nanocomposites for Energy Strorage , 2009 .

[25]  A. Govindaraj,et al.  Graphene: the new two-dimensional nanomaterial. , 2009, Angewandte Chemie.

[26]  Li-Jun Wan,et al.  LiFePO4 Nanoparticles Embedded in a Nanoporous Carbon Matrix: Superior Cathode Material for Electrochemical Energy‐Storage Devices , 2009, Advanced materials.

[27]  K. Oyaizu,et al.  Radical Polymers for Organic Electronic Devices: A Radical Departure from Conjugated Polymers? , 2009 .

[28]  Hiroyuki Nishide,et al.  Emerging N‐Type Redox‐Active Radical Polymer for a Totally Organic Polymer‐Based Rechargeable Battery , 2009 .

[29]  Jou-Hyeon Ahn,et al.  Electrochemical properties of rechargeable organic radical battery with PTMA cathode , 2009 .

[30]  Kenichiroh Koshika,et al.  An ultrafast chargeable polymer electrode based on the combination of nitroxide radical and aqueous electrolyte. , 2009, Chemical communications.

[31]  Jin-Song Hu,et al.  Nanostructured Materials for Electrochemical Energy Conversion and Storage Devices , 2008 .

[32]  B. Z. Jang,et al.  Processing of nanographene platelets (NGPs) and NGP nanocomposites: a review , 2008, Journal of Materials Science.

[33]  Jou‐Hyeon Ahn,et al.  Organic radical battery with PTMA cathode: Effect of PTMA content on electrochemical properties , 2008 .

[34]  Jean-Marie Tarascon,et al.  From biomass to a renewable LixC6O6 organic electrode for sustainable Li-ion batteries. , 2008, ChemSusChem.

[35]  P. Bruce,et al.  Nanomaterials for rechargeable lithium batteries. , 2008, Angewandte Chemie.

[36]  Naoya Ogata,et al.  Synthesis and properties of DNA complexes containing 2,2,6,6-tetramethyl-1-piperidinoxy (TEMPO) moieties as organic radical battery materials. , 2008, Chemistry.

[37]  H. X. Yang,et al.  Polytriphenylamine: A high power and high capacity cathode material for rechargeable lithium batteries , 2008 .

[38]  M. Armand,et al.  Building better batteries , 2008, Nature.

[39]  Taolei Sun,et al.  Aromatic Carbonyl Derivative Polymers as High‐Performance Li‐Ion Storage Materials , 2007 .

[40]  Hiroyuki Nishide,et al.  Photocrosslinked nitroxide polymer cathode-active materials for application in an organic-based paper battery. , 2007, Chemical communications.

[41]  Jiro Iriyama,et al.  High-rate capable organic radical cathodes for lithium rechargeable batteries , 2007 .

[42]  S. Stankovich,et al.  Graphene-based composite materials , 2006, Nature.

[43]  J. Maier,et al.  Nanoionics: ion transport and electrochemical storage in confined systems , 2005, Nature materials.

[44]  Jun Chen,et al.  Template-synthesized LiCoO2, LiMn2O4, and LiNi0.8 Co0.2 O2 nanotubes as the cathode materials of lithium ion batteries. , 2005, The journal of physical chemistry. B.

[45]  P. Bruce,et al.  Nanostructured materials for advanced energy conversion and storage devices , 2005, Nature materials.

[46]  John R. Owen,et al.  Poly(2,5-dihydroxy-1,4-benzoquinone-3,6-methylene): a new organic polymer as positive electrode material for rechargeable lithium batteries , 2003 .

[47]  Shigeyuki Iwasa,et al.  Rechargeable batteries with organic radical cathodes , 2002 .

[48]  P. Novák,et al.  Electrochemically Active Polymers for Rechargeable Batteries. , 1997, Chemical reviews.

[49]  N. Oyama,et al.  Dimercaptan–polyaniline composite electrodes for lithium batteries with high energy density , 1995, Nature.